• 센서학회지
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• 제16권5호
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• pp.349-354
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• 2007

This paper presents characteristics of surface acoustic wave (SAW) gas sensor for detecting volatile gases such as ethanol gas by measuring the phase shift of output signal. A delay-line with a center frequency of 400 MHz was fabricated on $128^{\circ}$ Y-Z $LiNbO_{3}$ substrates. Experimental results, which showed the phase change of the output signal under the absorption of volatile gas on sensor surface, were presented. The sensitivities of SAW delay lines coated with polyurethane films were greatly increased compared to those for uncoated devices. This SAW gas sensor system may be well suited for a high sensitivity electronic nose system.

• 한국세라믹학회지
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• 제37권4호
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• pp.308-313
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• 2000

Hydrous titanium oxide particles with anatase phase were prepared from 0.05 mol TiCl4 solution using NH4HCO3 as precipitant by the droopping precipitant method. The sequential change of pH is completed by a sudden and steep increase in a pH value of the range of 6~7 to which the concentration of adsorbed OH- and H+ ions on TiO2 surface is equal. Rutile phase started precipitating with anatase phase as an increase of reaction temperature above 6$0^{\circ}C$ in aqueous 0.05mol TiCl4 solution and its specific surface area was found to decrease from 452 $m^2$/g($25^{\circ}C$) to 164$m^2$/g(8$0^{\circ}C$). Specific surface area decreased rapidly when anatase powders precipitated at 4$0^{\circ}C$ were heat-treated at temperature higher 40$0^{\circ}C$. FT-IR result confirmed that it was due to the decrease of OH species within hydrous titanium oxides. The loss of ethanol after illumination of the powder heated at $600^{\circ}C$ and $700^{\circ}C$ for 4 h was 66 and 68.8%, respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.364-364
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• 2007

This paper presents characteristics of surface acoustic wave (SAW) gas sensor for detecting volatile gases such as ethanol gas by measuring phase shift of output signal. A delay-line with a center frequency of 400MHz was fabricated on 128o Y-Z $LiNbO_3$ substrates. Experimental results, which show the phase change of output signal under the absorption of volatile gas on sensor surface, were presented. The sensitivities of SAW delay lines coated with polyurethane films are greatly increased compared to those for uncoated devices. This SAW gas sensor system may be well suited for a high sensitivity electronic nose system.

• 한국군사과학기술학회지
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• 제25권5호
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• pp.487-500
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• 2022

Supercavitation is a phenomenon in which the cavity covers the entire underwater vehicle. The purpose of this paper is to compare and analyze the thermal effect on the cavity characteristics by changing the ventilated gas temperature through computational analysis. For this study, a homogeneous mixture model based on the 3D Navier-Stokes equation was used. As a phase change model, it is its own code considering both pressure change and temperature change. A dimensionless number T_m was presented to analyze the numerical results, and as the T_m increased, the cavity length increased by about 3.6 times and the cavity width by about 3.3 times at 393.15 K compared to room temperature. Analyzing these thermal effects, it was confirmed that rapid heat exchange and heat transfer between the gas phase and the liquid phase occurred at the location where the ventilated gas was sprayed, affecting the cavity characteristics. In addition, it can be confirmed that the initial cavity surface becomes unstable as the ventilated gas temperature increases, and it can be confirmed based on the numerical analysis results that the critical temperature at which the cavity surface becomes unstable is 373.15 K.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.361-361
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• 2010

The separated quasi-one-dimensional ($7{\times}7$) and ($5{\times}5$) phases on vicinal Si(557) surfaces were successfully realized by changing the crystallographic orientation and thermal treatment conditions. A small change in the crystallographic orientation of the Si(557) surface stabilized the quasi-one-dimensional ($5{\times}5$) phase of a (111) facet on vicinal Si(557) surfaces and made it coexist with a quasi-one-dimensional ($7{\times}7$) phase after an optimal thermal treatment, whereas only the quasi-one-dimensional ($7{\times}7$) phase was stable on the Si(557) surface. Interestingly, this causes the (111) terraces with different widths (L) to prefer only one of the $5{\times}5$ (L=12) and $7{\times}7$ (L=9) phases resulting in long-range order of both phases along the step edge direction, which was observed by scanning tunneling microscopy (STM) and was supported by first principle calculations. In contrast, the quasi-one-dimensional ($5{\times}5$ and ($7{\times}7$) phases were arranged randomly across the step edge direction. The change of surface morphology of vicinal Si(557) surfaces will be discussed with STM images and theoretical calculations by changing crystallographic cutting angles and thermal treatment conditions.

• 한국분말재료학회지
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• 제29권3호
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• pp.219-225
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• 2022

An alternative fabrication method for carburizing steel using spark plasma sintering (SPS) is investigated. The sintered carburized sample, which exhibits surface modification effects such as carburizing, sintered Fe, and sintered Fe-0.8 wt.%C alloys, is fabricated using SPS. X-ray diffraction and micro Vickers tests are employed to confirm the phase and properties. Finite element analysis is performed to evaluate the change in hardness and analyze the carbon content and residual stress of the carburized sample. The change in the hardness of the carburized sample has the same tendency to predict hardness. The difference in hardness between the carburized sample and the predicted value is also discussed. The carburized sample exhibits a compressive residual stress at the surface. These results indicate that the carburized sample experiences a surface modification effect without carburization. Field emission scanning electron microscopy is employed to verify the change in phase. A novel fabrication method for altering the carburization is successfully proposed. We expect this fabrication method to solve the problems associated with carburization.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.248.2-248.2
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• 2014

In this study, the optical properties and structural characteristics of gallium nitride (GaN) thin films prepared by radio frequency (RF) magnetron sputtering were investigated. Auger electron and X-ray photoelectron spectra showed that the deposited films consisted mainly of gallium and nitrogen. The presence of oxygen was also observed. The optical bandgap of the GaN films was measured to be approximately 3.31 eV. The value of the refractive index of the GaN films was found to be 2.36 at a wavelength of 633 nm. X-ray diffraction data revealed that the crystalline phase of the deposited GaN films changed from wurtzite to zinc-blende phase upon decreasing the sputtering gas pressure. Along with the phase change, a strong dependence of the microstructure of the GaN films on the sputtering gas pressure was also observed. The microstructure of the GaN films changed from a voided columnar structure having a rough surface to an extremely condensed structure with a very smooth surface morphology as the sputtering gas pressure was reduced. The relationship between the phase and microstructure changes in the GaN films will be discussed.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.150.2-150.2
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• 2013

We elucidate the mechanism of the self-assembled organic layer formation at the organic/metal interface of hexaaza-triphenylene-hexacarbonitrile (HATCN)/Au(111) by first-principles calculations and Lowtemperature scanning tunneling microscope (STM). In this work, we used HATCN to deposit organic material which is well known as an efficient OLED charge generation material. Low-temperature STM measurements revealed that self-assembled hexagonal porous structure is formed at terraces of Au(111). We also found that the hexagonal porous structure has chirality and forms only small (<1000 $nm^2$) phaseseparated chiral domains that can easily change their chiral phase in subsequence STM images at 80 K. To explain the mechanism of these observation, we calculated the molecular-molecular and molecule-surface interaction energies by using density functional theory method. We found that the change of their chiral phase resulted from the competition between the two energies. These results have not only verified our experimental observations, but also revealed the delicate balance between different interactions that caused the self-assembed structures at the surface.

• Journal of Advanced Marine Engineering and Technology
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• 제20권3호
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• pp.11-18
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• 1996

Liquid droplets of water and argon surrounded by their vapor have been simulated by the milecular dynamics method. To explore the surface phenomena of clusters, each molecule is classified into 'liquid', 'surface', or 'vapor' with respect to the number of neighbor molecules. The contribution of a 'surface' molecule of the water cluster to the far infrared spectrum is almist the same as that of the 'liquid' molecule. Hence, the liquid-vapor interface is viewed as geometrically and temporally varying boundary of 'liquid' molecules with only a single layer of 'surface' molecules that might have different characteristics from the 'liquid' molecules. The time scale of the 'phase change' of each molecule is estimated for the argon cluster by observing the instantancous kinetic and potential energies of each molecule. To compare the feature of clusters with macroscopic droplets, the temperature dependence of the surface tension of the argon cluster is estimated.

• 한국지구과학회지
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• 제27권3호
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• pp.302-312
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• 2006

이 연구에서는 1979년부터 2004년까지 25년 동안에 극 진동의 강도가 한반도 겨울 한파에 미치는 영향을 대기순환과 열원을 분석하여 조사하였다. 북극 진동이 강할 때 한파의 발생 횟수는 약할 때 보다 약 14.3% 더 발생하는 것으로 나타났다. 월 발생 횟수에서도 양의 AO에서 1.05회/월, 음의 AO에서 1.33회/월로 나타나서 북극 진동이 강할 때가 약할 때 보다 약 26.6% 더 많았다. 이것은 북극 진동이 강한 특정 달에 한파가 자주 발생한다는 것을 의미한다. 또한 북극 진동이 강할 때가 약할 때보다 $0.6^{\circ}C$ 더 낮은 기온을 보였다. 북극 진동의 강약에 따른 열원의 차이를 고찰한 결과, 북극 진동이 강해졌을 때 한반도 주변의 기온은 이류항에 의한 냉각이 강화되어 더 낮아지지만, 열원항에 의한 상쇄 효과에 의해 기온 하강을 억제하는 것으로 나타났다. 그 결과 대기 순환의 유의한 차이에도 불구하고 음의 AO와양의 AO 사이에 기온 차이는 평균적으로 $0.6^{\circ}C$로 작게 나타난다.