• Journal of Korean Society for Atmospheric Environment
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• v.11 no.1
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• pp.45-56
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• 1995

We considered that characteristics of surface ozone continuous and important meteorological parameters from the data measured 7 air quality continuous monitoring stations during 2 years (1990, 1993) in pusan. The diurnal ozone variation showed a primary peak near 1500LST and a secondary peak of the DP(double peaked) pattern. The episode day was defined when an ozone peak higher than 60 ppb was observed at least one station. The frequency of episode day was 100 (298 hours, 69 days). The frequency of the episode day was higher at Meongryundong and Daeyeondong than other sites and highest in August under control of pacific subtropical high. The high temporatant meteorological parameters accompanying the high episode days. The favorable synoptic environment accompanying ozone episode was distributed to 7 different pattern. These pattern can be taken as a nesessary but not an absolute indicator for predicting the occerrence of an episode.

• Journal of the Korean institute of surface engineering
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• v.31 no.2
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• pp.109-116
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• 1998

Highly transparent conductive pure and fluorine-doped tin oxide(FT0, $SnO_2$ : F) films have been prepared by low pressure metal organic chemical vapor deposition (LP-MOCVD) from various mixtures of tetramethyitin(TMT) with oxygen or oxygen containing ozone. The properties of TO films have been changed with the variation of gases, flow rate, and substrate temperature. The nsing of oxygen containing ozone instead of pure oxygen, reduced substrate temperature by 100-$150^{\circ}C$ while maintaining same thickness. The films prepared by using ozone showed the resistivity in the range from $10^~2$ to $10^{~3}\Omega$cm, and the mobiiity from 10 to $14\textrm{cm}^2$/Vs. Fluorine-doped tin oxide films had properties such as the resistivity about $10^{-4}\Omega$cm, and the mobility from 14 to $19\textrm{cm}^2$/Vs.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.121-122
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• 2003

Deposition to the sea surface is one of ozone's principal loss mechanisms (Galbally and Roy, 1980; Levy et al., 1985; Kramm, 1995). However, since complicated physical and chemical processes are involved, large uncertainties remain in evaluating this loss mechanism that need to be better characterized. In this study we attempted to explore possible causes that give rise to large variability of ozone deposition velocity in terms of wind speed and chemical reactivity in the aqueous-phase film. (omitted)

• Ocean and Polar Research
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• v.26 no.3
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• pp.439-451
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• 2004

Total solar irradiance (750), total UV irradiunce (TUV) and erythemal UV irradiance (EUV) measured at King Sejong station $(62.22^{\circ}S,\;58.78^{\circ}W)$ in west Antarctica have been used together with total ozone, cloud amount and snow cover to examine the effects of ozone, cloud and snow surface on these surface solar inadiunce over the period of 1998-2003. The data of three solar components for each scan were grouped by cloud amount, n in oktas $(0{\leq}n<3,\;3{\leq}n<4,\;4{\leq}n<5,\;5{\leq}n<6,\;6{\leq}n<7\;and\;7{\leq}n<8)$ and plotted against solar zenith angle (SZA) over the range of $45^{\circ}\;to\;75^{\circ}$. The radiation amplification factor (RAE) is used to quantify ozone effect on EUV. RAF of EUV decreases from 1.51 to 0.94 under clear skies but increases from 0.94 to 1.85 under cloudy skies as SZA increases, and decreases from 1.51 to 1.01 as cloud amount increases. The effects of cloud amount and snow surface on EUV are estimated as a function of SZA and cloud amount after normalization of the data to the reference total ozone of 300 DU. In order to analyse the transmission of solar radiation by cloud, regression analyses have been performed for the maximum values of solar irradiance on clear sky conditions $(0{\leq}n<3)$ and the mean values on cloudy conditions, respectively. The maximum regression values for the clear sky cases were taken to represent minimum aerosol conditions fur the site and thus appropriate for use as a normalization (reference) factor for the other regressions. The overall features for the transmission of the three solar components show a relatively high values around SZAs of $55^{\circ}\;and\;60^{\circ}$ under all sky conditions and cloud amounts $4{\leq}n<5$ and $5{\leq}n<6$. The transmission is, in general, the largest in TUV and the smallest in EUV among the three components of the solar irradiance. If the ground is covered with snow on partly cloudy days $(6{\leq}n<7)$, EUV increases by 20 to 26% compared to snow-free surface around SZA $60^{\circ}-65^{\circ}$, due to multiple reflections and scattering between the surface and the clouds. The relative difference between snow surface and snow-free surface slowly increases from 9% to 20% as total ozone increases from 100 DU to 400 DU under partly cloud conditions $(3{\leq}n<6)$ at SZA $60^{\circ}$. The snow effects on TUV and TSO are relatively high with 32% and 34%, respectively, under clear sky conditions, while the effects changes to 36% and 20% for TUV and TSO, respectively, as cloud amount increases.

• Journal of Environmental Science International
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• v.5 no.3
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• pp.265-275
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• 1996

Air pollution characteristics and the influence of sea breeze on surface ozone concentration were studied using the data measured at 7 air quality continuous monitoring stations from June to September using 3 years (1990, 1993, 1994) in Pusan coastal area. Among the 246 sea breeze days for research Period, there were approximately 89 sea breeze days (36%) from lune to September, And there were 120 the episode days (68%) of ozone greater than or equal to 60 ppb in summer season. In 89 sea breeze days, the episode day was highly marked as 56 days (63%). So, we knew that the sea breeze greatly affects the occurence of ozone episode day. the ozone concentration under the condition of the sea breeze increase about 40% in the daytime. Frequencies distribution of $O_3$ concentration for sea breeze moved toward high concentration class. The characteristics of ozone concentration in relation to meteorological conditions of sea breeze is significant because we can discover major weather factors for eastablishing an air pollution- weather forecast system. For further. study about meterological approach method for photochemical air pollution, it is necessary to explain the characteristics of atmosphere below 1, 000 m, especially concerning the formation mechanism of inversion layers. And finally, we will study the relationships to synoptic weather conditions and vertical structure and diurnal variation of local wind systems including sea breeze, and the vertical movements of atmosphere in the city.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.3
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• pp.67-73
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• 2010

Pine (Pinus densiflora) and aspen (Populus euramericana) wood meals were treated with ozone at various time schedule in acidic condition. The lignin contents and surface area of the ozone treated wood meals were determined and the enzymatic hydrolysis rate of ozonated wood meals was evaluated. The feasibility of enzymatic hydrolysis of the ozone treated wood meal was obviously influenced with the degree of delignification. After ozone treatment of wood meal for 10min, total pore volume were slightly increased in the surface of wood meal. When wood meals were treated with ozone longer than 10min, few change in the pore volume was observed. However, the area of over $50{\AA}$ of pore size is increased with ozonation time. As a conclusion, the rate of enzymatic hydrolysis of wood is more effective with the pore size distribution than the total pore volume.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.5
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• pp.656-665
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• 2004

An Ozone reaction model combined with CFD(Computational Fluid Dynamics) technique was developed in this research, in the simulation of ozonation, hydrodynamic behavior as well as reaction model is important because ozone is supplied to treated water as gas ozone. In order to evaluate hydrodynamic behavior in an ozone contactor, CFD technique was applied. CFD technique elucidated hydrodynamic behavior in the selected ozone contactor, which consisted of three main chambers. Three back-mixing zones were found in the contactor. The higher velocities of water were observed in the second and third compartments than that in the first compartment. The flow of the opposite direction to the main flow was observed near the water surface. Based on the results of CFD simulation, the ozone contactor was divided into small compartments. Mass balance equations were established were established in each compartment with reaction terms. This reaction model was intended to predict dissolved ozone concentration, especially. We concluded that the model could predict favorably the mass balance of ozone, namely absorption efficiency of gaseous ozone, dissolved ozone concentration and ozone consumption. After establishing the model, we discussed the effect of concentration of gaseous ozone at inlet, temperature and organic compounds on dissolved ozone concentration.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.30 no.2
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• pp.71-77
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• 2016

The dielectric barrier discharge (DBD) has low efficiency due to about 70% input power is consumed as thermal energy in the discharge space. However, because of the usage of DBD ozone generator is easier than other methods. The DBD ozone generator has been widely applied for high concentration ozone generation in the industrial application. But, the low-capacity compact DBD ozone generator is not applied so far. Therefore, the DBD ozone generator is necessary to improve ozone production efficiency and reduce the capacity. In this paper, the stainless steel pipe inner electrode was designed with hall type and screw type to improve the ozone production yield. The manufactured two inner electrodes were experimented with normal type for comparison of the discharge characteristics and the ozone generating characteristics. As the experimental results, the discharge current effective value of designed inner electrodes with hall type and screw type are higher than the normal type, due to unequal electric field is formed at the boundary. However, the difference of designed and original electrodes is less than 0.1mA that has no effect on the discharge characteristic. On the other hand, the screw type inner electrode increased higher than original model about 7 times when the flow rate of the oxygen source gas was increased from $0.6{\ell}/min$ to $1.0{\ell}/min$ The reason was assumed by the flow rate of the raw gas through the inner electrode was became fast that has a cooling effect. The designed hall type and screw type inner electrodes have shown good performances in ozone generation and ozone production that better than normal type in the same electrode surface area.

• Proceedings of the KIEE Conference
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• 1995.07c
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• pp.1410-1412
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• 1995

A high efficiency ozone generation using both of a electrode-edge discharge and a dielectric-harrier discharge from a modified silent type ozone generator has been proposed and studied for small scale applications. It is found that the output ozone concentration of the proposed generator depended greatly upon the air gap spacing and the applied power frequency and voltage on the ozone generation. The ozone generator showed higher ozone concentration than the same size of the ceramic type surface ozone generator(Masuda type one). And, it is found that the generator had a potential to be used as an ozone generator for small scale applications.

• Transactions on Electrical and Electronic Materials
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• v.2 no.2
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• pp.42-45
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• 2001

An ozone condensation system is evaluated from the viewpoint of an ozone supplier for Bi-superconductor thin film growth. An ozone condenser by a selective adsorption on the silica gel surface is constructed. Ozone density is evaluated by three methods; ultraviolet absorption, thermal decomposition and Q-mass analyzing methods. Thermal decomposition method is found to be available to the density evaluation from dilute to highly condensed ozone. The highest ozone density condensed by the adsorption method is evaluated to be 97 mol%.