• Corrosion Science and Technology
• /
• 제7권6호
• /
• pp.324-327
• /
• 2008

Stainless steels have been widely used as a building exterior materials in Asian countries for the last decade. It is required for the materials in this field to have an aesthetic appearance, a relatively high strength, and an excellent corrosion resistance. Other metallic materials such as copper, aluminum, and carbon steels have been also used as the exterior materials. Considering the cost of maintenance, stainless steel, having the outstanding corrosion resistance, is replacing other materials in the several parts in the building exteriors. Ferritic stainless steel has been applied as the roofing materials because its thermal expansion is much smaller than that of austenitic stainless steel. Therefore, it is suitable for the large-scale construction such as airport terminal, convention center, and football stadium. To improve the corrosion resistance of the ferritic stainless steels, the modification of alloy composition has been studied to develop new grade materials and the progress in the surface technology has been introduced. Corrosion properties of these materials were evaluated in the laboratory and in the field for longer than two years. High-Cr ferritic stainless steel showed excellent corrosion resistance to the atmospheric environments. In the region close to the sea, the corrosion resistance of high-Cr ferritic stainless steel was much superior to that of other materials, which may prove this steel to be the appropriate materials for the construction around seashore. In some of the large constructions around seashore in South Korea, high-Cr ferritic stainless steels have been used as the building exterior materials for six years.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2003년도 추계 학술대회논문집
• /
• pp.144-151
• /
• 2003

Computations of the mean and turbulence flows over three-dimensional hill of conical shape have implemented. Beside the standard $\kappa-\epsilon$, two other modifications proposed by Detering & Etling and Duynkerke for atmospheric applications were also considered. These predictions were compared with the data of a wind tunnel experiment. From the comparison, it was concluded that all three models predict the mean flow velocities equally well while only the Duynkerke's model accurately predicts the turbulence data statistics. It also concluded that there are large discrepancies between model predictions and the measurements near the ground surface. The flow field, which was obtained by using the Duynkerke's modification, was used to simulate gas dispersion from an upwind source. The calculation results are verified based on the measurement data. Modifications of the turbulent Schmidt number were carried out in order to match the measured results. The code was used to investigate the influence of the recirculation zone behind a building of cubical shape on the transport and dispersion of pollutant. For a stack behind and near the obstacle, some conclusions about the effect of the stack height and stack location were derive

• Wind and Structures
• /
• 제22권5호
• /
• pp.573-594
• /
• 2016

Simultaneous pressure measurements on 2D square prisms with various corner modifications were performed in uniform flow with low turbulence level, and the testing Reynolds numbers varied from $1.0{\times}10^5$ to $4.8{\times}10^5$. Experimental models were a square prism, three chamfered-corner square prisms (B/D=5%, 10%, and 15%, where B is the chamfered corner dimension and D is the cross-sectional dimension), and six rounded-corner square prisms (R/D =5%, 10%, 15%, 20%, 30%, and 40%, where R is the corner radius). Experimental results of drag coefficients, wind pressure distributions, power spectra of aerodynamic force coefficients, and Strouhal numbers are presented. Ten models are divided into various categories according to the variations of mean drag coefficients with Reynolds number. The mean drag coefficients of models with $B/D{\leq}15%$ and $R/D{\leq}15%$ are unaffected by the Reynolds number. On the contrary, the mean drag coefficients of models with R/D=20%, 30%, and 40% are obviously dependent on Reynolds number. Wind pressure distributions around each model are analyzed according to the categorized results.The influence mechanisms of corner modifications on the aerodynamic characteristics of the square prism are revealed from the perspective of flow around the model, which can be obtained by analyzing the local pressures acting on the model surface.

• Membrane and Water Treatment
• /
• 제6권3호
• /
• pp.173-187
• /
• 2015

The goal of present work is the preparation of a novel positively charged nanofiltration (NF) membrane and its development for the cation removal of aqueous solutions. This NF membrane was fabricated by the surface modification of polysulfone (PSf) ultrafiltration support. The active top-layer was formed by interfacial cross-linking polymerization of poly(ethyleneimine) (PEI) with p-xylylene dichloride (XDC) and then quaternized with methyl iodide to form a perpetually positively charged layer. In order to improve the efficiency of nanofiltration membrane, the concentration of PEI, XDC and methyl iodide solutions, PEI coating and cross-linking time have been optimized. As a result, a high water flux and high $CaCl_2$ rejection (1,000 ppm) was obtained for the composite membrane with values of $18.29L/m^2.h$ and 93.62% at 4 bar and $25^{\circ}C$, respectively. The rejections of NF membrane for different salt solutions followed the order of $Na_2SO_4$ < $MgSO_4$ < NaCl < $CaCl_2$. Molecular weight of cut off (MWCO) was calculated via retaining of PEG solutions with different molecular weights that finally, it revealed the Stokes and hydrodynamic radius of 1.457 and 2.507 nm on the membrane selective layer, respectively. The most efficient positively charged nanofiltration membrane exhibited a $Ni^{2+}$ rejection of 96.26% for industrial wastewater from Shamse Hadaf Co. (Kashan, Iran).

• Steel and Composite Structures
• /
• 제12권1호
• /
• pp.53-72
• /
• 2012

In this study, the physically-based failure models for matrix and fibers in compression and tension loading are introduced. For the 3D stress based fiber kinking model a modification is proposed for calculation of the fiber misalignment angle. All of these models are implemented into the finite element code by using the advantage of damage variable and the numerical results are discussed. To investigate the matrix failure model, purely in-plane transverse compression experiments are carried out on the specimens made by Glass/Epoxy to obtain the fracture surface angle and then a comparison is made with the calculated numerical results. Furthermore, shear failure of $({\pm}45)_s$ model is investigated and the obtained numerical results are discussed and compared with available experimental results. Some experiments are also carried out on the woven laminated composites to investigate the fracture pattern in the matrix failure mode and shown that the presented matrix failure model can be used for the woven composites. Finally, the obtained numerical results for stress based fiber kinking model and improved ones (strain based model) are discussed and compared with each other and with the available results. The results show that these models can predict the kink band angle approximately.

• 한국생산제조학회지
• /
• 제25권4호
• /
• pp.245-252
• /
• 2016

Girth gears are applied in the mining, cement, and mineral processing industries and used in various types of horizontal mills, rotary dryers and kilns, and other heavy-gear ring applications. The large ring gears are normally fitted outside mills or kilns to provide the primary rotational drive. Recently, an external pinwheel gear set (e-PGS) was introduced to overcome manufacturing problems associated with girth gears. e-PGS is also suitable for low-speed, heavy-duty mechanical transmission and dusty and poor-lubrication conditions. This paper first presents a new profile modification of root relief for the e-PGS cam pinion. We then investigate load-stress factors to estimate the surface fatigue life by varying the shape design parameters. The results show that the contact fatigue life of an e-PGS can be extended significantly by increasing the profile shift coefficient. However, support bearing life of the pinwheel depends more on the contact force distribution than the profile shift coefficient.

• Bulletin of the Korean Chemical Society
• /
• 제31권12호
• /
• pp.3679-3683
• /
• 2010

Niobium oxide ($Nb_2O_5$) and phosphated $Nb_2O_5$ were synthesized and used as catalysts for sorbitol dehydration to isosorbide. The characterization results of $N_2$ adsorption, XRD and $NH_3$-TPD revealed that the phosphoric acid modification could well prevent the crystallization of $Nb_2O_5$. And the amorphous phosphated $Nb_2O_5$ catalysts kept the relatively large surface area and stable acidity at high calcination temperature. The catalytic results showed that the selectivity to isosorbide could be dramatically enhanced over phosphated $Nb_2O_5$. The excellent catalytic performance with 100.0% sorbitol conversion and 62.5% isosorbide selectivity were obtained over the 0.8P/NBO-400 catalyst. Comparing with $Nb_2O_5$ catalysts, phosphated $Nb_2O_5$ catalysts regenerated through a simple calcination process showed no significant activity loss after recycling three runs.

• Bulletin of the Korean Chemical Society
• /
• 제28권11호
• /
• pp.1996-2002
• /
• 2007

The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.

• 한국전산구조공학회논문집
• /
• 제14권3호
• /
• pp.381-390
• /
• 2001

본 연구에서는 균열의 특이성과 불연속성을 Element-Free Galerkin(EFG) 법에 반영하기 위해 특이기저함수를 포함하는 확장항을 기존의 EFG 근사함수에 추가하고 균열면을 가로지르는 형상함수 구성시 불연속함수를 적용한 향상된 EFG 균열해석기법을 제안하였다. 기존의 EFG법이 균열선단주변의 특이응력장을 표현하기 위해 상당한 절점추가를 필요로 하지만 본 연구에서 제안한 기법은 절점의 추가나 해석모형의 수정이 필요 없다. 또한, 기존의 확장근사함수를 사용하는 EFG법이 계방정식의 크기를 상당히 증가시키는데 반해, 개선된 EFG 균열해석기법은 확장근사함수를 적용범위를 국소영역으로 제한하여 계방정식의 크기증가를 최소화하고서도 정도 높은 수치해를 얻었다. 수치예제는 제안된 기법의 향상된 면모와 효율성을 검증하여 준다.

• Membrane and Water Treatment
• /
• 제2권4호
• /
• pp.207-223
• /
• 2011

Supported Liquid Membranes (SLMs) have been widely studied as feasible alternative to traditional processes for separation and purification of various chemicals both from aqueous and organic matrices. This technique offers various advantages like active transport, possibility to use expensive extractants, high selectivity, low energy requirements and minimization of chemical additives. SLMs are not yet used at large scale in industrial applications, because of the low stability. In the present paper, after a brief overview of the state of the art of SLM technology the facilitated transport mechanisms of SLM based separation is described, also introducing the small and the big carrousel models, which are employed for transport modeling. The main operating parameters (selectivity, flux and permeability) are introduced. The problems related to system stabilization are also discussed, giving particular attention to the influence of membrane materials (solid membrane support and organic liquid membrane (LM) phase). Various approaches proposed in literature to enhance SLM stability are also reviewed. Modification of the solid membrane support, creating an additional layer on membrane surface, which acts as a barrier to LM phase loss, increases system stability, but the membrane permeability, and then the flux, decrease. Stagnant Sandwich Liquid Membrane (SSwLM), an implementation of the SLM system, results in both high flux and stability compared to SLM. Finally, possible large scale applications of SLMs are also reviewed, evidencing that if the LM separation process is opportunely carried out (no production of byproducts), it can be considered as a green process.