• Title/Summary/Keyword: Surface enrichment

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Assessment of the Pollution Levels of Organic Matter and Metallic Elements in the Intertidal Surface Sediments of Aphae Island (압해도 조간대 표층퇴적물의 유기물 및 금속원소 오염도 평가)

  • Hwang, Dong-Woon;Park, Sung-Eun;Kim, Pyoung-Jung;Koh, Byoung-Seol;Choi, Hee-Gu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.44 no.6
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    • pp.759-771
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    • 2011
  • We evaluated the pollution levels of organic matter and metallic element (Fe, Cu, Pb, Zn, Cd, Ni, Cr, Mn, As, and Hg) in the intertidal surface sediments of Aphae Island using several sediment quality guidelines (SQGs) and assessment techniques for sediment pollution. Based on the textural composition of sediment, the surface sediments were classified into two main sedimentary facies: slightly gravelly mud and silt. The concentrations of chemical oxygen demand (COD) and acid volatile sulfide (AVS) in the sediments ranged from 4.6-9.9 (mean $7.4{\pm}1.1$) $mgO_2/g{\cdot}dry$ and from ND-0.53 (mean $0.04{\pm}0.10$) mgS/$g{\cdot}dry$, respectively. These values were considerably lower than those reported from a farming area in a semi-enclosed bay of Korea and for SQGs in Japan. The metallic element concentrations in the sediments varied widely with the mean grain size and organic matter content, implying that the concentrations of metallic elements are influenced mainly by secondary factors, such as bioturbation, the resuspension of sediment, and anthropogenic input. The overall results for the comparison with SQGs, enrichment factor (EF), and geoaccumulation index ($I_{geo}$) indicate that the surface sediments are slightly polluted by Cr and Ni, and moderately polluted by As. Our results suggest that the intertidal surface sediments of Aphae Island are not polluted by organic matter or metallic elements and the benthic conditions are suitable for healthy organisms.

Environmental toxicity and biodegradation of Pseudomonas sp. EL-G527 producing biosurfactant

  • Mi Seon, Cha;Hong Ju, Son;Sang Jun, Lee
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2002.05b
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    • pp.452-454
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    • 2002
  • A biosurfactant-producing microorganism, .Pseudomouos sp. EL-G527 was isolated from activated sludge by enrichment culture when grown on mineral salt medium containing n-hexadecane as a carbon source. The biosurfactant from .Pseudomonar sp. EL-G527 exhibited lesser toxicity to bacterial population than synthetic surfactants and in the biodegradation test, biosurfactant was rapidly degraded and lost its activity as surface active material after 1 day incubation. In this study, the biosurfactant from Pseudomonas sp. EL-G527 was effective surface-active compound, more biodegradable and less toxic to microbial ecosystem than various synthetic surfactants.

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Immobilization of Polysiloxane Liquid Phase on the Gas Chromatographic Solid Supports via In-Situ Cross-Linking

  • Kim, Kyoung-Rae;Zlatkis, Albert
    • Bulletin of the Korean Chemical Society
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    • v.8 no.3
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    • pp.133-137
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    • 1987
  • Polysiloxane SE-54 liquid phase was immobilized on the support surface as coated in thin film via in-situ cross-linking. The cross-linking between liquid molecules was initiated by dicumylperoxide. Among the supports investigated, only Chromosorb W provided the cross-linkable surface. The optimal in-situ cross-linking was achieved when Chromosorb W was coated with 5% (w/w) SE-54 and cross-linked with 1% (w/w) dicumylperoxide. The cross-linked support was useful for the trace analysis as well as for the trace enrichment.

Geochemical Study of Coastal Sediments around the Samcheonpo Coal-fired Power Plant (삼천포화력발전소 주변해역 퇴적물의 지구화학적 연구)

  • Lee, Doo-Ho;Lim, Ju-Hwan;Jeong, Yeon-Tae;Jeong, Nyeon-Ho;Kang, Jeong-Won
    • Journal of Environmental Impact Assessment
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    • v.10 no.2
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    • pp.85-98
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    • 2001
  • This study was conducted to investigate the geochemical factors governing the distribution of heavy metals(Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) in the marine surface sediment samples collected from the Samcheonpo coal-fired power plant. Variations of absolute metal concentrations were related to those in textural and/or carbonate and organic matter content. Most elements, except for Pb, showed generally lower contents compared with the average shale concentration, and the effect of anthropogenic input appeared to be minimal in the sediments. Computations of LF%(labile fraction) and EF(enrichment factor) based on all trace metal data indicated the presence of mineralogical control for Co, Cr, Cu, Ni, and Zn, and anthropogenic contamination for Pb, which needs to be considered in the design of long term monitoring programmes.

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An analysis of neutron sources and gamma-ray in spent fuels using SCALE-ORIGEN-ARP (SCALE-ORIGEN-ARP를 이용한 사용후핵연료 내 중성자 및 감마선원 분석)

  • So-Hee Cha;Kwang-Heon Park
    • Journal of the Korean institute of surface engineering
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    • v.56 no.1
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    • pp.84-93
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    • 2023
  • The spent nuclear fuel is burned during the planned cycle in the plant and then generates elements such as actinide series, fission products, and plutonium with a long half-life. An 'interim storage' step is needed to manage the high radioactivity and heat emitted by nuclides until permanent-disposal. In the case of Korea, there is no space to dispose of high-level radioactive waste after use, so there is a need for a period of time using interim storage. Therefore, the intensity of neutrons and gamma-ray must be determined to ensure the integrity of spent nuclear fuel during interim storage. In particular, the most important thing in spent nuclear fuel is burnup evaluation, estimation of the source term of neutrons and gamma-ray is regarded as a reference measurement of the burnup evaluation. In this study, an analysis of spent nuclear fuel was conducted by setting up a virtual fuel burnup case based on CE16×16 fuel to check the total amount and spectrum of neutron, gamma radiation produced. The correlation between BU (burnup), IE (enrichment), and CT (cooling time) will be identified through spent nuclear fuel burnup calculation. In addition, the composition of nuclide inventory, actinide and fission products can be identified.

Distribution and Pollution Assessment of Heavy Metals in Surface Sediments Near Gwangan Bridge (광안대교 인근 퇴적토 중의 중금속 농도 및 오염도 조사 연구)

  • Lee, Junho;Yang, Changgeun;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.11
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    • pp.15-22
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    • 2018
  • The main objective of this study was to analyse heavy metals in sediments obtained from Gwangan bridge and to evaluate pollution intensity of the sites. To evaluate pollution intensity of the sites, we used enrichment factor (EF), geoaccumulation index, potential ecological risk factor (PERF), and mean PEL quotient. Pollution intensities of these sites were evaluated by above methods, and we found most dangerous heavy metal and polluted sites. All sites showed non polluted or low risk for the heavy metals such as Cr, Cu, Ni, Pb, and Zn, but all sites were categorized as minor enrichment for Cd. G4 was evaluated as moderately polluted by Cd ($I_{geo}$) but other sites were unpolluted by heavy metals. In summary, Cd was found to be higher concentrations for all sites. For G4 and G5 sites, Pb and Zn in addition to Cd were higher than other sites.

Geology and Ore Deposits of Geoje Dong-A Mine (거제(巨濟) 동아광산(東亞鑛山)의 지질(地質) 및 광상(鑛床))

  • Kim, Jong Dae
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.103-112
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    • 1986
  • The geology of the mine consists of Cretaceous lower andesitic breccia member, tuffaceous black shale, upper tuffaceous sandstone member and andesitic dike. Ore bodies are two parallel veins of breccia originated from hydrothermal activity of later acidic igneous intrusion. First two periods of mineralization, gold and silver, and copper, and later copper enrichment was identified. The first two might have been occurred during boiling of hydrothermal solution that formed breccia and copper enrichment was accomplished by enhancement of $CO_2$ fugacity from the organic material contained in the black shale. With all the geologic and mineralogic data and inferences attained from other investigators it was estimated that the optimum depth of the ore mineralization was between 500m and 300m below the surface of Kyong-Sang series.

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Some heavy metal concentration of surface sediments from the southwestern coast of Korea (서남해안 연근해저 퇴적물의 중금속 함량 및 분포)

  • 전수경;조영길
    • Journal of Environmental Science International
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    • v.11 no.12
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    • pp.1299-1305
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    • 2002
  • Thirty sediment samples of the <63${\mu}{\textrm}{m}$ fraction collected from the southwestern coast of Korea were analysed for their heavy metal (Fe, Mn, Cr, Co, Cu, Ni, Zn and Pb) concentration. The results show that sediment texture plays a controlling role on the total metal concentrations and their spatial distribution. A single lM HCl extraction procedure was used in order to assess the environmental risk of heavy metals in bottom sediments. The non-residual fraction was the most abundant pool for Mn and Pb in most samples, which means that this metals are highly avaliable in these sediments. Cr, Ni, Fe, Co, Zn and Cu were mainly associated with the residual fraction, suggesting that their concentrations are controlled significantly by transport processes with the fine particles as carriers from diffuse pollution source. Concentration enrichment ratios(CER) were calculated from the non-residual contents and their values allowed us to classify the sediments according to their environmental risk.

Tritium Concentrations in Surface Seawater around Korean Peninsula (한국 주변 해역 표층해수중 삼중수소 농도)

  • Kim, Chang-Kyu;Cho, Yong-Woo;Kim, Kye-Hun
    • Journal of Radiation Protection and Research
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    • v.21 no.2
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    • pp.107-115
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    • 1996
  • An electrolytic enrichment technique was used to measure low levels of tritium in seawater around the Korean peninsula. Tritium concentrations were determined for surface seawater samples collected from the East Sea, the South Sea, and the Yellow Sea. The tritium concentrations in surface seawater samples from the study area ranged from $0.12 BqL^{-1}\;to\;1.50BqL^{-1}$ with a mean value of $0.60{\pm}0.35 BqL^{-1}$. The means of the tritium concentration were $0.54{\pm}0.30 BqL^{-1}$ for the East Sea, $0.48{\pm}0.35 BqL^{-1}$ for the South Sea, and $0.77{\pm}0.32 BqL^{-1}$ for the Yellow Sea. The tritium concentrations in the sea areas did not show much difference no matter where the samples were taken. Due to the limited number and distribution of sampling points, no systematic change in tritium levels with latitude was observed. Measured tritium levels were similar to those observed in other data collected near Japan, but higher than mid-Pacific Ocean measurements.

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Structure and chemical composition of $CsB_{3}O_{5}$ (CBO) optical surface

  • V.V. Atuchin;V.G. Kesler;L.D. Pokrovsky;N. Yu. Maklakova;M. Yoshimura;N. Ushiyama;T. Matsui;K. Kamimura;Y. Mori;T. Sasaki
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.1
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    • pp.19-23
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    • 2003
  • Polished surface of $CsB_{3}O_{5}$ (CBO) has been observed by reflection high energy electron diffraction (RHEED) and X-ray photoelectron spectroscopy (XPS). For comparison, electronic properties of CBO powder have been studied by XPS. It has been found that the crystal surface is covered by thick amorphous layer with chemical composition closely related to that of CBO. Great enrichment of top surface by cesium, ~30 % in reference to the bulk of the modified layer, has been displayed by depth profiling.