• Smart Structures and Systems
• /
• 제12권1호
• /
• pp.55-71
• /
• 2013

Structural health monitoring (SHM) is vital for detecting the onset of damage and for preventing catastrophic failure of civil infrastructure systems. In particular, piezoelectric transducers have the ability to excite and actively interrogate structures (e.g., using surface waves) while measuring their response for sensing and damage detection. In fact, piezoelectric transducers such as lead zirconate titanate (PZT) and poly(vinylidene fluoride) (PVDF) have been used for various laboratory/field tests and possess significant advantages as compared to visual inspection and vibration-based methods, to name a few. However, PZTs are inherently brittle, and PVDF films do not possess high piezoelectricity, thereby limiting each of these devices to certain specific applications. The objective of this study is to design, characterize, and validate piezoelectric nanocomposites consisting of zinc oxide (ZnO) nanoparticles assembled in a PVDF copolymer matrix for sensing and SHM applications. These films provide greater mechanical flexibility as compared to PZTs, yet possess enhanced piezoelectricity as compared to pristine PVDF copolymers. This study started with spin coating dispersed ZnO- and PVDF-TrFE-based solutions to fabricate the piezoelectric nanocomposites. The concentration of ZnO nanoparticles was varied from 0 to 20 wt.% (in 5 % increments) to determine their influence on bulk film piezoelectricity. Second, their electric polarization responses were obtained for quantifying thin film remnant polarization, which is directly correlated to piezoelectricity. Based on these results, the films were poled (at 50 $MV-m^{-1}$) to permanently align their electrical domains and to enhance their bulk film piezoelectricity. Then, a series of hammer impact tests were conducted, and the voltage generated by poled ZnO-based thin films was compared to commercially poled PVDF copolymer thin films. The hammer impact tests showed comparable results between the prototype and commercial samples, and increasing ZnO content provided enhanced piezoelectric performance. Lastly, the films were further validated for sensing using different energy levels of hammer impact, different distances between the impact locations and the film electrodes, and cantilever free vibration testing for dynamic strain sensing.

• Carbon letters
• /
• 제22권
• /
• pp.48-59
• /
• 2017

This study synthesized pure anatase carbon doped $TiO_2$ photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/$TiCl_4$. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported $TiO_2$ nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results complemented one another and confirmed the presence of carbon species in or on the $TiO_2$ layer, and the XPS data suggested the substitution of titanium in $TiO_2$ by carbon. Instead of using calcination, PAN pyrolysis was used to control the carbon content, and the mesoporosity was tailored by the applied temperature. The supported $TiO_2$ nanocrystals prepared by pyrolysis at 300, 350, and $400^{\circ}C$ for 3 h on a stainless steel mesh were actual supported carbon doped $TiO_2$ nanocrystals. Thus, $PAN/DMF/TiCl_4$ offers a facile, robust sol-gel related route for preparing supported carbon doped $TiO_2$ nanocomposites.

• International Journal of Naval Architecture and Ocean Engineering
• /
• 제10권5호
• /
• pp.545-565
• /
• 2018

A numerical code is developed based on potential flow theory to investigate nonlinear sloshing in rectangular Liquefied Natural Gas (LNG) tanks under forced excitation. Using this code, internal free-surface elevation and sloshing loads on liquid tanks can be obtained both in time domain and frequency domain. In the mathematical model, acceleration potential is solved in the calculation of pressure on tanks and the artificial damping model is adopted to account for energy dissipation during sloshing. The Boundary Element Method (BEM) is used to solve boundary value problems of both velocity potential and acceleration potential. Numerical calculation results are compared with published results to determine the efficiency and accuracy of the numerical code. Sloshing properties in partially filled rectangular and membrane tank under translational and rotational excitations are investigated. It is found that sloshing under horizontal and rotational excitations share similar properties. The first resonant mode and excitation frequency are the dominant response frequencies. Resonant sloshing will be excited when vertical excitation lies in the instability region. For liquid tank under rotational excitation, sloshing responses including amplitude and phase are sensitive to the location of the center of rotation. Moreover, experimental tests were conducted to analyze viscous effects on sloshing and to validate the feasibility of artificial damping models. The results show that the artificial damping model with modifying wall boundary conditions has better applicability in simulating sloshing under different fill levels and excitations.

• BMB Reports
• /
• 제40권4호
• /
• pp.453-458
• /
• 2007

Bacterial luciferase is a heterodimeric enzyme, which catalyzes the light emission reaction, utilizing reduced FMN (FMNH2), a long chain aliphatic aldehyde and $O_2$, to produce green-blue light. This enzyme can be readily classed as slow or fast decay based on their rate of luminescence decay in a single turnover. Mutation of Glu175 in $\alpha$ subunit to Gly converted slow decay Xenorhabdus Luminescence luciferase to fast decay one. The following studies revealed that changing the luciferase flexibility and lake of Glu-flavin interactions are responsible for the unusual kinetic properties of mutant enzyme. Optical and thermodynamics studies have caused a decrease in free energy and anisotropy of mutant enzyme. Moreover, the role of Glu175 in transition state of folding pathway by use of stopped-flow fluorescence technique has been studied which suggesting that Glu175 is not involved in transition state of folding and appears as surface residue of the nucleus or as a member of one of a few alternative folding nuclei. These results suggest that mutation of Glu175 to Gly extended the structure of Xenorhabdus Luminescence luciferase, locally.

• 대한기계학회논문집B
• /
• 제26권8호
• /
• pp.1153-1163
• /
• 2002

A transient analysis on temperatures of fuel and oil in hydraulic and lubrication systems in an aircraft was studied using the finite difference method. Numerical calculation was performed by an explicit method with modified Dufort-Frankel scheme. Among various missions, air superiority mission was considered as a mission model with 20% hot day ambient condition in subsonic region. The ambience of the aircraft was assumed as turbulent flow. Convective heat transfer coefficient were used in calculating heat transfer between the aircraft surface and the ambience. For an aircraft on the ground, an empirical equation represented as a function of free-stream air velocity was used. And the heat transfer coefficient for flat plate turbulent flow suggested by Eckert was employed for in-flight phases. The governing equations used in this analysis are the mass and energy conservation equations on fuel and oils. Here, analysis of fuel and oil temperature in the engine was not carried out. As a result of this analysis, the ground operation phase has shown the highest temperature and the largest rate of temperature increase among overall mission phases. Also, it is shown that fuel flow rate through fuel/oil heat exchanger plays an important role in temperature change of fuel and oil. This analysis could be an important part of studies to ensure thermal stability of the aircraft and can be applicable to thermal design of the aircraft fuel system.

• Macromolecular Research
• /
• 제12권2호
• /
• pp.172-177
• /
• 2004

We have studied the lamella-level morphology of poly(ethylene terephthalate) (PET)/polycarbonate (PC) blends using small-angle X-ray scattering (SAXS). Measurements were made as a function of the holding time in the melt. We determined the morphological parameters at the lamellar level by correlation function analysis of the SAXS data. An increased amorphous layer thickness was identified in the blend, indicating that some PC was incorporated into the interlamellar regions of PET during crystallization. The blend also exhibits a larger lamella crystalline thickness (l$\sub$c/) than that of pure PET. A possible reason for the increase in l$\sub$c/ is that the inclusion of the PC molecules in the interlamellar regions causes an increase in the surface free energy of folding. At the early stage of isothermal crystallization, we observed a rapid drop in the value of l$\sub$c/ in the blend; this finding indicates that a relatively large fraction of secondary crystals form during the primary crystallization. In contrast, the value of l$\sub$c/ for the sample that underwent a prolonged holding time increased with time in the secondary crystallization-dominant regime; this observation suggests that the disruption of chain periodicity, which results from transesterification between the two polymers, favors the development of fringed micellar crystals that have larger values of l$\sub$c/ rather than the development of normal chain-folded crystals.

• 한국항해항만학회지
• /
• 제31권8호
• /
• pp.683-687
• /
• 2007

초대형 부체구조물은 파랑중 유탄성 변형이 심하게 발생하기 때문에 수평식 몰수평판과 같은 파랑에너지 흡수장치의 부가적인 개발이 요구된다. 본 연구에서는 몰수평판에 의해 야기되는 유체력 간섭현상이 폰툰형 부체구조물에 작용하는 라디에이션 유체력에 어떠한 영향을 미치는지 수치적인 해석을 통하여 그 특성을 파악하고자 한다. 폰툰형 부체구조물과 몰수평판의 상하운동에 의해 발생하는 라디에이션 유체력을 계산하기 위해 고정격자계와 이동격자계로 구성되는 중합격자법을 토대로 한 수치계산법을 개발한다. 또한 쇄파현상과 같은 비선형성이 강한 자유표면 문제를 해결하기 위하여 유한차분법을 적용하여 시뮬레이션을 실시하고 그 결과를 실험데이터와 비교함으로서 수치계산법의 신뢰성을 확인한다. 몰수평판에 의해 발생하는 유체력 간섭 영향의 특성을 분석하여 부체구조물의 파랑중 유탄성 변형에 미치는 그 효과에 대하여 논의한다.

• Korean Chemical Engineering Research
• /
• 제52권2호
• /
• pp.205-208
• /
• 2014

본 논문에서는 유기전자소자의 반도체 물질로 많이 사용되는 poly(9,9-dioctylflurorene) (PFO), poly(9,9-dioctylfluorene-co-benthiadiazole) (F8BT), (regioregular poly(3-hexylthiophene) (P3HT)를 기반으로 하는 균일한 크기와 특성을 가지는 고분자 나노와이어를 AAO 템플레이트를 이용하여 대량으로 제작하였다. 제작된 나노와이어는 결점이 없이 깨끗한 표면을 보였으며, 약 250~300 nm의 지름과 ${\sim}30{\mu}m$의 일정한 길이를 가지고 있었다. 나노와이어들은 스프레이 분사 방법을 통하여 유리 기판 위에 균일하게 분사할 수 있었으며, PFO와 F8BT 나노와이어의 경우 UV 빛의 조사하에 각각 나노와이어의 전체에 걸쳐서 왜곡없이 밝은 yellow와 blue luminescence를 보였다.

• 한국마린엔지니어링학회:학술대회논문집
• /
• 한국마린엔지니어링학회 2005년도 후기학술대회논문집
• /
• pp.156-157
• /
• 2005

Gas hydrate is ice-like crystalline lattice, formed at appropriate temperature and pressure, in which gas molecules are trapped. It is worldwide popular interesting subject as a potential energy. In korea, a seismic survey for gas hydrate have performed over the East sea by the KIGAM since 1997. In this paper, we had conducted numerical and physical modeling experiments for seismic properties on gas hydrate with field data which had been acquired over the East sea in 1998. We used a finite difference seismic method with staggered grid for 2-D elastic wave equation to generate synthetic seismograms from multi-channel surface seismic survey, OBC(Ocean Bottom Cable) and VSP(Vertical Seismic Profiling). We developed the seismic physical modeling system which is simulated in the deep sea conditions and acquired the physical model data to the various source-receiver geometry. We carried out seismic complex analysis with the obtained data. In numerical and physical modeling data, we observed the phase reversal phenomenon of reflection wave at interface between the gas hydrate and free gas. In seismic physical modeling, seismic properties of the modeling material agree with the seismic velocity estimated from the travel time of reflection events. We could easily find out AVO(Amplitude Versus Offset) in the reflection strength profile through seismic complex analysis.

• 한국응용과학기술학회지
• /
• 제7권1호
• /
• pp.13-24
• /
• 1990

2-N,N,N-trimethyl ammonia decanoate, 2-N,N,N-trimethyl ammonio dodecanoate, 2-N,N,N-trimethyl ammonia tetradecanoate and 2-N,N,N-hexadecanoate with in straight long chain alkyl carboxybetaines, and N-decyl N,N-dimethyl ammonio ethanoate, N-dodecyl N,N-dimethyl ammonia ethanoate, N-tetradecyl N,N-dimethyl ammonia ethanoate and N-hexadecyl N,N-dimethyl ammonia ethanoate with in nitrogen-straight long chain alkyl carboxy betaines measured respectively surface tensions by the stalagmometer method at various temperature, also their critical micelle concentration were evaluated. In micellization, the contribution of standard free energy change(${\Delta}G^{\circ}m$), standard enthalpy change(${\Delta}H^{\circ}m$) and standard entropy change (${\Delta}S^{\circ}m$), have been calculated, with increasing temperature. ${\Delta}H^{\circ}m$ changes from negative, and a similar change in the sign of ${\Delta}H^{\circ}m$ is observed with increasing chain length at $25^{\circ}C$, while the entropy of micellization, ${\Delta}S^{\circ}m$ is positive over the temperature range studied, it becomes less so at higher temperatures. Estimates of the enthalpy and entropy contribution attributable to the ion head group and alkyl chain have been made. The enthalpy and entropy change, per methylene group increase respectively with increasing chain length the result are discussed in terms of current theories of micellization.