• Journal of Energy Engineering
• /
• v.15 no.1 s.45
• /
• pp.8-13
• /
• 2006

The oxidation behavior of $UO_2$, pellet was studied using an XRD and a thermogravimetric analyzer in the temperature range from 573 to 873 K and in the density range from 94.64 to 99.10% of theoretical density in air. It was found from the XRD study that $UO_2$ was completely converted to $U_3O_8$ in this experimental temperature range. The formation of $U_3O_8$ displays sigmoidal reaction kinetics. The oxidation rate was reduced with density. Induction time for the oxidation of $UO_2$ was delayed with density because of open pore formed in surface of $UO_2$ pellet. The activation energy for oxidation of $UO_2$ was determined to be 89.54 kJ/mol and 34.40 kJ/mol in the temperature range from 573 to 723 K and from 723 to 873 K, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.34 no.11
• /
• pp.957-964
• /
• 2010

The deflagration-to-detonation transition (DDT) causes a strong pressure wave that can adversely affect surrounding structures. The pressure generated by multiple detonative pulses is strong enough to cause metal surface erosion and chipping of the edges of bulk structures. In this study, we investigate the damage caused by the DDT phenomenon and perform hydrocode simulations to evaluate the structural damage caused to a metallic pulverized-coal injector used in a pulverized-coal-oxygen combustion furnace. The experimental conditions are selected in order to accurately model the damage caused to metal injectors that are exposed to multiple DDT pulses.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.38 no.6
• /
• pp.629-636
• /
• 2014

For surface modification, bulk metallic glass coatings were fabricated using metallic glass powder and a mixture of a self-fluxing alloy or/and hard metal alloys with a heat-resisting property using a high velocity oxy-fuel coating thermal spraying process. Microstructural analyses and mechanical tests were carried out using X-ray diffraction, a scanning electron microscope, an atomic force microscope, a three-dimensional optical profiler, and nanoindenation. As a result, the monolithic metallic glass coating was found to consist of solid particle and lamellae regions that included many pores. Second phase-reinforced composite coatings with a self-fluxing alloy or/and hard metal alloy additives were employed with in-situ $Cr_2Ni_3$ precipitate or/and ex-situ WC particles in an amorphous matrix. The mechanical behaviors of the solid particles and lamella regions showed large hardness and elastic modulus differences. The mechanical properties of the particle regions in the metallic glass composite coatings were superior to those of the lamellae regions in the monolithic metallic glass coatings, but indicated similar trends in matrix region of all the coating layers.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.42 no.7
• /
• pp.616-621
• /
• 2014

Consumption of the fuel on the satellite operating in low earth orbit, is increased due to the air resistance and the amount of increase makes the satellite lifetime decrease or the satellite mass risen. Therefore the prediction of drag force of the satellite is important. In the paper, drag force and drag coefficient analysis of the parabolic antenna satellite in low earth orbit using direct simulation monte carlo method (DSMC) is conducted according to the mission altitude and angle of attack. To verify the DSMC simulated rarefied air movement, Starshine satellite drag coefficient according to the altitude and gas-surface interaction are compared with the flight data. Finally, from the analysis results, it leads to appropriate satellite drag coefficient for orbit lifetime calculation.

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.4
• /
• pp.439-445
• /
• 2008

Sawdust is considered one of the cheapest and abundantly available adsorbents, and it is not necessary to regenerate. The spent sawdust can be incinerated or reused as a fuel. The sawdust adsorption can be applied to the removal of color and metal cations from the wastewater. The aim of this study was to evaluate the adsorptive capacities of sawdust with respect to color, COD, SS, turbidity, metal cation from textile wastewater. Langmuir, Freundlich, BET and Sips adsorption isotherm were obtained for the sawdust adsorption of Fe(III). The effects of particle size and amount of sawdust on the adsorption of Fe(III) were also studied. COD, SS, color, turbidity and Fe(III) removal efficiencies were examined at the continuous fixed-bed adsorption test. It was showed the removal efficiencies of SS 50.0%, Fe(III) 25.0%, turbidity 79.4%, color 48.6% and COD 50.9%. In addition, the changes of surface structure between before and after adsorption were investigated through SEM analysis. It is confirmed that the waste sawdust can be successfully used as an adsorbent for wastewater treatment.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.15 no.1
• /
• pp.65-82
• /
• 2017

The result of a preliminary safety assessment that was completed by applying the radionuclide inventory calculated on the basis of available data from radioactive waste generation agencies suggested that many difficulties are to be expected with regard to disposal safety and operation. Based on the results of the preliminary safety assessment of the entire disposal system, in this paper, a unit package exceeding the safety goal is selected that occupies a large proportion of radionuclides in intermediate-level radioactive waste. We introduce restrictions on the amount of radioactivity in a way that excludes the high surface dose rate of the package. The radioactivity limit for disposal will be used as the baseline data for establishing the acceptance criteria and the disposal criteria for each disposal facility to meet the safety standards. It is necessary to draw up a comprehensive safety development plan for the Gyeongju waste disposal facility that will contribute to the construction of a Safety Case for the safety optimization of radioactive waste disposal facilities.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2004.02a
• /
• pp.220-237
• /
• 2004

China, as a developing country with a great number of population and relatively less energy resources, reasonably emphasizes the nuclear energy utilization development. For the long term sustainable energy supply, as for nuclear application the basic strategy of PWR-FBR-Fusion has been settled and envisaged. Due to the economy and experience reasons the nuclear power and technology development with a moderate style are kept in China up to now. In China mainland apart from two NPPs with the total capacity of 2.1 GWe in operation, four NPPs are under construction and two NPPs are planned for the Tenth Five Year Plan(2001-2005). Also another one or two NPPs are still in discussion. It could be foreseen that the total nuclear power capacity will reach 8.5GWe before the year 2005 and 14-15 GWe before 2010 respectively. As the first step for the Chinese fast reactor engineering development the 65MWt China Experimental Fast Reactor(CEFR) is under construction. The main components of primary, secondary and tertiary circuits and of fuel handling system have been ordered. The reactor building under construction has reached the top namely 57m above the ground. More than one hundred components and shielding doors have been installed. It is planned that the construction of reactor building with about 40,000$m^2$ floor surface will be completed in the end of the year 2002 and envisaged that the first criticality of the CEFR will be in the end of 2005. The second step of the Chinese fast reactor engineering development is a 300MWe Prototype Fast Breeder Reactor which is only under consideration up to now. Some important technical selections have been settled, but its design has not yet started.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.10 no.1
• /
• pp.55-62
• /
• 2012

As an alternative of the high-level radioactive waste disposal in the subsurface repository, a deep borehole disposal is reviewed by several nuclear advanced countries. In this study, the state of the art on the borehole disposal researches was reviewed, and the possibility of borehole disposal in Korean peninsula was discussed. In the deep borehole disposal concept radioactive waste is disposed at the section of 3 - 5km depth in a deep borehole, and it has known that it has advantages in performance and cost due to the layered structure of deep groundwater and small surface disposal facility. The results show that it is necessary to acquisite data on deep geologic conditions of Korean peninsula, and to research the engineering barrier system, numerical modeling tools and disposal techniques for deep borehole disposal.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.1
• /
• pp.63-68
• /
• 2018

This paper presents an integrated photochemical reaction system (i.e., an artificial leaf) that uses earth-abundant catalysts for artificial photosynthesis with a carbon dioxide ($CO_2$) fixation process. The performance of the system was investigated in terms of the energy capture and conversion capabilities. A wireless configuration was achieved by directly doping cobalt oxide as an oxygen-evolving catalyst for water splitting reaction on the illuminated surface of photovoltaic (PV) cell, as well as molybdenum disulfide ($MoS_2$) as an efficient catalyst for $CO_2$ reduction on the back substrate surfaces of the PV cell. The system produces hydrogen and carbon monoxide (CO) as sustainable fuels (i.e., synthesis gas) at around 4.5% efficiency, which implies more than 75% catalytic efficiency at the cathode. The process of solar-driven $CO_2$ conversion and water-splitting reaction is contained in one system, which is one step closer to the successful realization of artificial photosynthesis.

• Advances in environmental research
• /
• v.9 no.1
• /
• pp.65-84
• /
• 2020

The potential use of Sargassum boveanum algae for the removal of uranium from aqueous solution has been studied by varying three independent parameters (pH, initial uranium ion concentration, S. boveanum dosage) using a central composite design (CCD) under response surface methodology (RSM). Batch mode experiments were performed in 20 experimental runs to determine the maximum metal adsorption capacity. In CCD design, the quantitative relationship between different levels of these parameters and heavy metal uptake (q) were used to work out the optimized levels of these parameters. The analysis of variance (ANOVA) of the proposed quadratic model revealed that this model was highly significant (R² = 0.9940). The best set required 2.81 as initial pH(on the base of design of experiments method), 1.01 g/L S. boveanum and 418.92 mg/L uranium ion concentration within 180 min of contact time to show an optimum uranium uptake of 255 mg/g biomass. The biosorption process was also evaluated by Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models represented that the experimental data fitted to the Langmuir isotherm model of a suitable degree and showed the maximum uptake capacity of 500 mg/g. FTIR and scanning electron microscopy were used to characterize the biosorbent and implied that the functional groups (carboxyl, sulfate, carbonyl and amine) were responsible for the biosorption of uranium from aqueous solution. In conclusion, the present study showed that S. boveanum could be a promising biosorbent for the removal of uranium pollutants from aqueous solutions.