• Title/Summary/Keyword: Surface equilibrium temperature

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Equilibrium, kinetic and thermodynamic studies of the adsorption of acidic dye onto bagasse fly ash

  • Shouman, Mona A.;Fathy, Nady A.;El-Khouly, Sahar M.;Attia, Amina A.
    • Carbon letters
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    • v.12 no.3
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    • pp.143-151
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    • 2011
  • Bagasse fly ash (BFA) is one of the important wastes generated in the sugar industry; it has been studied as a prospective low-cost adsorbent in the removal of congo red (CR) from aqueous solutions. Chemical treatment with $H_2O_2$ was applied in order to modify the adsorbability of the raw BFA. Batch studies were performed to evaluate the influence of various experimental parameters such as dye solution pH, contact time, adsorbent dose, and temperature. Both the adsorbents were characterized by Fourier-transform infrared spectrometer, energy-dispersive X-ray spectrophotometer and nitrogen adsorption at 77 K. Equilibrium isotherms for the adsorption of CR were analyzed by Langmuir, Freundlich and Temkin models using non-linear regression technique. Intraparticle diffusion seems to control the CR removal process. The obtained experimental data can be well described by Langmuir and also followed second order kinetic models. The calculated thermodynamic parameters indicate the feasibility of the adsorption process for the studied adsorbents. The results indicate that BFA can be efficiently used for the treatment of waste water containing dyes.

An Analysis of Changes in Catch Amount of Offshore and Coastal Fisheries by Climate Change in Korea (기후변화에 따른 한국 연근해 어업생산량 변화 분석)

  • Eom, Ki-Hyuk;Kim, Hong-Sik;Han, In-Seong;Kim, Do-Hoon
    • The Journal of Fisheries Business Administration
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    • v.46 no.2
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    • pp.31-41
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    • 2015
  • This study aimed to analyze the relationship between sea surface temperature as a climatic element and catch amount of offshore and coastal fisheries in Korea using annual time series data from 1970 to 2013. It also tried to predict the future changes in catch amount of fisheries by climate change. Time series data on variables were estimated to be non-stationary from unit root tests, but one long-term equilibrium relation between variables was found from a cointegration test. The result of Granger causality test indicated that the sea surface temperature would cause directly changes in catch amount of offshore and coastal fisheries. The result of regression analysis on sea surface temperature and catch amount showed that the sea surface temperature would have negative impacts on the catch amount of offshore and coastal fisheries. Therefore, if the sea surface temperature would increase, all other things including the current level of fishing effort being equal, the catch amount of offshore and coastal fisheries was predicted to decrease.

An Experimental Study on Ram Pressure and THD Performance of Pivoted Pad Thrust Bearing (피봇식 주력베어링의 선단압력과 THD성능에 관한 실험적 연구)

  • 박홍규;김경웅
    • Tribology and Lubricants
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    • v.2 no.1
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    • pp.61-68
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    • 1986
  • Effects of the ram-pressure on the THD-performance of pivoted pad thrust bearings are investigated experimentally. A sector-shaped tilting pad thrust bearing and a rotating disk are used. Temperature distribution on the disk surface as well as on the pad surface, distribution of the pressure generated within the fluid film, and the film thickness are measured continuously in the circumferential direction after thermal equilibrium is established. The ram-pressure is proportional to the mean pressure of oil film and to the rotational speed of the disk and affects the maximum pressure and the pressure distribution. The temperature rise on the mating surface of the disc and the pad, contacting with the oil film, is proportional to to the bearing load and the disk speed. The ram-pressure and the temperature rise on the disk surface are dominant factors that affect the THD-performance of pivoted pad thrust bearings.

Nucleation and Growth of Diamond in High Pressure

  • Choi, Jun-Youp;Park, Jong-Ku;Kang, Suk-Joong L.;Kwang, Yong-Eun
    • The Korean Journal of Ceramics
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    • v.2 no.4
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    • pp.221-225
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    • 1996
  • In diamond synthesis by metal film growth method under high pressure and high temperature, the nucleation and growth of diamond was observed dependent on the carbon source variation from graphite powder to the heat treated powders of lamp black carbon. At the low driving force condition near equilibrium pressure and temperature line, nucleation of diamond did not occur but growth of seed diamond appeared in the synthesis from lamp black carbon while both nucleation and growth of diamond took place in the synthesis from graphite. Growth morphology change of diamond occurred from cubo-octahedron to octahedron in the synthesis from graphite but very irregular growth of seed diamond occurred in the synthesis from lamp block carbon. Lamp black carbon transformed to recrystallized graphite first and very nucleation of diamond was observed on the recrystallized graphite surface. Growth morphology of diamond on the recrystallized graphite was clear cubo-octahedron even at higher pressure departure condition from equilibrium pressure and temperature line.

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Moisture Migration of Concrete Members under High Temperature (고온조건에서 콘크리트 부재의 수분이동)

  • Lee, Tae-Gyu;Kim, Hye-Uk
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.1530-1535
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    • 2009
  • Moisture evaporates, when concrete is exposed to fire, not only at concrete surface but also at inside the concrete to adjust the equilibrium and transfer properties of moisture. The equilibrium properties of moisture are described by means of water vapor sorption isotherms, which illustrate the hysteretical behavior of materials. In this paper, the prediction method of the moisture distribution inside the high strength concrete members under the high temperature is presented. Finite element method is employed to facilitate the moisture diffusion analysis for any position of member. And the moisture diffusivity model of high strength concrete by high temperature is proposed. To demonstrate the validity of this numerical procedure, the prediction by the proposed algorithm is compared with the test result of other researcher. The proposed algorithm shows a good agreement with the experimental results including the vaporization effect inside the concrete.

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Synthesis and Crystallization Behaviors of Modified PET Copolymers

  • Hu, Seung-Woo;Myung, Hee-Soo;Bae, Jong-Seok;Yoo, Eui-Sang;Im, Seung-Soon
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.76-82
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    • 2000
  • A series of random copolyesters having various compositions were synthesized by bulk copolymerization of bishydroxyethyl terephthalate (BHET) with 1,4-cyclohexane dimethanol (CHDM) or dimethyl isophthalate (DMI). CHDM and DMI content was less than 10 wt%. For the synthesized copolyesters, isothermal crystallization rate, melting behavior, and equilibrium temperature were investigated by calorimetry and by Avrami and Hoffman-Weeks equation. Crystalline lattice and morphology were studied by WAXD and SEM. Regardless of the composition, the value of the Avrami exponent was about 3, which indicates that crystallization mechanism of the copolyester was similar to those of PET homopolymer. Incoporation of CHDM or DMI units in PET backbone decreased the crystallization rate of the copolyesters. Surface free energy of copolyesters was evaluated using the newly proposed equation. The value of surface free energy was about 189$\times$$10^{-6}$/$J^{2}$/$m^{4}$ regardless of comonomer contents. This result is in good agreement with that of PET homopolymer.

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MEASUREMENT OF SURFACE TENSION OF MOLTEN METALS IN ARC WELDING

  • Shinobu Satonaka;Shigeo Akiyoshi;Inoue, Rin-taro;Kim, Kwang-Ryul
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.757-762
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    • 2002
  • Many reports have been shown that the buoyancy, electromagnetic force, surface tension, and gas shear stress are the driving forces of weld pool circulation in arc welding. Among them, the surface tension of molten metal plays an important role in the flow in weld pool, which are clarified by the specially designed experiments with small particles as well as the numerical simulations. The surface tension is also related to the penetration in arc welding. Therefore, a quantitative evaluation of surface tension is demanded for the development of materials and arc process control. However, there are few available data published on the surface tension of molten metals, since it depends on the temperature and the composition of materials. In this study, a new method was proposed for the evaluation of surface tension and its temperature dependence, in which it is evaluated by the equilibrium condition of acting forces under a given surface geometry, especially back surface. When this method was applied to the water pool and to the back surface of molten pool in the stationary gas tungsten arc welding of thin plate, following results were obtained. In the evaluation of surface tension of water, it was shown that the back surface geometry was very sensitive to the evaluation of surface tension and the evaluated value coincided with the surface tension of water. In the measurement of molten pool in the stationary gas tungsten arc welding, it was also shown that the comparison between the surface tension and temperature distribution across the back surface gave the temperature dependent surface tension. Applying this method to the mild steel and stainless steel plates, the surface tension with negative gradient for temperature is obtained. The evaluated values are well matched with ones in the published papers.

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Sea Surface Cold Water near the Southeastern Coast of Korea: Wind Effect (한국(韓國) 남동해안(南東海岸)부근의 해표면(海表面) 냉수(冷水) : 바람의 영향(影響))

  • Byun, Sang-Kyung
    • 한국해양학회지
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    • v.24 no.3
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    • pp.121-131
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    • 1989
  • Cold water observed at sea surface near the southeastern coast of Korea in summers 1982 and 1983 was studied by using data of hydrography, sea level, wind and satellite image. In summer season when water column shows 3-layered structure a "full" upwelling occurs by southwesterly transient wind continuing for several days. During upwelling event, surface water of high temperature moved offshore, middle water of low temperature outcropped to the sea surface, and sea level was lowered, however, equilibrium depth of surface layer was not changed. It may be concluded that cold water at the surface originates from middle layer and strong surface front is a result of surfacing of seasonal thermocline. In order to see the relationship between position of surface front and wind input, a model of Csanady (1982) was applied in a rigid lid approximation. The results show that frontal position can be determined by wind input and water structure near the southeastern coast of Korea. Cold water in summer can appear at the sea surface only when there is wind larger than a minimum wind impulse of order $10m^2/sec$.

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Moisture Sorption Isotherm and Quality Deterioration of Dry Jujube (건대추의 등온흡습곡선 및 품질열화특성)

  • 김영숙;안덕순
    • Food Science and Preservation
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    • v.4 no.1
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    • pp.33-38
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    • 1997
  • In order to provide informations for designing packaging and storage condition of dry jujube (Zizyphus jujuba MILLER), moisture sorption isotherm was determined for temperatures of 20, 30 and 4$0^{\circ}C$, and quality changes were evaluated as function of temperature and water activity. Dry jujube at a given water activity showed higher equilibrium moisture content for lower temperature. Moisture isothem could be fitted by GAB model equation, giving higher C value, lower m0 and relatively constant k value with increase in temperature. Ascorbic acid was lost more highly at higher temperature and water activity, and showed negligible retention for whole range of water activity and temperature studied after 141 days. Browning increased with water activity up to 0.73 at 30 and 4$0^{\circ}C$. Dry jujube of high water activity had high L value in surface color, which represent brightness of surface color. Considering quality retention in the storage, dry jujube is desired to be dried to water activity of 0.42 and be stored at temperature below 3$0^{\circ}C$

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NUMERICAL ANALYSIS OF A 150KW HUELS TYPE ARC HEATER (150kW급 Huels형 아크 히터 내부의 유동 해석)

  • Han, S.H.;Byeon, J.Y.;Kim, K.H.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.562-566
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    • 2010
  • Numerical analysis of 150kW Huels-type arc jet was performed using compressible Navier-Stokes CFD code. To consider chemical reaction by high temperature, the flow was assumed to be chemical equilibrium states. As a turbulence and a radiation model, the two-equation k-epsilon model and the 3-band radiation model were adopted, respectively. Mass flow rate and current density were given as conditions for calculations. In this study, two kinds of mechanisms for injection of air flow wire considered. One is that air is provided by left wall surface and the other is that air is injected from upper wall surface. The pressure, density and temperature contours of two cases were compared and heat transfer rates were estimated. The numerical results of two cases were not much different to each other. However, in real 150KW device, air is injected from upper wall surface with swirl. To calculate more accurately, swirl effect is must be considered.

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