• 한국표면공학회지
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• 제31권5호
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• pp.266-277
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• 1998

The effects of $H_2S$ gas ratio, temperature and time on the case depth, hardness, and sulfide and nitride formation on the surface of sulfnitrided SCM440 steel have been studied by micro-pulse plasma technique. The thickness of compound layer of sulfide and nitride increased with the increase of time, temperautre and $H_2S$ gas ratio. But surface hardness decreased with the increase of soft sulfide layer because the hard nitride layer formed beneath the sulfide. The thickness of sulfide layer was about 10$\mu\textrm{m}$ abpve 0.0088% of $H_2S$ gas. The highest surface hardness of the compound layer was Hv835 at $530^{\circ}C$, 1hr and 0.06% of $H_2S$ gas. X-ray diffraction indicated that the surface products were $Fe_{1_x}S$, $Fe_{2.5}N$ and $Fe_4N$. It was confirmed by EPMA that sulfide only existed in the surface.

• 대한치과기공학회지
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• 제27권1호
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• pp.73-78
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• 2005

The surface-reacted layer of titanium castings greatly affects their mechanical properties. This study analyzed the interfacial zone of Ti-20%Zr-5%Cr alloy castings obtained from phosphate bonded investment and examined the relationship between the surface-reacted layer and hardness. The Vickers hardness of cast disks were tested at 20$\mu m$ intervals from the surface to 120$\mu m$ in depth. The cross-section was observed metallurgically, and line profile of the reacted layer was conducted under the EDX. The surface-reacted layer of Ti-20%Zr-5%Cr alloy is showed a similar tendency to Ti-6%Al-4%V alloy in thickness, and also Si diffusion in multiple reacted layer of Ti-20%Zr-5%Cr alloy is less than cp Ti and similar to Ti-6%Al-4%V alloy. The Vickers hardness in the surface layer was greater than in the inner part, and the Vickers hardness of Ti-20%Zr-5%Cr alloy ranged 650 to 390 and cp Ti ranged 810 to 160, Ti-6%Al-4%V alloy ranged 710 to 530 respectively.

• 정보저장시스템학회논문집
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• 제4권1호
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• pp.13-18
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• 2008

Scratches are observed on a polymer cover-layer of near-field recording (NFR) media after a servo test with rotating disc. The scratches are formed by the collision of a solid immersion lens (SIL)-media. One of the possible ways to avoid the scratch problem is to coat a dielectric protective film on the polymer cover-layer which enhances the hardness of the surface. The surface with hard characteristics in the surface reduces the scratch problem in the cover-layer. Not only the mechanical properties but also the optical properties should be controlled. Specifically, the refractive index of the dielectric protective film should be matched with the polymer cover-layer not to lose light at the interface due to the difference of the refractive index. The refractive index of the dielectric film can be tailored by controlling process parameters during sputtering and matched with that of the polymer cover-layer.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2018년도 춘계학술대회 논문집
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• pp.43.1-43.1
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• 2018

Spatial distribution of binding state in depth direction is investigated in a hard skin layer on soft polydimethylsiloxane (PDMS) fabricated by Ar ion beam irradiations. The hard skin layer known as a silica-like homogenous layer was composed of two layers. Impinging Ar ions transfer energy to PDMS as a function of collisional energy transfer rate, which is the maximum at surface and decreases gradually as an ion penetrates. This formed the heterogeneous hard skin layer that consists of a top-most layer and an intermediate layer. XPS depth profiling showed the existence of the top-most layer and intermediate layer. In the top-most layer, scission and cross-linking were occurred simultaneously and Si-O bond showed dissociated status, SiOx (x = 1.25 - 1.5). Under the top-most layer, there was the intermediate layer in which cross-linking is mainly occurred and Si-O bond showed silica-like binding status, SiOx (x = 1.75 - 2). And theoretical analysis which calculates the collisional energy transfer and a displacement per atom explained the thickness variation of top-most layer according to Ar ion energy from 360 eV to 840 eV.

• Journal of Pharmaceutical Investigation
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• 제37권1호
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• pp.7-13
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• 2007

To produce stable polymer coating layer using the interaction between metal stent and polymer layer, Ahx-HSAB was synthesized by coupling 6-aminoheanoic acid (Ahx) with N-Hydroxy succinimidyl 4-azidobenzonate (HSAB) containing photo reactive group. Then, Ahx-HSAB was applied to self·assembled monolayer (SAM) on $TiO_2$-coated surface, since one end of Ahx-HSAB was carboxyl acid which was known to be able to interact with $TiO_2$ surface. That SAM layer was incubated in 1% polycaprolacton (PCL) solution and photoreacted by ultraviolet light (254 nm) to produce the chemical bond between SAM and polymer layer, followed by PCL polymer coating ({\sim}5\;{\mu}m$) by the method of spray coating. The surface change was investigated by measuring of contact angle of the surface. The contact angle values of stainless steel (SS) surface, $TiO_2$-coated surface, SAM layer by Ahx-HSAB, photoreacted surface with PCL and PCL layer by spray coating were 70.48${\pm}$1.89, 38.57${\pm}$3.31, 60.14${\pm}$2.21, 54.91${\pm}$2.70 and 56.47${\pm}$2.12, respectively. The stability of polymer layers was tested by incubation of PCL-coated plates in 0.1M PBS buffer (pH 7.4, 0.05%, Tween 80) with vigorous shaking (200 rpm). While the poiymer layer prepared by these processes showed the intact surface morphology over 3 days, the polymer layers prepared by spray coating of PCL onto SS plate (control 1) and $TiO_2$-coated SS plate (control 2) were Peeled off in 3 days. Thus, the polymer coating method using SAM and photoreaction seems to be a effective method to obtain the stable polymer layer onto SS surface.

• 한국정밀공학회지
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• 제11권5호
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• pp.153-160
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• 1994

In this study, residual stress and surface roughness were investigated experimentally to evaluate surface integrity on surface layer machined by CBN, ceramics and WC cutting tools. When machining difficult-to-cut material (hardened STD11 steel $H_{R}$C 60), residual stresses remaining in machined surface layer were mainly compressive. The increase of flank wear caused a shift of the compressive residual stress maximum to greater workpiece depths, but the changes did not penetrate the workpiece beneath a depth of 300 .mu. m. Surface roughness was influenced considerably by variations of the cutting speed and feed. In machining hard material, CBN and A1$_{2}$ $O_{3}$ ceramics cutting tool materials proved significantly superior to mixed ceramics A1$_{2}$ $O_{3}$-TiC and WC in evaluation of surface integrity.y.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2014년도 추계학술대회 논문집
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• pp.12-12
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• 2014

Atomic layer etching system를 이용하여 $MoS_2$를 layer by layer control를 하였다. 이 방법이 전통적인 에칭에 비해서 low damage 층간 식각이 가능하였다.

• 한국대기환경학회지
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• 제13권2호
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• pp.103-113
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• 1997

The research described in this paper was conducted to estimate the stability and heat budget in planetary boundary layer (PBL) at Kimhae. The upper air observation was carried out during period from 3 Februsry 1993 to 5 February 1993 at Kimhae. The surface observation data used the one during period from 1 April 1994 to 31 March 1995. The maximum height of inversion layer observed at Kimhae was 310 m. Destruction of the inversion was simultaneously occurred at the surface and the mid-layer (200 $\sim$ 300 m), however the origin of destruction is different each other. The surface inversion is destructed by surface heating owing to growing radiation in surface but disappearance of the mid-layer inversion is related to the upper cold air movement.

• Tribology and Lubricants
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• 제19권5호
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• pp.245-250
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• 2003

Water is known to playa crucial role on friction of moving parts in nanoscale contact. Little is, however, known about the tribological behavior of a solid surface that is covered with water adsorption layer. The objective of this study is to investigate the nanotribological behavior of the water layer in relation to water affinity of the surface and relative humidity. This paper presents an examination of the frictional behavior of water adsorption layer as 'confined liquid film'. It is shown that the friction is inversely proportional to the hydrophilicity of surface and relative humidity. On the other hand, friction of hydrophobic surface is not influenced by relative humidity. A model is proposed for the water-mediated contact in which it is shown that the water layer between two hydrophilic surfaces with high relative humidity behaves as a lubricant.

• International Journal of CAD/CAM
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• 제12권1호
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• pp.29-37
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• 2012

A new algorithm has been developed to construct surface from the contours having branches and the final smooth surface is obtained by the reversible Catmull-Clark subdivision. In branching, a particular layer has more than one contour that correspond with at least one contour at the adjacent layer. In the next step, three-dimensional composite curve is constructed from contours of a layer having correspondence with at least one contour at the adjacent layer by inserting points between them and joining the contours. The points are inserted in such a way that the geometric center of the contours should merge at the center of the contours at the adjacent layer. This process is repeated for all layers having branching problems. Polyhedra are constructed in the next step with the help of composite curves and the contours at adjacent layer. The required smooth surface is obtained in the proposed work by providing the level of smoothness.