• Title/Summary/Keyword: Surface free energy

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A time-domain simulation of an oscillating water column with irregular waves

  • Koo, Weoncheol;Kim, Moo-Hyun
    • Ocean Systems Engineering
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    • v.2 no.2
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    • pp.147-158
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    • 2012
  • A time-domain simulation of a land-based Oscillating Water Column (OWC) with various irregular waves as a form of PM spectrum is performed by using a two-dimensional fully nonlinear numerical wave tank (NWT) based on the potential theory, mixed Eulerian-Lagrangian (MEL) approach, and boundary element method. The nonlinear free-surface condition inside the OWC chamber was specially devised to describe both the pneumatic effect of the time-varying pressure and the viscous energy loss due to water column motions. The quadratic models for pneumatic pressure and viscous loss are applied to the air and free surface inside the chamber, and their numerical results are compared with those with equivalent linear ones. Various wave spectra are applied to the OWC system to predict the efficiency of wave-energy take-off for various wave conditions. The cases of regular and irregular waves are also compared.

Relationships between Antithrombogenicity and Surface Free Energy of Regenerated Silk Fibroin Films

  • Park, Won Ho;Ha, Wan Shik;Ito, Hiraku;Miyamoto, Takeaki;Inagaki, Hiroshi;Noishiki, Yasuharu
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.58-63
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    • 2001
  • Silk fibroin (SF) was dissolved in calcium chloride/ethanol/water mixture(1/2/8 in mole ratio) at $70^{\circ}C$ for 4h. The dissolved silk fibroin was regenerated by casting the dialyzed solution into films. The films were treated with 50% aqueous solution of methanol for different times, and their antithrombogenicity was evaluated by in vivo tests. In vivo blood tests were made by a method of peripheral vein indwelling suture. It was found that the silk fibroin had a good antithrombogenicity and an absorbability even though the polymer showed foreign body reaction. Finally, the blood compatibilty of silk fibroin films which were subjected to structural change by the methoanl treatment, was examined in connection with their interfacial surface energy, and a correlation between these properties was found to be present.

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Study on the Flow Characteristics of the Epoxy Resin w.r.t. Sizing Materials of Carbon Fibers (탄소섬유 사이징에 따른 에폭시 수지 유동 특성에 관한 연구)

  • Lim, Su-Hyun;On, Seung Yoon;Kim, Seong-Su
    • Composites Research
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    • v.31 no.6
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    • pp.379-384
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    • 2018
  • This paper aims to study flow characteristics of epoxy resin w.r.t. the sizing agents treated on the carbon fibers which have the same surface morphologies before sizing treatment. Dynamic contact angle (DCA) was measured to evaluate wettability of a single carbon fiber. Wicking test and Vacuum Assisted Resin Transfer Molding (VARTM) were performed to find relation between DCA measurement results and impregnation characteristics. In addition, surface properties of the carbon fibers such as surface free energy and chemical compositions were measured and interfacial shear strength (IFSS) between the carbon fiber and the resin were experimentally characterized by using micro-droplet tests. According to these experimental results, the sizing agent for carbon fibers should have appropriate level of surface free energy and good chemical compatibility with the resin to reconcile resin flow characteristics and interfacial strength.

Effect of Ozone Treatment on Dyeability of Polyethylene Film (오존 처리가 폴리에틸렌 필름의 염색성에 미치는 영향)

  • 박수진;신준식;김학용;이덕래
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.98-105
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    • 2003
  • The surface energy and the effect of functional groups on the surface of the ozone-treated low-density polyethylene (LDPE) film were studied. Treatment conditions were treatment time, total amount of transferred ozone, and ozone concentration. The introduction of polar groups on the surface of LDPE film after ozone treatment was confirmed by FTIR-ATR and XPS analyses. Surface fee energy of the LDPE film was examined by a contact angle method. The ozone treated-LDPE film showed a decreased water contact angles about 15$^{\circ}$ mainly due to the increased concentration of oxygen-containing functional groups, which was attributed to the increased surface free energy or $O_{IS}/C_{IS}$Also, the concentrations of the oxygen-containing functional groups on the surface of LDPE film increased with ozone treatment time and concentration, whereas no significant effects were found for the total amount of transferred ozone. From the dyeability test using Kubelka-Munk equation, it was found that the ozone treatment plays an important role in the growth of oxygen-containing functional groups of LDPE film, resulting in the improvement of dyeability for basic dyeing agent.

Thermomechanical Local QC Analysis of Nanoscale Structure Considering Surface Effect (표면효과를 고려한 나노 사이즈 구조물의 local QC 열탄성 해석)

  • Yoo, Su-Young;Rhee, Seung-Yun;Cho, Maeng-Hyo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2007.04a
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    • pp.415-420
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    • 2007
  • In analyzing the nano-scale behavior of nano devices or materials, QC method is efficient because it does not treat all the atoms. But for more accurate analysis in QC method, it is important to consider temperature and surface effects. In finite temperature, free energy is considered instead of potential energy. Because the surface area to volume ratio increases as the length scale of a body decreases, the surface effects are more dominant. In this paper, temperature related Cauchy-Born rule and surface Cauchy-Born rule are proposed to configurate the strain energy density. This method is applied to small and homogeneous deformation in two dimensional problem using finite element simulation.

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Effect of NH3 plasma on thin-film composite membrane: Relationship of membrane and plasma properties

  • Kim, Eun-Sik;Deng, Baolin
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.109-126
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    • 2013
  • Surface modification by low-pressure ammonia ($NH_3$) plasma on commercial thin-film composite (TFC) membranes was investigated in this study. Surface hydrophilicity, total surface free energy, ion exchange capacity (IEC) and zeta (${\zeta}$)-potentials were determined for the TFC membranes. Qualitative and quantitative analyses of the membrane surface chemistry were conducted by attenuated total reflectance Fourier transform infrared (ATR FT-IR) spectroscopy. Results showed that the $NH_3$ plasma treatment increased the surface hydrophilicity, in particular at a plasma treatment time longer than 5 min at 50 W of plasma power. Total surface free energy was influenced by the basic polar components introduced by the $NH_3$ plasma, and isoelectric point (IEP) was shifted to higher pH region after the modification. A ten (10) min $NH_3$ plasma treatment at 90 W was found to be adequate for the TFC membrane modification, resulting in a membrane with better characteristics than the TFC membranes without the modification for water treatment. The thin-film chemistry (i.e., fully-aromatic and semi-aromatic nature in the interfacial polymerization) influenced the initial stage of plasma modification.

Development of Debris-free Process using Erasable Ink for Polymer Ablation (폴리머의 어블레이션 시 소거성 잉크를 이용한 잔유물 제거공정 개발)

  • Shin, D.S.;Lee, J.H.;Suh, J.;Kim, T.H.
    • Laser Solutions
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    • v.8 no.2
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    • pp.21-32
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    • 2005
  • The excimer laser ablation of a polymer occurs by the excitation of chemical bonds to energy levels that are above the dissociation energy. In this process, however, fragmented debris is finally ejected explosively by the scission of bonds and accumulates on the material surface. In the present work, a process for eliminating surface debris contamination generated by the laser ablation of a polymer is developed. The proposed approach for removing surface debris utilizes an erasable ink pasted on a polymide. The ink pasted polyimide is ablated by KrF excimer laser. The surface debris ejected from the polyimide is then combined with the ink layer on the polymer. Finally, both the surface debris and the ink layer are removed using adhesive tape or alcohol solvent. The results suggest that the erasable ink method is a simple, low cost, and extremely effective debris eliminating process.

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Numerical Analysis of Chamber Flow and Wave Energy Conversion Efficiency of a Bottom-mounted Oscillating Water Column Wave Power Device (고정식 진동수주형 파력 발전장치의 챔버 유동 및 파에너지 변환효율 해석)

  • Koo, Weon-Cheol;Kim, Moo-Hyun;Choi, Yoon-Rak
    • Journal of the Society of Naval Architects of Korea
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    • v.47 no.3
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    • pp.388-397
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    • 2010
  • A two-dimensional time-domain, potential-theory-based fully nonlinear numerical wave tank (NWT) was developed by using boundary element method and the mixed Eulerian-Lagrangian (MEL) approach for free-surface node treatment. The NWT was applied to prediction of primary wave energy conversion efficiency of a bottom-mounted oscillating water column (OWC) wave power device. The nonlinear free-surface condition inside the chamber was specially devised to represent the pneumatic pressure due to airflow velocity and viscous energy loss at the chamber entrance due to wave column motion. The newly developed NWT technique was verified through comparison with given experimental results. The maximum energy extraction was estimated with various chamber-air duct volume ratios.

Fully nonlinear time-domain simulation of a backward bent duct buoy floating wave energy converter using an acceleration potential method

  • Lee, Kyoung-Rok;Koo, Weoncheol;Kim, Moo-Hyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.513-528
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    • 2013
  • A floating Oscillating Water Column (OWC) wave energy converter, a Backward Bent Duct Buoy (BBDB), was simulated using a state-of-the-art, two-dimensional, fully-nonlinear Numerical Wave Tank (NWT) technique. The hydrodynamic performance of the floating OWC device was evaluated in the time domain. The acceleration potential method, with a full-updated kernel matrix calculation associated with a mode decomposition scheme, was implemented to obtain accurate estimates of the hydrodynamic force and displacement of a freely floating BBDB. The developed NWT was based on the potential theory and the boundary element method with constant panels on the boundaries. The mixed Eulerian-Lagrangian (MEL) approach was employed to capture the nonlinear free surfaces inside the chamber that interacted with a pneumatic pressure, induced by the time-varying airflow velocity at the air duct. A special viscous damping was applied to the chamber free surface to represent the viscous energy loss due to the BBDB's shape and motions. The viscous damping coefficient was properly selected using a comparison of the experimental data. The calculated surface elevation, inside and outside the chamber, with a tuned viscous damping correlated reasonably well with the experimental data for various incident wave conditions. The conservation of the total wave energy in the computational domain was confirmed over the entire range of wave frequencies.