• Title/Summary/Keyword: Surface fuel

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Fundamental Studies on the Manufactruring of prouse Electrode for Plosphoric Acid Fuel Cell. (인산형 연료전지의 다공성전극 제조에 관한 기초적연구)

  • 김영우;박정일;이주성
    • Journal of the Korean institute of surface engineering
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    • v.22 no.2
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    • pp.55-61
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    • 1989
  • A fuel cell which causes electrochemical ratio of conventional with oxygen consists of mainly there parts, such as electrolyte, fuel and oxidant electrode. IN this paper, most efforts were delivered to manufacturing PETE-bonded gas-diffusion electrode, and preparation methods of the porous electrodes has been discussd. A medio temperature, phosphoric acid fuel cell (PAFC) provided with fuel (hydrogen) and oxygen showed oxygen showed excellent performance characteristics with made electrodes. Performance data obtained from hydrgen-oxygen cell were presented to illustrate their properties. It was found that the optimum amounts of platinum in clectrode for hydrgen-oxygen PAFC were about 3mg/cm3 and the PTFE content of gas diffusion layer and catalyst layer were 25% and 15%, respectively.

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A Study on the Chamical and Physical Characteristics of Ultrasonic-Energy-Added Diesel Fuel (초음파 에너지 부가 지젤연료의 화학적, 물리적 특성에 관한 연구)

  • 최두석;윤면근;류정인
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.3
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    • pp.147-155
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    • 1996
  • This study investigated the characteristics of ultrasonic-energy-added diesel fuel. We compared the characteristics used H-NMR spectrum, FT-IR spectrum, viscosity and surface tension between conventional diesel fuel and ultrasonic-energy-added diesel fuel. The result are obtained as follow : We knew that ultrasonic energy result to reduce BI and weaken viscosity and surface tension. Also, the ultrasonic energy caused to reduce aromatics Ha and increase Alkanes Hγ. The effect of ultrasonic-energy-added dieselfuel was principally caused by change of chemical structures and a physical characteristics.

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Cathode Microstructure Control and Performance Improvement for Low Temperature Solid Oxide Fuel Cells (저온 고체산화물 연료전지용 공기극 미세구조 제어 및 성능개선)

  • Kang, Jung-Koo;Kim, Jin-Soo;Yoon, Sung-Pil
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.727-732
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    • 2007
  • In order to fabricate a highly performing cathode for low-temperature type solid oxide fuel cells working at below $700^{\circ}C$, electrode microstructure control and electrode polarization measurement were performed with an electronic conductor, $La_{0.8}Sr_{0.2}MnO_3$ (LSM) and a mixed conductor, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$(LSCF). For both cathode materials, when $Sm_{0.2}Ce_{0.8}O_2$ (SDC) buffer layer was formed between the cathode and yttria-stabilized zirconia (YSZ) electrolyte, interfacial reaction products were effectively prevented at the high temperature of cathode sintering and the electrode polarization was also reduced. Moreover, cathode polarization was greatly reduced by applying the SDC sol-gel coating on the cathode pore surface, which can increase triple phase boundary from the electrolyte interface to the electrode surface. For the LSCF cathode with the SDC buffer layer and modified by the SDC sol-gel coating on the cathode pore surface, the cathode resistance was as low as 0.11 ${\Omega}{\cdot}cm^2$ measured at $700^{\circ}C$ in air atmosphere.

A Study on the Atomization Characteristics of the Ultrasonic-Energy-Irradiation High Viscosity Biodiesel Blended Fuel (초음파 에너지 조사 고 점도 바이오디젤 혼합연료의 미립화 특성에 관한 연구)

  • Song Yong-Seek;Yang In-Kwon;Kim Bong-Seock;Ryu Jung-In
    • Journal of Energy Engineering
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    • v.13 no.4
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    • pp.235-241
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    • 2004
  • This experiment was undertaken to investigate the atomization characteristics of the high viscosity biodiesel blended fuel and ultrasonic energy irradiation one. Test fuels were conventional diesel fuel and biodiesel one. We compared to the characteristics of viscosity and surface tension, SMD between high viscosity biodiesel blended fuel and ultrasonic energy irradiation one. Sauter mean diameter was measured under the variation of the spray distance. Viscosity and surface tension were measured under the variation of the time trace. To measure the droplet size, we used the Malvern system 2600c. Droplet size distribution was analyzed from the result data of Malvern system. Through this experiment, we found that the condition of the ultrasonic energy irradiation situation had smaller Sauter mean diameter of droplet, viscosity and surface tension than those of the conventional situation.

Excellent Seam Weldable Nano-Composite Coated Zn-Ni Plating Steels for Automotive Fuel Tank

  • Jo, Du-Hwan;Yun, Sang-Man;Park, Kee-Cheol;Kim, Myung-Soo;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.18 no.1
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    • pp.16-23
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    • 2019
  • Steels for automotive fuel tank require unique properties such as corrosion resistance for fuel, welding for joining, forming for press, and painting for exterior. Recently, automakers have been requiring excellent seam weldable steels to enhance manufacturing productivity of fuel tank. Thus, POSCO developed a new type of functional steels coated with nano-composite thin layer on Zn-Ni plating steels. The nano-composite coating solution was prepared by mechanical fine dispersion of solutions consisting of polymeric resin and nano-composite materials in aqueous media. The composite solution was coated on the plating steel surface by using roll coater and cured through induction furnace. These new developed plating steels were evaluated for quality performances such as seam and spot weldability, press formability, and corrosion resistance. These new functional steels coated with nano-composite layer exhibited excellent seam weldability and press formability. Detailed discussion of coating solution and experimental results suggest that nano-sized composite dispersion as coating layer plays a key role in enhancing the quality performance.

Effects of anode surface area and methylene blue dye treatment on the power density of microbial fuel cell with sponge and carbon nano tube electrode (음극 전극 표면적과 메틸렌블루 염색이 스펀지 탄소나노 튜브 전극 미생물 연료전지의 전력수율에 미치는 영향)

  • Lee, Chae-Young;Park, Su-Hee;Song, Young-Chae;Woo, Jung-Hui;Yoo, Kyu-Seon;Chung, Jae-Woo;Han, Sun-Kee
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.883-888
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    • 2012
  • Anode electrode is one of the most important factors in microbial fuel cell (MFC). This study was conducted to investigate the effects of mediator as methylene blue (MB) and electrode surface area on the power density of MFC with sponge and carbon nano tube (CNT) electrode (SC). The SC electrode with MB (MC) showed the maximum power density increased from 74.0 $mW/m^2$ to 143.1 $mW/m^2$. The grid shaped sponge and CNT (GSC) electrode showed the maximum power density of 209.2 $mW/m^2$ due to the increase of surface area from 88.0 to 152.0 $cm^2$. The GSC electrode with MB (GMC) revealed the maximum power density of 384.9 $mW/m^2$ which was 5.2 times higher than that obtained from the MFC with SC. Therefore MB and increase of surface area led to enhance the performance of microbial fuel cell such as power density.

CFD Analysis on Two-phase Flow Behavior of Liquid Water in Cathode Channel of PEM Fuel Cell (PEM 연료전지 공기극 유로에서 물의 가동에 대한 CFD 해석)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.8-15
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    • 2007
  • Liquid water in flow channel is an important factor that limits the steady and transient performance of PEM fuel cells. A computational fluid dynamics study based on the volume-of-fluid [VOF] multi-phase model was conducted to understand the two-phase flow behavior of liquid water in cathode gas channels. The liquid water transport in $180^{\circ}{\Delta}$ bends was investigated, where the effects of surface characteristics (hydrophilic and hydrophobic surfaces], channel geometries (rectangular and chamfered corners], and air velocity in channel were discussed. The two-phase flow behavior of liquid water with hydrophilic channel surface and that with hydrophobic surface was found very different; liquid water preferentially flows along the corners of flow channel in hydrophilic channels while it flows in rather spherical shape in hydrophobic channels. The results showed that liquid water transport was generally enhanced when hydrophobic channel with rounded corners was used. However, the surface characteristics and channel geometries became less important when air velocity was increased over 10m/s. This study is believed to provide a useful guideline for design optimization of flow patterns or channel configurations of PEM fuel cells.

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The Numerical Analysis for the Surface Crack Behavior in the Planar Solid Oxide Fuel Cell (평판형 고체산화물 연료전지 표면균열거동에 관한 수치해석)

  • Park, Cheol Jun;Kwon, Oh Heon;Kang, Ji Woong
    • Journal of the Korean Society of Safety
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    • v.33 no.5
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    • pp.1-8
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    • 2018
  • A fuel cell is an energy conversion device that converts a chemical energy directly into an electrical energy and has higher energy efficiency than an internal combustion engine, but solid oxide fuel cell (SOFC) consisting of brittle ceramic material remains as a major issue regarding the mechanical properties as the crack formation and propagation. In this study, the stress distribution and crack behavior around the crack tip were evaluated, due to investigated the effects of the surface crack at the operating condition of high temperature. As a result, the difference of the generated stress was insignificant at operating conditions of high temperature according to the surface crack length changes. This is because, the high stiffness interconnect has a closed structure to suppress cell deformation about thermal expansion. The stress intensity factor ratio $K_{II}/K_I$ increased as the crack depth increased, at that time the effect of $K_{II}$ is larger than that of $K_I$. Also the maximum stress intensity factor increased as the crack depth increased, but the location of crack was generated at the electrolyte/anode interface, not at the crack tip.

The Study on Surface Fire Spread in Fuel Bed (Fuel Bed에서의 지표화 확산에 관한 연구)

  • Kim, Jeong-Hun;Kim, Eung-Sik;Kim, Dong-Hyun;Kim, Jang-Whan
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.22-27
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    • 2014
  • In this study a Fuel bed where surface fire spreads through is made to measure the data such as the flame height, radiation, spread rate and temperature distribution of Fuel bed. As experimental variables species of trees, wind velocities and slop are chosen. Fallen leaves of Quercus Variabilis (Q.V.) and Pinus Densiflora (P.D.) are used as fuel. Wind velocity is controlled by simply designed wind turnnel from 1 to 5 m/s. Slope of fuel bed is changed from $0^{\circ}$ to $30^{\circ}$. For the measurements of temperature distribution and spread rate total 35 of K-type 1.6 mm thermocouples are positioned as a lattice design. Radiant heat flow meters are used besides video camera and thermovision camera.

An Experimental Study on the Characteristics of Electrochemical Reactions of RDF/RPF in the Direct Carbon Fuel Cell (직접탄소 연료전지에서 RDF 및 RPF의 전기화학반응 특성에 관한 실험적 연구)

  • Ahn, Seong Yool;Rhie, Young Hoon;Eom, Seong Yong;Sung, Yeon Mo;Moon, Cheor Eon;Kang, Ki Joong;Choi, Gyung Min;Kim, Duck Jool
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.513-520
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    • 2012
  • The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.