• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2012년도 춘계학술발표회 논문집
• /
• pp.184-186
• /
• 2012

In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of contact resistance and electric conductivity of GDL on the fuel cell performance. For numerical simulation contact resistance of Carbon and Stainless steel was measured. The simulation results reveal that 10 times change of electric conductivity leads only 6.5% decrease of PEMFC performance. But stainless steel which has high contact resistance decrease fuel cell performance over 25% at a high current density region than carbon. This results show that suitable Surface treatment technology is needed for metal bipolar plate, especially stainless steel.

• 한국응용과학기술학회지
• /
• 제23권2호
• /
• pp.160-168
• /
• 2006

The conductances of trimethyltetradecylammonium bromide (TTAB) plus triphenyltetradecyl phosphonium bromide (TTPB) and TTAB plus trimethylhexadecylammonium bromide (HTAB) over the entire mole fraction range of TTAB were measured in water and in cyclodextrin plus water mixtures at fixed 4 and 8 mM of cyclodextrin at $30^{\circ}C$. The conductivity plot for both binary mixtures shows a single break from which the mixed critical micelle concentration and degree of micelle ionization were computed. From the slope of the conductivity curve, the equivalent ionic conductivities of the monomeric, associated, and the micelle states were calculated and discussed with respect to the surfactant-cyclodextrin complexation in the whole mole fraction range of both surfactant binary mixtures. The association constant K between the respective monomeric surfactant and cyclodextrin cavity of fixed 4 mM cyclodextrin was computed by considering 1:1 association from the surface tension measurement. A comparison among the K values for HTAB-cyclodetrin, TTAB-cyclodextrin, and TTPB-cyclodextrin shows that the former complexation is significantly stronger in comparison to the other ones due to the longer hydrophobic tail.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2005년도 춘계 학술발표회 논문집
• /
• pp.1426-1433
• /
• 2005

In this paper, reliability analysis of surface settlement by ground water drawdown is performed using a reliability-groundwater flow numerical model. The result is compared with that of the deterministic model to evaluate the influence of the uncertainty from hydraulic conductivity in the soft ground as well as to determine the range of hydraulic conductivity of grouted ground. From the analyses, it was found that probability of failure to exceed the tolerable settlement was very high, if the hydraulic conductivity of grouted ground is decided from the deterministic flow model only. Reliability analysis which evaluates variance of hydraulic conductivity should be used together with the deterministic model for grouting design of tunnels to prevent ground water drawdown.

• 펄프종이기술
• /
• 제43권1호
• /
• pp.17-22
• /
• 2011

The conventional coated paper has many functional problems for printed RFID tag. This study was carried out in order to evaluate the effect of coating color components on conductivity of printed coated paper. It has been well known that the efficiency of printed RFID tag is influenced by surface properties of substrate. The required properties for suitable substrate of printed RFID tag are high smoothness and waterproof property. In this study high grammage base paper surface sized with PVA was used. Coated paper was manufactured with five different formulations. Types of coating pigments and dosage of latex were varied. It was obtained high smoothness and also less binder demand with clay than GCC. On the other hand, suitable surface resistance and smoothness of coated paper for RFID tag was obtained with 20% of latex. Besides it shows the possibility of using coated paper for printed RFID tag.

• 폴리머
• /
• 제24권5호
• /
• pp.673-681
• /
• 2000

플라즈마 처리가 나일론 6 직물의 표면 특성과 폴리아닐린/나일론 6 복합직물의 전도도에 미치는 영향을 연구하였다. 산소 플라즈마로 처리한 나일론 6 직물의 표면을 XPS 분석을 통해 확인한 결과 C-O, C-OH 등의 관능기가 도입되었으며, 이는 직물과 폴리아닐린의 결합력을 향상시켜 전기 전도도와 폴리아닐린 부착량을 증가시켰다. 또한 산소 플라즈마로 처리된 폴리아닐린/나일론 6 복합직물은 세탁과 마모에서도 우수한 안정성을 나타내었다. 초음파 처리는 매질에 발생된 cavitation과 진동에 의해 직물 내부로 아닐린을 확산시키는데 효과적이었으며, 이는 폴리아닐린/나일론 6 복합직물의 전기 전도도를 크게 향상시켰다. 아닐린의 농도와 중합욕에 침지 휫수가 증가함에 따라 전기 전도도와 복합직물의 형태안정성에 대한 영향을 살펴보았는데, 단량체 농도는 0.5M 까지는 증가함에 따라 전도도가 향상되었으며, 침지 횟수가 증가함에 따라서도 전도도가 향상되었다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제53권7호
• /
• pp.382-386
• /
• 2004

A study has been made of surface modification of organic materials by ion implantation to increase the surface electrical properties. The substrate used were PET(polyethylene teraphtalate). N$^{＋}$, Ar$^{＋}$ implantation was peformed at energies of 40 keV and 50 keV with fluences from $5{\times}10^{15}$, $1{\times}10^{16}$,$7{\times}10^{16}$, $1{\times}10^{17}$/ ions/$cm^2$. UV/Vis, FT-IR and XPS spectroscopy measured for surface structure changes. Surface resistance decrease of implanted polymers was affected by ion implantation energy, ion species and ion dose rate. Surface conductivity of PET increased $2{\times}10^{9}$/∼$2{\times}10^{10}$/$\Omega$/sq by ion implantation. Result of various spectroscopy analysis, the cause of increasing PET surface conductivity was expected to breaking C=O bonds. It was formation carbon network structure by promote cross-linking and create C-C, C=C bonds.

• Bulletin of the Korean Chemical Society
• /
• 제34권6호
• /
• pp.1845-1847
• /
• 2013

The lateral photovoltaic effect (LPE) can be observed in semiconductors by irradiating a light spot position between electrodes on sample's surface. Because lateral photovoltaic voltage (LPV) is sensitively changed by light spot position, a LPE device has been tried as a position-sensitive detector. This study discusses the correlation between LPV and conductivity in p-type silicon and nano-structured Au deposited p-type silicon (nano-Au silicon), respectively. Conductivity measurement of the sample was carried out using the four-wire method to eliminate contact resistance, and conductivity dependence on LPV was simultaneously measured by changing the light irradiation position. The result showed a strong correlation between conductivity and LPV in the p-type silicon sample. The correlation coefficient was 0.87. The correlation coefficient between LPV and conductivity for the nano-Au silicon sample was 0.41.

• 지질공학
• /
• 제30권2호
• /
• pp.147-160
• /
• 2020

지표 미고결퇴적층의 불포화 수리전도도는 지표 퇴적층의 물리적 성질과 함수비에 좌우된다. 지금까지 지표 미고결퇴적층의 불포화 수리전도도에 대하여 많은 연구가 수행되어왔다. 그러나 불포화 균열암반에 대한 수리전도도에 대해서는 상대적으로 연구가 적은 편이다. 중·저준위 방폐물의 표층처분시설 건설과 관련하여, 본 연구에서는 국내 방사성폐기물 처분부지 내 균열 혼펠스 암반에 대하여 반 게누텐 불포화함수(α, n)와 현장시험에서 얻어진 수리전도도를 서로 비교·분석하였다. 현장수리시험과 실내수리시험이 동시에 이루어진 지하수공 3공의 10개 구간에 대한 현장 수리전도도와 반 게누텐 매개변수에 대한 상관성 분석 결과, 현장 수리전도도와 매개변수α의 상관계수는 0.7607로 양의 상관관계를 보이며, 현장 수리전도도와 반 게누텐 형상관련 매개변수 n의 상관계수는 -0.8720으로 음의 상관관계를 보였다. 그러므로 이 연구는 불포화 균열 혼펠스에서 현장수리전도도와 실내수리시험에 의한 불포화함수의 관계를 확인하였다.

• 한국재료학회지
• /
• 제28권5호
• /
• pp.308-314
• /
• 2018

Among the fuel cell electrolyte candidates in the intermediate temperature range, glass materials show stable physical properties and are also expected to have higher ion conductivity than crystalline materials. In particular, phosphate glass has a high mobility of protons since such a structure maintains a hydrogen bond network that leads to high proton conductivity. Recently, defects like volatilization of phosphorus and destruction of the bonding structure have remarkably improved with introduction of cations, such as Zr4+ and Nb5+, into phosphate. In particular, niobium has proton conductivity on the surface because of higher surface acidity. It can also retain phosphorus content during heat treatment and improve chemical stability by bonding with phosphorus. In this study, we fabricate niobium phosphate glass thin films through sol-gel processing, and we report the chemical stability and electrical properties. The existence of the hydroxyl group in the phosphate is confirmed and found to be preserved at the intermediate temperature region of $150-450^{\circ}C$.

• Bulletin of the Korean Chemical Society
• /
• 제31권10호
• /
• pp.2967-2972
• /
• 2010

Poly-N-vinylcarbazole/polyaniline (PVK-PANI) composites are synthesized by varying target loading concentrations of aniline (0.025 - 0.1 M). The surface morphology of the composites is studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The temperature-dependent DC conductivity of PVK-PANI composite films was studied at the temperature range of 300 - 500 K. The data suggest that the conductivity increase with an increase in aniline concentration in the composite with an increase in temperature. Further based on the conductivity behavior we can suggest that the PVK-PANI composites show a semiconducting behavior with a positive temperature coefficient of resistivity (TCR). The enhanced conductivity and the positive TCR of the PVK-PANI composite films may be due to the strong interaction between PANI and PVK in the composite films.