• 제목/요약/키워드: Surface modification

검색결과 1,917건 처리시간 0.029초

은 나노입자를 담지한 collagen/silica microsphere 복합체의 제조 (Preparation of Silica/collagen Microsphere Composit Doped with Silver Nanoparticles)

  • 정효정;김연범;장윤호
    • Korean Chemical Engineering Research
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    • 제46권4호
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    • pp.722-726
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    • 2008
  • 실리카 microsphere는 HPLC를 위한 흡착 충진제와 같은 용도로 사용하기에 적합한 혁신적인 소재로 널리 알려져 있다. microsphere을 기능성고분자나 금속, 생리활성 물질과 같은 특정한 성질을 지닌 물질로 표면 개질시키므로 다양한 용도로 활용할 수 있다. 콜라겐은 생체조직을 구성하는 기본 단백질로 생체적합성이 뛰어난 물질로 주목받고 있는 기능성 소재이다. 본 연구에서는 50% 이상의 세공부피를 지닌 다공성 silica microsphere를 고분자 응집법인 PICA 법을 이용하여 colloidal silica로부터 제조하고 콜라겐 hydrogel을 사용하여 표면 개질시키므로 생체적합성을 증진시키는 방법을 연구하였다. 실리카/콜라겐 microsphere 에 은 나노입자를 담지시킨 microsphere 복합체를 만들고 특성을 조사하므로 생체소재로의 활용 가능성을 조사하였다.

민속복식의 가변성 스타일링 유형분류 (The Type Classification on Modifiable Styling Methods in Wearing Folk Costumes)

  • 김혜리;전혜정
    • 복식
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    • 제61권8호
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    • pp.114-126
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    • 2011
  • Many varieties in folk costumes have inspired fashion designs for a long time. Each country, with a unique style of its own reflects their own traditions, beliefs, customs and morals into their traditional costumes. The traditional methods of creating different ways of drapery methods by using only a rectangular piece of cloth have been passed down from generation to generation and it is still used today. This way of styling has been developed mainly in the Middle East, Asia and Africa and the modifiable ways of creating drapery wearing methods are as follows. The first modifiable styling method is changing the purpose of wearing costumes according to the needs and the wants of the person who wears it. The second method is exposing the knots on the surface of the garments and by doing this, there was no visible difference on the aesthetic formation and it did not alternate for a long time. This means that simple knot shapes have been used to tie edges of rectangular fabrics. The third method is a wrapping type of modifiable styling method, which has been used most commonly in folk costumes because there are lots of ways to wrap a rectangular cloth around the body. The fourth way is the fixed type of modifiable styling method and this method can only be noticed only in the Moroccan Izar using fibulas and belts to alter the shape of the Izar. The fifth method is the composite type of modifiable styling method. This method starts by cutting out cylindrical shapes of fabrics and then wraps or twists it to fit the body. The most significant character of modifiable styling methods in folk costumes is to use rectangular cloths, which varies only in ratio of length, width and sizes. Therefore, this study suggests that rectangular cloths can create enormous amounts of fashion styling which can be easily adapted and created in everyday fashion life.

초음속/극초음속 풍동(MAF)의 성능 향상을 위한 개조 및 검증 (Modificaion and Performance Test for improving ability of Supersonic/Hypersonic Wind Tunnel(MAF))

  • 최원혁;서동수;이재우;변영환
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.717-722
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    • 2010
  • 초음속 풍동은 실험하고자 하는 모델 주위에 인공적으로 초음속 유동장을 형성하여 모델에 작용하는 현상을 관찰 및 측정하는 실험 장비이다. 이러한 풍동 실험 장비는 비행체 설계에 있어 시제기를 제작하지 않고도 비행체 외형에 대한 공기역학적 특성을 파악하는데 유용하다. 본 연구에서는 러시아에서 제작된 초음속/극초음속 풍동(MAF : The Model Aerodynamic Facility)을 시험 시간 증가 및 활용성 증가를 목적으로 개조하였다. 안전성 확보 및 원격 작동을 위해 공압 밸브를 설치, 실험 시간의 증가를 위해 새 저장 탱크를 설치했다. 설치한 밸브와 탱크를 이용할 수 있도록 배관 시스템을 개조하였다. 또한 광학적 시험을 위하여 시험부의 광학창을 확장하였다. 개조 후 마하수 2,3,4에 대하여 성능 시험을 수행하였다. 유동가시화 기법중 하나인 Shadow graph 기법을 이용하여 초음속 유동장의 형성을 확인하였으며, 마하수 2,3,4에 대하여 Settling Chamber, Working section의 압력측정을 통해 성능 시험을 수행하였다. 결과로부터 해당 초음속 풍동에 사용가능한 모델 크기 및 시험 시간을 도출하였다.

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Solution Mixing법에 의한 PS/MWCNT 복합재료의 열 및 전기전도 특성: MWCNT 표면 개질의 영향 (Thermal and Electrical Properties of PS/MWCNT Composite Prepared by Solution Mixing: Effect of Surface Modification of MWCNT)

  • 박은주;이정우;정동수;심상은
    • Elastomers and Composites
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    • 제45권1호
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    • pp.17-24
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    • 2010
  • 본 논문에서는 MWCNT/PS 복합재료 제조 시, MWCNT의 표면 개질에 의한 분산도에 따른 열 및 전기전도도에 관하여 연구하였다. 다양한 종류의 MWCNT를 PS/THF 용액에서 분산시킨 후 침전을 통하여 복합재료를 제조하였다. 사용된 MWCNT는 pristine MWCNT의 상이동 촉매 존재 하에서 상온에서 $KMnO_4$를 이용하여 하이드록실기로 개질된 MWCNT, BYK-9077 분산제를 이용한 MWCNT를 사용하였다. 분석 결과 MWCNT의 PS/THF 용액 내에서의 분산 안정성은 최종 제조되어진 복합재료의 열 및 전기전도도 특성 향상에 중요하게 기여하였다. PS/3 wt% pristine MWCNT에 비하여, 특히 분산제 BYK-9077을 사용한 경우에는 열전도도가 9.7% 및 전기전도도가 30~50% 향상되는 결과를 얻었다.

선수부 선저 슬래밍 충격에 대비한 설계압력의 산출 (Computation of Design Pressure against the Bow Bottom Slamming Impact)

  • 김용직;이승철;하영록;홍사영
    • 대한조선학회논문집
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    • 제55권3호
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    • pp.187-195
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    • 2018
  • Ship's bottom slamming has been studied by many researchers for a very long time. But still some ships suffer structure damages caused by the bottom slamming impacts. This paper presents a practical computation method of the design impact pressure due to ship's bow bottom slamming. Large heave and pitch motions of a rigid hull ship are simulated by the nonlinear strip method in time domain and the relative colliding velocity between the bow bottom and the water surface is calculated using the simulated ship motions. The bottom slamming impact pressure is calculated as a product of the relative colliding velocity squared and the bottom slamming pressure coefficient that is obtained by modification of the SNAME pressure coefficients based on Ochi's slamming experiments. Not only the bottom slamming pressures but also the required bottom plate thicknesses are calculated and compared with those of the classification society rules. The comparisons show good agreements and it is confirmed that the present method is practically very useful for the bottom structure design against ship's bow bottom slamming impacts.

CAD/CAM 전문 인력 양성을 위한 교육 및 업무의 필요성 (The Need of Education and Practice to Bring Up CAD/CAM Experts)

  • 나정숙
    • 대한치과기공학회지
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    • 제38권4호
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    • pp.365-380
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    • 2016
  • Purpose: The purpose of this study was to ascertain the need to reform curriculums for digital experts in a way that include the practical and educational aspects of dental labs by determining why educational reforms are needed to comply with changes in dental technology business that are brought by the applications of digital scanning and what changes are being actually brought by the use of CAD/CAM. Methods: This study analyzed the need of education and practice in relation to CAD/CAM by using the independent sample t-test and One-way ANOVA. in accordance with the participants demographic characteristics and job-related variables and factors related to CAD/CAM, and provided only some of the analysis results that were found statistically significant. Concerning the need of education and practice in relation to CAD/CAM, the study also used the independent sample t-test to measure difference in the perception of that need within each of the three groups, or those of job performance, job efficiency and knowledge gain at the signficance level of ${\alpha}=.05$. Results: Dental technologists surveyed here were perceiving that the use of CAD/CAM would bring changes in their job performance, job efficiency and knowledge gain. They were expecting that the biggest changes would be made in work climate and product quality as sub-areas of job performance. However, they said that in terms of job efficiency, the use of CAD/CAM would change job contribution, job satisfaction and job efficiency, but not lead to staffing. These results suggest that more special programs for CAD/CAM education are needed to bring up CAD/CAM experts who are more specialized. Conclusion: Among 13 skills related to CAD/CAM, what is most needed to be educated to dental technologists was "molding the occlusal surface" (M=4.19), followed by "designing the 3-D work" (M=4.17), "final shape modification" (M=4.16), "molding the border" (M=4.15) and "checking the fit of prothesis" (M=4.14) in order.

The improvement of Cu metal film adhesion on polymer substrate by the low-power High-frequency ion thruster

  • Jung Cho;Elena Kralkina;Yoon, Ki-Hyun;Koh, Seok-Keun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.60-60
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    • 2000
  • The adhesion interface formation between copper and poly(ethylene terephthalate)(PET), poly(methyl methacrylate)(PMMA) and Polyimide films was treated using Ion assisted reaction system to sequential sputter deposition by High-Frequency ion source. The ion beam modification system used a new type of low power HF ion thruster for space application as new low thruster electric propulsion system. Low power HF ion thruster with diameter 100mm gives the opportunity to obtain beams of Ar+ with currents 20~150 mA (current density 0.5~3.5 mA/cm2) and energy 200~2500eV at HF power level 10~150 W. Using Ar as a working gas it is possible to obtain thrust within 3~8 mN. Contact angles for untreated films were over 95$^{\circ}$ and 80 for Pet, 10o for PMMA and 12o for PI samples as a condition of ion assisted reaction at the ion dose of 10$\times$1016 ions/cm2, the ion beam potential of 1.2 keV and 4 ml/min for environmental gas flow rate. 900o peel tests yielded values of 15 to 35 for PET, 18 to 40 and 12 to 36 g/min. respectively. High resolution X-ray photoelectron spectrocopy is the Cls region for Cu metal on these polymer substrates showed increases in C=O-O groups for polymide, whereas PET and PMMA treated samples showed only C=O groups with increase the ion dose. Finally, unstable polymer surface can be changed from hydrophobic to hydrophilic formation such as C-O and C=O that were confirmed by the XPS analysis, conclusionally, the ion assisted reaction is very effective tools to attach reactive ion species to form functional groups on C-C bond chains of PET, PMMA and PI.

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Photoluminescent Graphene Oxide Microarray for Multiplex Heavy Metal Ion Analysis

  • Liu, Fei;Ha, Hyun Dong;Han, Dong Ju;Park, Min Su;Seo, Tae Seok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.281.2-281.2
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    • 2013
  • Since heavy metal ions included in water or food resources have critical effects on human health, highly sensitive, rapid and selective analysis for heavy metal detection has been extensively explored by means of electrochemical, optical and colorimetric methods. For example, quantum dots (QDs), such as semiconductor QDs, have received enormous attention due to extraordinary optical properties including high fluorescence intensity and its narrow emission peaks, and have been utilized for heavy metal ion detection. However, the semiconductor QDs have a drawback of serious toxicity derived from cadmium, lead and other lethal elements, thereby limiting its application in the environmental screening system. On the other hand, Graphene oxide (GO) has proven its superlative properties of biocompatibility, unique photoluminescence (PL), good quenching efficiency and facile surface modification. Recently, the size of GO was controlled to a few nanometers, enhancing its optical properties to be applied for biological or chemical sensors. Interestingly, the presence of various oxygenous functional groups of GO contributes to opening the band gap of graphene, resulting in a unique PL emission pattern, and the control of the sp2 domain in the sp3 matrix of GO can tune the PL intensity as well as the PL emission wavelength. Herein, we reported a photoluminescent GO array on which heavy metal ion-specific DNA aptamers were immobilized, and sensitive and multiplex heavy metal ion detection was performed utilizing fluorescence resonance energy transfer (FRET) between the photoluminescent monolayered GO and the captured metal ion.

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이상 혐기성 막공정에 의한 침출수 처리 모니터링 (Monitoring of the Treatment of Leachate by Two Phase Anaerobic Membrane Process (TPAMP))

  • 황문현;현승훈;장남정;조재원;김인수
    • 한국물환경학회지
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    • 제18권2호
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    • pp.151-157
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    • 2002
  • Landfill leachate is one of highly contaminated and heterogeneous wastewater. The leachate from initial landfill can be treated by anaerobic process because it contains biodegradable matters, particularly, volatile fatty acids (VFAs). However, the anaerobic treatment of leachate is generally required longer hydraulic retention time (HRT) than aerobic process and another treatment process to satisfy effluent concentration. Therefore the modification of conventional anaerobic treatment is needed. Two phase anaerobic membrane process (TPAMP) is an integrated membrane process to be able to separate anaerobic metabolism into two phase which are acidogenesis and methanogenesis for improvement of anaerobic treatment efficiency. In this study, the efficiency of TPAMP and conventional anaerobic treatment were compared in terms of HRT, effluent SCOD, VFAs Membrane used in TPAMP was the UF of capillary type with the surface area of $0.048m^2$. The average effluent SCOD of conventional anaerobic treatment was 1352 mg/L and the removal was 96 % at HRT 60 days, while in TPAMP, 927 mg/L and 98% at HRT 30 days.

하이퍼써미아 응용을 위한 하이브리드 에어로젤 내 분산된 마그네타이트 나노입자 (Magnetite Nanoparticles Dispersed in Hybrid Aerogel for Hyperthermia Application)

  • 이은희;좌용호;김창열
    • 한국재료학회지
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    • 제22권7호
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    • pp.362-367
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    • 2012
  • Magnetite nanoparticles(NPs) have been the subject of much interest by researchers owing to their potential use as magnetic carriers in drug targeting and as a tumor treatment in cases of hyperthermia. However, magnetite nanoparticles with 10 nm in diameter easily aggregate and thus create large secondary particles. To disperse magnetite nanoparticles, this study proposes the infiltration of magnetite nanoparticles into hybrid silica aerogels. The feasible dispersion of magnetite is necessary to target tumor cells and to treat hyperthermia. Magnetite NPs have been synthesized by coprecipitation, hydrothermal and thermal decomposition methods. In particular, monodisperse magnetite NPs are known to be produced by the thermal decomposition of iron oleate. In this study, we thermally decomposed iron acetylacetonate in the presence of oleic acid, oleylamine and 1,2 hexadecanediol. We also attempted to disperse magnetite NPs within a mesoporous aerogels. Methyltriethoxysilicate(MTEOS)-based hybrid silica aerogels were synthesized by a supercritical drying method. To incorporate the magnetite nanoparticles into the hybrid aerogels, we devised two methods: adding the synthesized aerogel into a magnetite precursor solution followed by nucleation and crystal growth within the pores of the aerogels, and the infiltration of magnetite nanoparticles synthesized beforehand into aerogel matrices by immersing the aerogels in a magnetite nanoparticle colloid solution. An analysis using a vibrating sample magnetometer showed that approximately 20% of the magnetite nanoparticles were well dispersed in the aerogels. The composite samples showed that heating under an inductive magnetic field to a temperature of $45^{\circ}C$ is possible.