• Title/Summary/Keyword: Surface modification

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Integrated Process for Development of an Optimal Axial Flow Fan (Design, RP, Measurement, Injection Molding, Assembly) (최적 축류팬 개발을 위한 통합공정 (설계, 시제품제작, 측정, 금형가공, 사출, 조립))

  • 박성관;최동규
    • Korean Journal of Computational Design and Engineering
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    • v.3 no.3
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    • pp.201-209
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    • 1998
  • To develop timely an optimal fan, a design system and a new manufacturing process used step by step have to be integrated. A small sized optimal fan for refrigerators, that was the goal on this project, was developed by the following principal processes. All processes are technologically linked in many directions: The existing fan was measured through reverse engineering. The measured data was used for the basic source of 3D design. The performance tests were carried and used as the data for the evaluation of the existing fan. Flow analysis by FANS-3D/sup [1]/ was performed at the given information (pressure drop and flow rate) to find out the configuration of optimal fan design. The flow patterns were investigated to measure the performance of fan through numerical experiment. The grid point data obtained by the above analysis turned into 3D high efficiency fan model by using CATIA. The product was manufactured by RP process (SLS, SLA) and tested the characteristic curves of the developed fan to compare with the existing fan. The modification of fan design were all examined to see any change in performance and checked to find any deficiency in assembling the fan into a duct. After the plastics flow analysis of the injection molding cycle to ensure acceptable quality fan, an optimal mold was processed by using tool-path for the newly designed fan.

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A Numerical Study on the Formation Mechanism of a Mesoscale Low during East-Asia Winter Monsoon

  • Koo, Hyun-Suk;Kim, Hae-Dong;Kang, Sung-Dae;Shin, Dong-Wook
    • Journal of the Korean earth science society
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    • v.28 no.5
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    • pp.613-619
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    • 2007
  • Mesoscale low is often observed over the downstream region of the East Sea (or, northwest coast off the Japan Islands) during East-Asia winter monsoon. The low system causes a heavy snowfall at the region. A series of numerical experiments were conducted with the aid of a regional model (MM5 ver. 3.5) to examine the formation mechanism of the mesoscale low. The following results were obtained: 1) A well-developed mesoscale low was simulated by the regional model under real topography, NCEP reanalysis, and OISST; 2) The mesoscale low was simulated under a zonally averaged SST without topography. This implies that the meridional gradient of SST is the main factor in the formation of a mesoscale low; 3) A thermal contrast ($>10^{\circ}C$) of land-sea and topography-induced disturbance served as the second important factor for the formation; 4) Paektu Mountain caused the surface wind to decelerate downstream, which created a more favorable environment for thermodynamic modification than that was found in a flat topography; and 5) The types of cumulus parameterizations did not affect the development of the mesoscale low.

Poly-3,4-dihydroxybenzaldehyde Modified with 3,4-dihydroxybenzoic acid for Improvement of Electrochemical Activities

  • Cha Seong-Keuck
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.167-172
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    • 2004
  • 3,4-dihydroxybenzaldehyde(3,4-DHB) was oxidatively el electropolymerized on glassy carbon (GC) electrodes to prepare CC/p-3,4-DHB type electrodes, which were subsequently modified with 3,4-dihydroxybenzoic acid(3,4-DHBA) using 0.05M HCI as a catalyst. The esterification reactions were performed between -OH sites on the polymeric film surface of the p-3,4-DHB and the -COOH sites within the 3,4-DHBA molecules in solution. These reactions had a rate constant value of $1.1\times10^{-1}\;s^{-1}$ for the esterification step as obtained from the first-order rate constant in the solution. The electrochemical responses of the GC/p-3,4-DHB-3,4-DHBA electrodes exert an influence upon the buffer solution, its pH and applied potential ranges. The redox process of the electrode was more easily controlled by charge transfer kinetics than that of the CC/p-3,4-DHB. The modified electrodes had redox active sites that were 10 times more active than those present before modification. The electrical admittance of the modified electrodes was also three times higher than that of the unmodified electrodes. After being annealed in ethanol for 20 hrs the electrodes brought about a 3.3 times greater change of water molecules in the redox reaction. The modified electrodes are stable in the potential range of 0.4 to 0.55V.

Raman spectroscopy study on the reactions of UV-generated oxygen atoms with single-layer graphene on SiO2/Si substrates

  • Ahn, Gwang-Hyun;Kim, Hye-Ri;Hong, Byung-Hee;Ryu, Sun-Min
    • Carbon letters
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    • v.13 no.1
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    • pp.34-38
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    • 2012
  • Successful application of graphene requires development of various tools for its chemical modification. In this paper, we present a Raman spectroscopic investigation of the effects of UV light on single layer graphene with and without the presence of $O_2$ molecules. The UV emission from a low pressure Hg lamp photolyzes $O_2$ molecules into O atoms, which are known to form epoxy on the basal plane of graphene. The resulting surface epoxy groups were identified by the disorder-related Raman D band. It was also found that adhesive residues present in the graphene samples prepared by micro-mechanical exfoliation using adhesive tape severely interfere with the O atom reaction with graphene. The UV-induced reaction was also successfully applied to chemical vapor deposition-grown graphene. Since the current method can be readily carried out in ambient air only with UV light, it will be useful in modifying the surfaces of graphene and related materials.

Functional Properties of Modified Low Density Lipoprotein and Degradation of Modified LDL by Human Monocyte-Macrophages

  • Kim, Tae-Woong;Park, Jae-Hoon;Park, Young-June;Son, Heung-Soon;Yang, Ki-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.3
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    • pp.362-370
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    • 1995
  • Human plasma low density lipoprotein(LDL) is the main carrier for cholesterol, and recent studies suggest the normal LDL can be readily oxidized by free radical and not interact with LDL receptor. Lipoprotein pariticles are consisted of lipid andprotein, and fatty acids of lipoproteins are prone to oxidation. LDL particles readily undergo oxidative modification by copper. From the results, oxidized LDL altered its biological properties. A marked increase in the electrophoretic mobility of LDl on agarose gel indicated that negative surface charge of the LDL particles was increased. Also, the results from the HPLC showed that oxidized LDL was degraded into several polypeptides nonenzymatically. Degradation tests which measured the amount of 5-IAF labelled oxidized LDL were carried out by monocyte and hepatocyte cell culture. Hepatocyte cell culture of modified LDL did not show consistent pattern. However, binding rate of modified LDL with HMDM(human monocyte derived macrophage) was enhanced with oxidation, but was retarded by addition of antioxidants(hyaluronic acid, vitamin A, vitamin E). Also comparisons of oxidized-LDL, acetyl-LDL and MDA-LDL showed significant differences in the chemical properteis and binding affinity to HMDM. Thus, modificaition of normal LDL altered its biological properties.

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Performance Evaluation of a Solar Tracking PV System with Photo Sensors (포토센서를 이용한 태양위치 추적기의 성능분석에 관한 연구)

  • Jeong, Byeong-Ho;Cho, Geum-Bae;Lee, Kang-Yeon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.5
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    • pp.67-73
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    • 2013
  • The conversion of solar radiation into electrical energy by Photo-Voltaic (PV) effect is a very promising technology, being clean, silent and reliable, with very small maintenance costs and small ecological impact. The output power produced by the PV panels depends strongly on the incident light radiation. The continuous modification of the sun-earth relative position determines a continuously changing of incident radiation on a fixed PV panel. The point of maximum received energy is reached when the direction of solar radiation is perpendicular on the panel surface. Thus an increase of the output energy of a given PV panel can be obtained by mounting the panel on a solar tracking device that follows the sun trajectory. Tracking systems that have two axes and follow the sun closely at all times during the day are currently the most popular. This paper presents research conducted into the performance of Solar tracking system with photosensors. The results show that an optimized dual-axis tracking system with photosensor performance and analysis. From the obtained results, it is seen that the sun tracking system improves the energy and energy efficiency of the PV panel.ti-junction CPV module promises to accelerate growth in photovoltaic power generation.

Development and Application of High-Cr Ferritic Stainless Steels as Building Exterior Materials

  • Kim, Yeong H.;Lee, Yong H.;Lee, Yong D.
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.324-327
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    • 2008
  • Stainless steels have been widely used as a building exterior materials in Asian countries for the last decade. It is required for the materials in this field to have an aesthetic appearance, a relatively high strength, and an excellent corrosion resistance. Other metallic materials such as copper, aluminum, and carbon steels have been also used as the exterior materials. Considering the cost of maintenance, stainless steel, having the outstanding corrosion resistance, is replacing other materials in the several parts in the building exteriors. Ferritic stainless steel has been applied as the roofing materials because its thermal expansion is much smaller than that of austenitic stainless steel. Therefore, it is suitable for the large-scale construction such as airport terminal, convention center, and football stadium. To improve the corrosion resistance of the ferritic stainless steels, the modification of alloy composition has been studied to develop new grade materials and the progress in the surface technology has been introduced. Corrosion properties of these materials were evaluated in the laboratory and in the field for longer than two years. High-Cr ferritic stainless steel showed excellent corrosion resistance to the atmospheric environments. In the region close to the sea, the corrosion resistance of high-Cr ferritic stainless steel was much superior to that of other materials, which may prove this steel to be the appropriate materials for the construction around seashore. In some of the large constructions around seashore in South Korea, high-Cr ferritic stainless steels have been used as the building exterior materials for six years.

Numerical Simulation of Air Flow and Gas Dispersion around Obstacles

  • Nguyen The-Duc;Duong Ngoc-Hai;Park Wam-Gyu
    • 한국전산유체공학회:학술대회논문집
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    • 2003.08a
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    • pp.144-151
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    • 2003
  • Computations of the mean and turbulence flows over three-dimensional hill of conical shape have implemented. Beside the standard $\kappa-\epsilon$, two other modifications proposed by Detering & Etling and Duynkerke for atmospheric applications were also considered. These predictions were compared with the data of a wind tunnel experiment. From the comparison, it was concluded that all three models predict the mean flow velocities equally well while only the Duynkerke's model accurately predicts the turbulence data statistics. It also concluded that there are large discrepancies between model predictions and the measurements near the ground surface. The flow field, which was obtained by using the Duynkerke's modification, was used to simulate gas dispersion from an upwind source. The calculation results are verified based on the measurement data. Modifications of the turbulent Schmidt number were carried out in order to match the measured results. The code was used to investigate the influence of the recirculation zone behind a building of cubical shape on the transport and dispersion of pollutant. For a stack behind and near the obstacle, some conclusions about the effect of the stack height and stack location were derive

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Experimental study on Re number effects on aerodynamic characteristics of 2D square prisms with corner modifications

  • Wang, Xinrong;Gu, Ming
    • Wind and Structures
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    • v.22 no.5
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    • pp.573-594
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    • 2016
  • Simultaneous pressure measurements on 2D square prisms with various corner modifications were performed in uniform flow with low turbulence level, and the testing Reynolds numbers varied from $1.0{\times}10^5$ to $4.8{\times}10^5$. Experimental models were a square prism, three chamfered-corner square prisms (B/D=5%, 10%, and 15%, where B is the chamfered corner dimension and D is the cross-sectional dimension), and six rounded-corner square prisms (R/D =5%, 10%, 15%, 20%, 30%, and 40%, where R is the corner radius). Experimental results of drag coefficients, wind pressure distributions, power spectra of aerodynamic force coefficients, and Strouhal numbers are presented. Ten models are divided into various categories according to the variations of mean drag coefficients with Reynolds number. The mean drag coefficients of models with $B/D{\leq}15%$ and $R/D{\leq}15%$ are unaffected by the Reynolds number. On the contrary, the mean drag coefficients of models with R/D=20%, 30%, and 40% are obviously dependent on Reynolds number. Wind pressure distributions around each model are analyzed according to the categorized results.The influence mechanisms of corner modifications on the aerodynamic characteristics of the square prism are revealed from the perspective of flow around the model, which can be obtained by analyzing the local pressures acting on the model surface.

Preparation of novel NF membrane via interfacial cross-linking polymerization

  • Lehi, Arash Yunessnia;Akbari, Ahmad;Soleimani, Hosna
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.173-187
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    • 2015
  • The goal of present work is the preparation of a novel positively charged nanofiltration (NF) membrane and its development for the cation removal of aqueous solutions. This NF membrane was fabricated by the surface modification of polysulfone (PSf) ultrafiltration support. The active top-layer was formed by interfacial cross-linking polymerization of poly(ethyleneimine) (PEI) with p-xylylene dichloride (XDC) and then quaternized with methyl iodide to form a perpetually positively charged layer. In order to improve the efficiency of nanofiltration membrane, the concentration of PEI, XDC and methyl iodide solutions, PEI coating and cross-linking time have been optimized. As a result, a high water flux and high $CaCl_2$ rejection (1,000 ppm) was obtained for the composite membrane with values of $18.29L/m^2.h$ and 93.62% at 4 bar and $25^{\circ}C$, respectively. The rejections of NF membrane for different salt solutions followed the order of $Na_2SO_4$ < $MgSO_4$ < NaCl < $CaCl_2$. Molecular weight of cut off (MWCO) was calculated via retaining of PEG solutions with different molecular weights that finally, it revealed the Stokes and hydrodynamic radius of 1.457 and 2.507 nm on the membrane selective layer, respectively. The most efficient positively charged nanofiltration membrane exhibited a $Ni^{2+}$ rejection of 96.26% for industrial wastewater from Shamse Hadaf Co. (Kashan, Iran).