• 제목/요약/키워드: Surface free energy

검색결과 636건 처리시간 0.027초

Nonlocal effects on propagation of waves in a generalized thermoelastic solid half space

  • Singh, Baljeet;Bijarnia, Rupender
    • Structural Engineering and Mechanics
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    • 제77권4호
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    • pp.473-479
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    • 2021
  • The propagation of plane waves in a linear, homogeneous and isotropic nonlocal generalized thermoelastic solid medium is considered in the framework of Lord and Shulman generalization. The governing field equations are formulated and specialized in a plane. Plane wave solutions of governing equations show that there exists three plane waves, namely, P, thermal and SV waves which propagate with distinct speeds. Reflection of P and SV waves from thermally insulated or isothermal boundary of a half-space is considered. The relevant boundary conditions are applied at stress free boundary and a non-homogeneous system of three equations in reflection coefficients is obtained. For incidence of both P and SV waves, the expressions for energy ratios of reflected P, thermal and SV waves are also obtained. The speeds and energy ratios of reflected waves are computed for relevant physical constants of a thermoelastic material. The speeds of plane waves are plotted against nonlocal parameter and frequency. The energy ratios of reflected waves are also plotted against the angle of incidence of P wave at a thermally insulated stress-free surface. The effect of nonlocal parameter is shown graphically on the speeds and energy ratios of reflected waves.

Fabrication of Large-Area Photovoltaic Crystal with Modified Surface Using Trimethoxysilyl Propyl Methacrylate (TMSPM) for Solar Cell Protection

  • Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • 제2권3호
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    • pp.84-87
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    • 2014
  • Protection of solar cell surface is important to prevent from dust, pollen, sand, etc. Therefore, development of large area antifouling film is urgent for high performance of solar cells. The surface of silica spheres was modified to fabricate large area antifouling film. The surface of monodisperse silica spheres has been modified with 3-(trimethoxysilyl) propylmethacrylate (TMSPM) to fabricate large area photonic crystal. Although the surface modification of silica spheres with TMSPM has been failed for the base catalyst, the second trial using acid catalyst showed the following results. The FTIR absorption peak at $1721cm^{-1}$ representing C=O stretching vibration indicates that the TMSPM was attached on the surface of silica spheres. The methanol solution comprised of the surface modified silica spheres (average diameter of 380 nm) and a photoinitiator was poured in the patterned silicon wafer with the dimension of 10 cm x 10 cm and irradiated UV-light during the self-assembly process. The result showed large area crack and defect free nanostructures.

비말 가림막과 휴대형 공기청정기 사용에 의한 대화 중 비말 및 공기전파 저감 효과 (Effectiveness of droplet protective screens and portable air purifiers against droplet and airborne transmission during conversation)

  • 허지은;신동호;조희주;박현설;조윤행
    • 한국입자에어로졸학회지
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    • 제18권4호
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    • pp.87-95
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    • 2022
  • Currently, droplet protective screens (DPSs) are used to prevent the spread of respiratory diseases. As virus particles can maintain their infective in indoor environments, recent studies have investigated the risk of airborne transmission. However, the ability of DPSs to block airborne transmission has not been verified yet. In this study, the preventive ability of DPSs against droplet and airborne transmission was evaluated. Moreover, the effectiveness of a Portable air purifier (PAP) was investigated. According to results, in a simulated room where an infectious person spoke, the DPS blocked more than 90% of the micron-sized droplets (with a diameter larger than 1 ㎛) transmitted to the front of the infectious person. However, sub-micron droplets (with a diameter smaller than 1 ㎛) passed through the DPS and spread in a room. However, the PAP reduced the amount of both micron and sub-micron droplets transmitted to the front of the infectious person. When the PAP airflow direction was set from the DPS surface to the free space near the infectious person, improved prevention against droplet and airborne transmission was recorded. However, airborne transmission was accelerated when the PAP airflow direction was set from the free space to the DPS surface.

폴리실록산이미드 막의 제조와 투과증발특성 (The Preparation of Polysiloxaneimide Membranes and their Pervaporation Properties)

  • 장연희;김정훈;이수복;이희우
    • 공업화학
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    • 제10권7호
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    • pp.1041-1045
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    • 1999
  • 세 가지 종류의 방향족 다이안하이드라이드(6FDA, BTDA, PMDA)와 polydimethylsiloxane(SIDA, 평균 분자량 800)을 단독 다이아민으로 하여 축중합반응에 의하여 폴리실록산이미드(PSI) 막을 제조하였다. 이들은 모두 실록산 30~40 wt % 함유하고 있는 고무상의 고분자로서 낮은 밀도, 높은 비자유부피, 그리고 낮은 표면에너지를 가지고 있었다. 제조된 PSI막을 0.05 wt %의 4가지 혼합용매(ethyl acetate, methylene chloride, trichloroethylene, toluene)에 대해 투과증발 특성을 알아본 결과 이들은 유기용매의 소수성 경향이 증가할수록 높은 선택도와 투과도를 보였다.

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부유기 OWC 챔버의 파중 운동해석 (A Study on the Floating OWC Chamber Motion in Waves)

  • 홍도천
    • 한국해양공학회지
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    • 제16권3호
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    • pp.19-27
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    • 2002
  • The motion of a floating OWC chamber in waves is studied taking account of fluctuating air pressure in the air chamber. An atmospheric pressure drop occurs across the upper opening of the chamber which causes not only hydrodynamic but also pneumatic added mass and damping forces to the floating chamber. A velocity potential in the water due to the free surface oscillating pressure patch is added to the conventional radiation-diffraction potential problem. the potential problem inside the chamber is formulated by making use of the Green integral equation associated with the Rankine Green function wile the outer problem with the Kelvin Green function. The two integral equations are solved simultaneously by making use of a matching boundary condition at the lower opening of the chamber to the outer water region. The chamber motion in the frequency domain is calculated for various values of parameters related to the atmospheric pressure drop. The present methods can also be sued for the analysis of air-cushion vehicle motion as well as for the design of a floating OWC wave energy absorber.

부유식 OWC 챔버의 파중 운동해석 (A Study on the Floating OWC Chamber Motion in Waves)

  • 홍도천;홍사영
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2002년도 춘계학술대회 논문집
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    • pp.191-197
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    • 2002
  • The motion of a floating OWC chamber in waves is studied taking account of fluctuating.air pressure in the air chamber. An atmospheric pressure drop occurs across the upper opening of the chamber which causes not only hydrodynamic but also pneumatic added mass and damping forces to the floating chamber. A velocity potential in the water due to the free surface oscillating pressure patch is added to the conventional radiation-diffraction potential problem. The potential problem inside the chamber is formulated by making use of the Green integral equation associated with the Rankine Green function while the outer problem with the Kelvin Green function. The two integral equations are solved simultaneously by making use of a matching boundary condition at the lower opening of the chamber to the outer water region. The chamber motion in the frequency domain is calculated for various values of parameters related to the atmospheric pressure drop. The present methods can also be used for the analysis of air-cushion vehicle motion as well as for the design oj a floating owe wave energy absorber.

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Contact analysis of spherical ball and a deformable flat model with the effect of tangent modulus

  • Sathish Gandhi, V.C.;Ramesh, S.;Kumaravelan, R.;Thanmanaselvi, M.
    • Structural Engineering and Mechanics
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    • 제44권1호
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    • pp.61-72
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    • 2012
  • The paper is on contact analysis of a spherical ball with a deformable flat, considering the effect of tangent modulus on the contact parameters of a non-adhesive frictionless elastic-plastic contact. The contact analysis of this model has been carried out using analysis software Ansys and Abaqus. The contact parameters such as area of contact between two consecutive steps, volume of bulged material are evaluated from the formulated equations. The effect of the tangent modulus is considered for determining these parameters. The tangent modulus are accounted between 0.1E and 0.5E of materials E/Y value greater than 500 and less than 1750. Result shows that upto an optimal tangent modulus values the elastic core push up to the free surface in the flat. The simulation is also carried out in Abaqus and result provide evidence for the volume of bulged material in the contact region move up and flow into the free surface of the flat from the contact edge between the ball and flat. The strain energy of the whole model is varied between 20 to 40 percentage of the stipulated time for analysis.

Pigment Degradation by Lignin Peroxidase Covalently Immobilized on Magnetic Particles

  • Park, Jin-Won
    • 청정기술
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    • 제23권4호
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    • pp.408-412
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    • 2017
  • Pigment red 53:1 is a dye used in various products as a component of the inks, suspected of being carcinogenic. Thus, the environmental and occupational issues related to it are important. The enzyme-based approach with reusability has advantages to consume less energy and generate less harsh side- products compared to the conventional strategies including separations, microbe, and electrochemical treatment. The degradation of Pigment red 53:1 by the lignin peroxidase immobilized on the surface of magnetic particles has been studied. The immobilization of the peroxidase was conducted on magnetic particle surface with the treatment of polyethyleneimine, glutaraldehyde, and the peroxidase, in sequence. The immobilization was confirmed using X-ray photon spectroscopy. The absorbance peak of the pigment was monitored at 495 nm of UV/Vis spectrum with respect to time to calculate the catalytic activities of the pigment for the immobilized lignin peroxidase. For the comparison, the absorbance of the lignin peroxidase free in solution was also monitored. The catalytic rate constant values for the free lignin peroxidases and the immobilized those were 0.51 and $0.34min^{-1}$, respectively. The reusable activity for the immobilized lignin peroxidase was kept to 92% after 10 cycles. The stabilities for heat and storage were also investigated for both cases.

투과성 격벽을 이용한 수평 운동하는 사각형 탱크내의 슬로싱 감쇠 (Sloshing Damping in a Swaying Rectangular Tank Using a Porous Bulkhead)

  • 조일형
    • 한국해양공학회지
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    • 제32권4호
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    • pp.228-236
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    • 2018
  • The performance of a porous swash bulkhead for the reduction of the resonant liquid motion in a swaying rectangular tank was investigated based on the assumption of linear potential theory. The Galerkin method (Porter and Evans, 1995) was used to solve the potential flow model by adding a viscous frictional damping term to the free-surface condition. By comparing the experimental results and the analytical solutions, we verified that the frictional damping coefficient was 0.4. Darcy's law was used to consider the energy dissipation at a porous bulkhead. The tool that was developed with a built-in frictional damping coefficient of 0.4 was confirmed by small-scale experiments. Using this tool, the free-surface elevation, hydrodynamic force (added mass, damping coefficient) on a wall, and the horizontal load on a bulkhead were assessed for various combinations of porosity and submergence depth. It was found that the vertical porous bulkhead can suppress sloshing motions significantly when properly designed and by selecting the appropriate porosity(${\approx}0.1$) and submergence depth.

Emulsification of Asphalt Modified with Styrene Butadiene Rubber (SBR) and Styrene Butadiene Styrene (SBS); 1) Phase Stability Behavior and 2) Physical Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제54권4호
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    • pp.335-344
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    • 2019
  • In this work, styrene butadiene rubber (SBR) and styrene butadiene styrene (SBS) were used to modify asphalt, resulting in SBR- and SBS-modified asphalt, respectively. The two modified asphalts were emulsified with a nonionic emulsifier (Span 60) and cationic emulsifiers (ID, DDA) and their phase stabilization was investigated via particle size, Zeta potential, and flow behavior analysis. With increasing amount of the mixed emulsifier, the particle size decreased, leading to an increase in viscosity. The shear thinning behaviors and Zeta potential values ranging from 35-65 mV were determined and remained considerably stable. In addition, the adhesion strength and compression strength of the SBR-and SBS-modified asphalt emulsion were evaluated via surface free energy examination. The remarkable adhesion and compression strengths were estimated when 5 phr ID and 6 phr DDA were added to the emulsified asphalt modified with SBR and SBS. Therefore ID and DDA, the two cationic surfactants, played significant roles in improving the dispersion and interfacial adhesion strength, resulting in the improved adhesion and compression strength of the emulsified asphalts modified with SBR and SBS.