• Title/Summary/Keyword: Surface conductivity

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In-Plane Thermoelectric Properties of InGaAlAs Thin Film with Embedded ErAs Nanoparticles (ErAs 나노입자가 첨가된 InGaAlAs 박막의 평면정렬방향으로의 열전특성)

  • Lee, Yong-Joong
    • Korean Journal of Materials Research
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    • v.21 no.8
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    • pp.456-460
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    • 2011
  • Microelectromechanical systems (MEMS)-fabricated suspended devices were used to measure the in-plane electrical conductivity, Seebeck coefficient, and thermal conductivity of 304 nm and 516 nm thick InGaAlAs films with 0.3% ErAs nanoparticle inclusions by volume. The suspended device allows comprehensive thermoelectric property measurements from a single thin film or nanowire sample. Both thin film samples have identical material compositions and the sole difference is in the sample thickness. The measured Seebeck coefficient, electrical conductivity, and thermal conductivity were all larger in magnitude for the thicker sample. While the relative change in values was dependent on the temperature, the thermal conductivity demonstrated the largest decrease for the thinner sample in the measurement temperature range of 325 K to 425 K. This could be a result of the increased phonon scattering due to the surface defects and included ErAs nanoparticles. Similar to the results from other material systems, the combination of the measured data resulted in higher values of the thermoelectric figure of merit (ZT) for the thinner sample; this result supports the theory that the reduced dimensionality, such as in twodimensional thin films or one-dimensional nanowires, can enhance the thermoelectric figure of merit compared with bulk threedimensional materials. The results strengthen and provide a possible direction in locating and optimizing thermoelectric materials for energy applications.

The Relation Among the Linear Energy Transfer and Changes of Polyphenylene Sulfide Surface by ion Implantation (이온주입에 의한 고분자(Polyphenylene Sulfide)표면 특성 변화와 선에너지전달(Pineal Energy Transfer)과의 관계)

  • Lee, Jae S.;Kim, Bo-Young;Lee, Jae-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.407-413
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    • 2005
  • Ion implantation provides a unique way to modify the mechanical, optical and electrical properties of polymer by depositing the energy of ions in the material on the atomic scale. Implantation of ions into the polymers generally leads to a radiation damage, which, in many cases, modifies the properties of the surface and bulk of the material. These modifications result from the changes of the chemical structure caused in their turn by changing the chemical bonding when the incident ions cut the polymer chains, breaks covalent bonds, promotes cross-linking, and liberates certain volatile species. We studied the relation among the linear energy transfer (LET) and changes of surface microstructure and surface resistivity on PPS material using the high current ion implantation technology The surface resistivity of nitrogen implanted PPS decreased to $10^{7}{\Omega}/cm^{2}$ due to the chain scission, cross linking, ${\pi}$ electron creation and mobility increase. In this case, the surface conductivity depend on the 1-dimensional hopping mechanism.

Mitigating the Urban Heat Island Phenomenon Using a Water-Retentive Artificial Turf System

  • Tebakari, Taichi;Maruyama, Tatsuya;Inui, Masahiro
    • Proceedings of the Korea Water Resources Association Conference
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    • 2010.05a
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    • pp.91-100
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    • 2010
  • To investigate the thermal properties of a water-retentive artificial turf system (W-ATS), we estimated hydrologic parameters including thermal conductivity, heat capacity, and surface albedo for both the W-ATS and natural grass. We used a model experiment to measure surface temperature and evaporation for both the W-ATS and natural grass. We found that the W-ATS had lower thermal conductivity than natural grass did, and it was difficult for the W-ATS to convey radiant heat to the ground. Compared to natural grass, the W-ATS also had lower heat capacity, which contributed to its larger variation in surface temperature: the W-ATS had higher surface temperatures during daytime and lower surface temperatures during nighttime. The albedo of the W-ATS was one-quarter that of natural grass, and reflected shortwave radiation from the W-ATS surface was lower than that from the surface of natural grass. These results indicate that the W-ATS caused the soil temperature to increase. Furthermore, evaporation from the W-ATS was one-quarter the value of evapotranspiration from natural grass.

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Surface Modification of Bentonite for the Improvement of Radionuclide Sorption

  • Hong, Seokju;Kim, Jueun;Um, Wooyong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.1
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    • pp.1-12
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    • 2022
  • Bentonite is the most probable candidate to be used as a buffer in a deep geological repository with high swelling properties, hydraulic conductivity, thermal conductivity, and radionuclide sorption ability. Among them, the radionuclide sorption ability prevents or delays the transport of radionuclides into the nearby environment when an accident occurs and the radionuclide leaks from the canister, so it needs to be strengthened in terms of long-term disposal safety. Here, we proposed a surface modification method in which some inorganic additives were added to form NaP zeolite on the surface of the bentonite yielded at Yeonil, South Korea. We confirmed that the NaP zeolite was well-formed on the bentonite surface, which also increased the sorption efficiency of Cs and Sr from groundwater conditions. Both NaP and NaX zeolite can be produced and we have demonstrated that the generation mechanism of NaX and NaP is due to the number of homogeneous/heterogeneous nucleation sites and the number of nutrients supplied from an aluminosilicate gel during the surface modification process. This study showed the potential of surface modification on bentonite to enhance the safety of deep geological radioactive waste repository by improving the radionuclide sorption ability of bentonite.

Characteristics of Electroplated Sn-2.5Cu Alloy Layers for Surface Finishing (표면마무리를 위한 Sn-2.5Cu 합금 도금막의 특성)

  • Kim, Ju-Youn;Bae, Kyoo-Sik
    • Korean Journal of Materials Research
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    • v.13 no.2
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    • pp.133-136
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    • 2003
  • Sn-2.5Cu alloy layers were deposited on the Alloy 42 lead-frame substrates by the electroplating method, and their microstructures, adhesion strength, and electrical resistivity were measured to evaluate the applicability of Sn-Cu alloy as a surface finishing material of electronic parts. The Sn-2.5Cu layers were electroplated in the granular form, and composed of pure Sn and Cu$_{6}$Sn$_{5}$ intermetallic compound. Surfaces of the electroplated Sn-2.5Cu layers were rather rough and also the thickness variance was large. The adhesion strength of the Sn-2.5Cu electroplated layers was highly comparable to that of the electroplated Cu alloy layer and the electrical conductivity was about 10 times higher than the pure Sn. After the 20$0^{\circ}C$ 30 min. annealing of the electroplated Sn-2.5Cu layers, the surface roughness was reduced, and adhesion strength and conductivity were improved. These results showed the Sn-Cu alloys can be used as an excellent surface finishing material.ial.

A Review of Graphene Plasmons and its Combination with Metasurface

  • Liu, Chuanbao;Bai, Yang;Zhou, Ji;Zhao, Qian;Qiao, Lijie
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.349-365
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    • 2017
  • Graphene has attracted a lot of attentions due to the unique electrical and optical properties. Compared with the noble metal plasmons in the visible and near-infrared frequencies, graphene can support surface plasmons in the lower frequencies of terahertz and mid-infrared and it demonstrates an extremely large confinement at the surface because of the particular electronic band structures. Especially, the surface conductivity of graphene can be tuned by either chemical doping or electrostatic gating. These features make graphene a promising candidate for plasmonics, biosensing and transformation optics. Furthermore, the combination of graphene and metasurfaces presents a powerful tunability for exotic electromagnetic properties, where the metasurfaces with the highly-localized fields offer a platform to enhance the interaction between the incident light and graphene and facilitate a deep modulation. In this paper, we provide an overview of the key properties of graphene, such as the surface conductivity, the propagating surface plasmon polaritons, and the localized surface plasmons, and the hybrid graphene/metasurfaces, either metallic and dielectric metasurfaces, from terahertz to near-infrared frequencies. Finally, there is a discussion for the current challenges and future goals.

Polyamic Acid Alkylamine Salts(PAAS) (Langmuir-Blodgett(LB) Films의 광학적 및 전기적 특성)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.277-280
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    • 1997
  • It is important to investigate the molecular arrangement and the orientational distribution in the study of LB films. Polarized UV/visible absorption spectra make it possible to reveal the molecular arrangement and the orientational distribution. It is clarified that the PAAS LB films have specific directions in the molecular arrangement and the orientational distribution, which art different in intensity corresponding to the surface pressure. Unpolarized UV/visible absorption spectra reveal that the surface pressure is proportional to the finn thickness and is related to the molecular orientation. Current-Voltage(I-V) measurements provide that the current decreases as the surface pressure increases and there are certain phenomena called switching phenomena. Switching effort indicates that the current flows in high conductivity during on-state and suddenly decreases into low conductivity during off-state.

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Melting of Ice Inside a Horizontal Cylinder under the Volume Change (수평원관내 체적변화를 고려한 얼음의 용용시 전열특성에 관한 연구)

  • 조남철;김동춘;이채탈;임장순
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1266-1274
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    • 2001
  • Heat transfer phenomena during melting process of the phase change material (ice) was studied by numerical analysis and experiments. In a horizontal ice storage tube, the natural convection caused an increase in melting rate. However, the reduction of the heating surface area caused a decrease in melting rate. Therefore, during the melting process of ice in a horizontal cylinder, the reduction of the heating surface area should be considered. Under the same heating wall and initial water temperature condition, the melting rate became higher for $V_s/V_tot/=0.545 \;than \;that\; for\; V_s/V_tot$/=1.00 due to the difference in the reduction of heating surface area. A modified melting model considering the equivalent thermal conductivity of liquid phase and volume reduction was proposed. The results of the model were compared with the measured values and found to be in good agreement.

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The Electromagnetic Shielding Effectiveness Using Conducting Polymers (전도성 고분자를 이용한 전자파 차폐효과)

  • 하남규;김종은;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.306-309
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    • 2000
  • The conductive polymers, polyaniline (PANI) emeraldine base and 3, 4-polyethylene dioxythiophene (PEDOT) were synthesized and coated on the PET film primer-dealt with acryl type to find out the electromagnetic shielding effectiveness. When conductive polymer such as PANI and PEDOT is used, if the thickness of coating increases then the electromagnetic shielding effectiveness increases, too, but the visible light transmittance decreases. For PANI, when its conductivity increased, its electromagnetic shielding effectiveness increased, too. For PANI, if the surface resistance is about 140 $\Omega$/$\square$, the shielding effectiveness is about 11 dB in the far field, and about 13 dB in the near field at 1 GHz. For PEDOT, when the surface resistance is about 200 $\Omega$/$\square$, the shielding effectiveness is about 3 dB.

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Correlating the hydraulic conductivities of GCLs with some properties of bentonites

  • Oren, A. Hakan;Aksoy, Yeliz Yukselen;Onal, Okan;Demirkiran, Havva
    • Geomechanics and Engineering
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    • v.15 no.5
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    • pp.1091-1100
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    • 2018
  • In this study, the relationships between hydraulic conductivity of GCLs and physico-chemical properties of bentonites were assessed. In addition to four factory manufactured GCLs, six artificially prepared GCLs (AP-GCLs) were tested. AP-GCLs were prepared in the laboratory without bonding or stitching. A total of 20 hydraulic conductivity tests were conducted using flexible wall permeameters ten of which were permeated with distilled deionized water (DIW) and the rest were permeated with tap water (TW). The hydraulic conductivity of GCLs and AP-GCLs were between $5.2{\times}10^{-10}cm/s$ and $3.0{\times}10^{-9}cm/s$. The hydraulic conductivities of all GCLs to DIW were very similar to that of GCLs to TW. Then, simple regression analyses were conducted between hydraulic conductivity and physicochemical properties of bentonite. The best correlation coefficient was achieved when hydraulic conductivity was related with clay content (R=0.85). Liquid limit and plasticity index were other independent variables that have good correlation coefficients with hydraulic conductivity (R~0.80). The correlation coefficient with swell index is less than other parameters, but still fairly good (R~0.70). In contrast, hydraulic conductivity had poor correlation coefficients with specific surface area (SSA), smectite content and cation exchange capacity (CEC) (i.e., R < 0.5). Furthermore, some post-test properties of bentonite such as final height and final water content were correlated with the hydraulic conductivity as well. The hydraulic conductivity of GCLs had fairly good correlation coefficients with either final height or final water content. However, those of AP-GCLs had poor correlations with these variables on account of fiber free characteristics.