• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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• pp.2193-2195
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• 2005

The hybrid discharge reactor was designed for the application of wastewater treatment and the removal of hazardous volatile organic substances in water. This discharge type was similar to the barrier discharge, and the surface discharge on the dielectric surface was propagated to the water surface. That caused the heterogeneous chemical reaction strongly at the interface between the working gases and the water surface. Changes of the conductivity, acidity, and the dissolved ozone with respect to the treatment time and water quantities were studied as the fundamental experiment. The concentration of hydrogen ions largely increased with increasing the treatment time and the conductivity increased with respect to the increase of water quantities under the constant other discharge parameters.

• 정보저장시스템학회논문집
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• 제9권2호
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• pp.42-47
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• 2013

In this study, we have experimentally analyzed how the surface properties of transparent electrode layer influence the photovoltaic performance of bulk heterojunction organic solar cell by the contact angle measurement and X-ray photoelectron spectroscopy(XPS) observation. As a result, the power conversion efficiency of test devices improved from 0.64% to 1.83% and 2.15% by UV-ozone exposure and $O_2$ plasma treatment, respectively. Thus, we conclude that the surface activation process is very important for better performance and stability in addition to the cleaning process of carbonate residue on the surface.

• 대한화학회지
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• 제60권6호
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• pp.402-409
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• 2016

3-Mecaptopropionic acid (MPA) 리간드와 하이브리드 타입 리간드($MPA+CdCl_2$)로 각각 부동화(passivation) 된 2.8 nm 크기의 황화납 콜로이드 양자점 박막을 제작하고, 각각을 대기 중, 질소 분위기에서 열처리, 오존 처리 하였을 때 나타나는 두 양자점 박막의 전자 구조와 조성 원소의 변화를 광전자 분광법을 이용하여 연구하였다. 대기에서 열처리는 리간드 종류와 관계없이 황화납 양자점의 가전자대 시작점이 공통적으로 약한 p-도핑 효과가 있음을 직접적으로 확인할 수 있었다. 또한, 오존처리 후 두 황화납 양자점 표면에 공통적으로 $Pb(OH)_2$, $PbSO_x$, PbO를 형성하는 것을 확인하였다. 하지만, 오존에 의해 형성된 산화물 중 PbO 성분은 특별히 하이브리드 타입 리간드로 부동화 된 양자점에서 형성된 양이 MPA 리간드만으로 부동화 된 양자점과 비교했을 때 감소한 것을 확인할 수 있었다. 이것은 PbS(111) 격자면에 있는 과량의 Pb 표면이 $Cl_2$으로 부동화되면서, Pb 양이온과 오존의 반응을 차단함으로써 PbO의 형성을 어렵게 했기 때문으로 추정된다.

• 한국대기환경학회지
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• 제25권5호
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• pp.369-381
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• 2009

The objective of this study was to simulate surface air pollutants and to examine reliability of mobile emission for CMAQ system using an observation-based approach in the Seoul Metropolitan Area. Accurate assessment of emissions from mobile source is one of the most debatable parts in the entire emissions inventory process. For this study, we evaluated the official emission inventories of Volatile Organic Compounds (VOCs) and nitrogen oxides ($NO_x$) using an observation-based approach. In this paper, we achieved VOCs/CO and $NO_x$/CO ratios derived from ambient measurements taken from June to August of 2005 in early morning (07:00~08:00). And we compared them with those derived from the emission inventory. Based on these ratios and on the assumption that official inventory of CO emissions is reasonably accurate, mobile emissions of $NO_x$ seem to be slightly overestimated and VOCs emissions significantly underestimated. The results of simulations using modified emission of mobile source were in closer agreement with the observation results except NO. Predicted NO values based on revised $NO_x$ emissions were considerably lower than the observed values. Using modified emission inventories brings the modeled values into closer agreement with observed ozone levels in Seoul. Especially in case of CO, $NO_x$ and VOCs emission, the modified values were suitable for simulating ozone levels in Seoul and Gyeonggi. However, ozone values predicted using the modified emissions were higher than the observed and predicted values based on original emissions. According to the 95 percentile ozone concentrations, emission revised by CO, $NO_x$ and VOCs from mobile source was the best for predicting high concentration.

• 한국안전학회지
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• 제33권1호
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• pp.41-46
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• 2018

Experiments were carried out the phenomenal observation on effect of corona treated hotmelt laminating film in process of manufacture by 2 kinds of rolling speed and electric power variatons. Surface treatment by corona which is exposure of film surface to electron of ion bombardment, rather than mere exposure to active species, like atomic oxygen or ozone, can enhance adhesion by removing contaminant, electret, roughening surface, and introducing reactive chemical group. Reactive neutrals, ions, electron and photons generated during the corona treatment interact simultaneously with polymers to alter surface chemical composition, wettability, and thus film adhesion. However, it is highly recommended that extensive chains scission is avoided because it can lead to side-effect by forming sticky matter, resulting in dropouts. This paper reviews principles of surface preparation of polypropylene substrate by corona discharging. In addition, the experimental section provides a description of parameter optimization on corona discharging treatment and its side-effect. Experimental results are discussed in terms of surface wetting as determined by contact angle and SEM measurements. When the rolling speed of the film decreased from 1.666 [m / sec] to 0.083 [m / sec], contact angle decreased from $80[^{\circ}]$ to $64[^{\circ}]$, and the wettability was greatly improved. As the supply power increased from 0.4 [kVA] to 2 [kVA] at the corona discharge surface treatment, the contact angle decreased from $77[^{\circ}]$ to $65[^{\circ}]$, and the wettability was greatly improved.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• 제23권1호
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• pp.18-33
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• 1995

동쪽 연안지역에서 큰 경사를 갖인 산맥위를 흘러가는 종관규모의 서풍하에서 내부 중력파와 같은 강한 하강폭풍이 산의 후면에서 발생되어 진다. 주간에 해양에서 내륙으로 향하는 중규모의 열적 강화에 의해 유도되는 해풍순환이 동쪽으로 향하는 내부중력파에 기인하여 연안의 앞바다까지만 국한된다. 따라서 연안해 근처의 표층풍은 외해나 내륙의 위치에서보다 상대적으로 더 약하다. 명백하게 서풍의 내부중력파순환파 해면 근처에서 동풍 및 상층에서 서풍을 갖는 해풍순환과 같은 두개의 상이한 종류의 대기순환이 뚜렷하게 나타났다. 이런 상황에서 강릉시에서의 대기오염물질은 반대 방향의 두개의 상이한 순환에 의해 갇히게 되고 부유분진과 오존의 고농도가 초래되었다. 야간에 육지에서 연안해로 향하는 중규모의 육풍은 기존의 동쪽으로 향하는 하강풍과 협력하여 연안지역에서 서풍의 더욱 강화를 유도할 수 있었다. 산쪽에서 연안해로 향하여 부는 강한 표층풍에 의해 조절되는 부유분진의 농도는 추간의 경우보다 야간에 비교적 더 높았으며, 상층대기로 부터 지표면으로 오존의 하양수송에 기인하여 오존의 농도가 주간보다 야간에 매우 높았다. 결과로 바람폭풍하의 산악연안지역에서 대기오염농도는 바람푹풍 전.후보다 더 높았다.

• 한국대기환경학회지
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• 제26권2호
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• pp.177-189
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• 2010

In order to incorporate correctly the large or local scale circulation in an atmospheric model, a nudging term is introduced into the equation of motion. The MM5 model was used to assess the meteorological values differences in each case, during ozone episode days in Gwangyang bay. The main objective of this study is to investigate the effect of horizontal and vertical flow fields according to the surface and vertical observation data assimilation by upper wind conditions. Therefore, we carried out several numerical experiments with various parameterization methods for nudging coefficient considering the upper wind conditions (synoptic or asynoptic condition). Nudging considering the synoptic and asynoptic nudging coefficient does have a clear advantage over dynamic initialization, therefore appropriate limitation of these nudging coefficient values on its upper wind conditions is necessary before making an assessment. Obviously, under the weak synoptic wind, there was apparent advantage associated with nudging coefficient by the regional difference. The accuracy for the prediction of the meteorological values has been improved by applying the appropriate PBL (Planetary Boundary Layer) limitation of circulation.

• 한국대기환경학회지
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• 제23권6호
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• pp.640-652
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• 2007

The MM5, RAMS and WRF, meteorological models have provided the dynamical parameters as inputs to air quality model. A major content of this study is that significant characteristics of three models for high-ozone occurrence analyze for surface wind and air temperature fields and compare with observation data in Seoul metropolitan area. An analysis of air temperature field revealed that location of core in high temperature of MM5 and WRF differed from that of RAMS. MM5 and WRF indicated high temperature in Seoul but RAMS represented it on the outskirts of Seoul. MM5 and WRF were underestimated maximum temperature during daytime but RAMS simulated similar value with observation data. Surface wind field with three models, it was shown many differences at horizontal distribution of wind direction. RAMS indicated weak wind speed in land and strong sea breeze at coastal areas than MM5 and WRF. However wind speed simulated by three model were overestimated during both daytime and nighttime.

• 웰빙융합연구
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• 제6권1호
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• pp.17-22
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• 2023

Purpose: VOCs (volatile organic compounds) are all the organic compounds that react with solar rays and increase the concentration of ozone in the troposphere and are partially also known as carcinogens. The adsorption using activated carbon is usually applied to remove VOCs. Research design, data and methodology: The 20 places of surface coating facilities were selected to evaluate the emission amount of VOCs in Seoul. In addition, the removal efficiency of VOCs in 25 places of automobile coating facilities was evaluated. Results: The average emission amount of VOCs was 10.903 kg/hr from automobile coating facilities, while 3.520 kg/hr from other surface coating facilities. The removal efficiency in adsorption with the combustion catalytic process has the mean value of 87.9% and the regeneration efficiency of activated carbon has the mean value of 95.0%. Conclusions: The removal efficiency in adsorption with the biofiltration process has the mean value of 89.8% and the regeneration efficiency of activated carbon has the mean value of 94.8%. The removal efficiency in the plasma catalyst process has the mean value of 79.3%.

• 폴리머
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• 제27권5호
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• pp.458-463
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• 2003

표면처리된 몬모릴로나이트 (montmorillonite, MMT)가 PP 나노복합재료의 열안정성에 미 치는 영향을 조사하였다. $Na^{+}$-MMT는 dodecylammonium chloride를 이용하여 유기적으포 개질하였다. 비표면적 ( $S_{BET}$), 평형확산압력 ($\pi$$_{e}$ ), 그리고 비극성 요소 (${\gamma}$ $s^{L}$)를 포함하는 표면 특성은 $N_2$ 흡착을 이용하는 BET 방법을 이용하여 고찰하였다. 또한, 나노복합재료의 열안정성은 시차주사열량계 (DSC)와 열중량 분석기 (TGA)를 통해 알아보았다. 실험 결과, 오존처리된 dodecylammonium chloride (DA-MK ( $O_3$))의 $\pi$$_{e}$ 과 ${\gamma}$ $s^{L}$는 1.7과 3.5 mJ/ $m^2$로 증가하였는데, 이는 미세기공이 증가하기 때문으로 판단된다. DSC 결과로부터, PP/DA-MK와 PP/DA-MK ( $O_3$)의 용융 온도와 결정화 온도는 순수한 PP보다 더 높았는데, 이러한 결과는 나노크기의 DA-MK가 PP 결정화를 위한 핵생성 효과를 유도하기 때문으로 판단된다. 또한, PP/DA-MK ( $O_3$) 나노복합재료의 열안정성은 64 kJ/mol 향상되었는데, 이는 PP 매트릭스 내 DA-MK ( $O_3$)의 분산성 향상에 기인하는 것으로 판단된다.단된다.다.