• Title/Summary/Keyword: Surface concentration

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Effect of Residual Chlorine on the Analysis of Geosmin and 2-MIB Using SPME (Solid Phase Microextraction) (SPME를 이용한 Geosmin과 2-MIB분석 시 잔류염소의 영향에 관한 연구)

  • Kim, Sung-Jin;Hong, Seong-Ho;Min, Dal-Ki
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.6
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    • pp.713-719
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    • 2005
  • SPME (Soild phase microextraction) has been used in the analysis of many volatile organic compounds, such as geosmin and 2-methylisoborneol (2-MIB), trihalomethanes (THMs) in drinking water. SPME fiber is characterized by high adsorption capacity (DVB/CAR/PDMS, DVB/PDMS etc.). Although the highly active adsorption capacities of the SPME fiber are often to the chemical functional group, surface properties play a significant role in determining the surface adsorption capacities. The objectives of this study were to evaluate effect of residual chlorine on analysis of geosmin and 2-MIB. Image taken by SEM before preloaded with chlorine, the surface and porous media was almost perfect spherical shape and no clogging of pores. However, after preloaded with chlorine the surface was aggregated and pore was blocked. The recovery rate of geosmin and 2-MIB coexisting with chlorine was reduced by 35 to 62%. The recovery rate with preloaded with chlorine was reduced by 25 to 43%. The lower concentration of geosmin and 2-MIB and the higher concentration of chlorine existed in water, the lower the recovery rate was.

Sorption of Chromium Ions from Aqueous Solution onto Chemically Activated Carbons Developed from Maize Cobs

  • Youssef, A.M.;El-Nabarawy, Th.;Shouman, Mona A.;Khedr, S.A.
    • Carbon letters
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    • v.9 no.4
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    • pp.275-282
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    • 2008
  • Chemically activated carbons were prepared from maize cobs, using phosphoric acid of variable concentration. The textural parameters of the activated carbons were determined from the nitrogen adsorption isotherms measured at 77 K. The chemistry of the carbon surface was determined by measuring the surface pH, the pHPZC and the concentration of the carbon - oxygen groups of the acid type on the carbon surface. Kinetics of Cr(VI) sorption/reduction was investigated at 303 K. Two processes were investigated in terms of kinetics and equilibrium namely; Cr(VI) removal and chromium sorption were studied at various initial pH (1-7). Removal of Cr(VI) shows a maximum at pH 2.5. At pH<2.5, sorption decreases because of the proton competition with evolved Cr(III) for ion exchange sites. The decrease of sorption at pH>2.5 is due to proton insufficiency and to the decrease of the extent of Cr(VI) reduction. The chemistry of the surface of activated carbon is an important factor in determining its adsorption capacity from aqueous solutions particularly when the sorption process involves ion exchange.

The Physical Properties and Dyeability of KOH Treated Cotton Fabrics (KOH 처리 면직물의 물성 및 염색성)

  • Song, Hyun-Joo;Kim, Su-Mi;Song, Wha-Soon
    • Fashion & Textile Research Journal
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    • v.7 no.1
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    • pp.91-95
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    • 2005
  • The purpose of this study is to investigate the improvement of fiber surface, physical properties and research the physical properties and dyeability of cotton fabrics treated with KOH solution at low and high temperature. The treatment conditions for mercerization with KOH were changed various temperatures(25, $90^{\circ}C$), concentrations(15, 20, 25, 30%. w/v) and times(30, 60, 180, 300sec). The effects of mercerization after KOH treatment estimated with tensile strength, tearing strength, shrinkage, drape stiffness, moisture regain, fiber surface, and dyeability. The optimal conditions were concentration of KOH 20%, time 180sec in low temperature and concentration of KOH 20%, time 60sec in high temperature. The results are as follows; Tensile strength, tearing strength and moisture regain were much improved than those of untreated cotton fabric. Shrinkage and drape stiffness of KOH treated cotton were more increased at $25^{\circ}C$ than $90^{\circ}C$. Fiber surface showed more rounded shape at $25^{\circ}C$ than $90^{\circ}C$. Dyeability of cotton fabrics improved by KOH treatment.

Characterization of the SnAg Electrodeposits according to the Current Density and Cross-sectional Microstructure Analysis in the Cu Pillar Solder Bump (전류밀도에 따른 SnAg 도금층의 특성 및 Cu 필라 솔더 범프의 단면 미세구조 측정)

  • Kim, Sang-Hyuk;Hong, Seong-Ki;Yim, Hyunho;Lee, Hyo-Jong
    • Journal of the Korean institute of surface engineering
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    • v.48 no.4
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    • pp.131-135
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    • 2015
  • We investigated the surface morphology and the change of Ag concentration for SnAg electrodeposits according to the current density using labmade and commercial plating solutions. The concentration of Ag in the SnAg electrodeposits decreased with increasing the current density. The Ag concentrations at the conditions of over $50mA/cm^2$ were below 3 wt% and the surface was relatively smooth. Cu pillar bump was fabricated by using SnAg electroplating, and it was reflowed at $240^{\circ}C$ for 90 sec. The cross-sectional microstructure was investigated by using EBSD measurement and it was found that the grain size of SnAg became smaller by increasing the number of reflow treatments.

Electrochemical Corrosion Damage Characteristics of Alumium Alloy and Stainless Steel with Sea Water Concentration (알루미늄 합금 및 스테인리스강의 해수 농도 변화에 따른 전기화학적 부식 손상 특성)

  • Park, Il-Cho;Kim, Young-Bok;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.50 no.4
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    • pp.259-265
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    • 2017
  • 5000 series aluminium alloys and austenitic stainless steels have excellent corrosion resistance and sufficient strength, which are widely used as materials for marine equipment and their parts in the marine environment. The corrosion characteristics of materials are important factors for selecting the appropriate material due to fluid component changes in the estuarine and coastal areas where seawater and fresh water are mixed. Therefore, for 5083 Al alloy, STS304 and STS316L widely used in the marine environment, anodic polarization experiments were performed to compare the corrosion damage characteristics of each material by three kinds of solutions of 100 % tap water, 50 % tap water+50 % natural seawater and 100 % natural seawater. As a result of the anodic polarization experiments, aluminum alloy (5083) caused locally corrosion on the surface in the tap water, and corrosion damage occurred all over the surface when the seawater was included. Stainless steels (STS304 and STS316L) presented almost no corrosion damage in tap water, but they grew pitting corrosion damage with increasing seawater concentration. STS316L showed better corrosion resistance than STS304.

Study on effect of chemical impregnation on the surface and porous characteristics of activated carbon fabric prepared from viscose rayon

  • Bhati, Surendra;Mahur, J.S.;Dixit, Savita;Chobey, O.N.
    • Carbon letters
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    • v.15 no.1
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    • pp.45-49
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    • 2014
  • In this study, synthetic viscose rayon fabric has been used for preparing activated carbon fabric (ACF), impregnated with different concentrations of $H_3PO_4$. The effect of $H_3PO_4$ impregnation on the weight yield, surface area, pore volume, chemical composition and morphology of ACF were studied. Experimental results revealed that both Brunauer-Emmett-Teller surface area and micropore volume increased with increasing $H_3PO_4$ concentration; however, the weight yield and microporosity (%) decreased. It was observed that samples impregnated at $70^{\circ}C$ (AC-70) give higher yield and higher microporosity as compared to $30^{\circ}C$ (AC-30). The average pore size of the ACF also gradually increases from 18.2 to 19 and 16.7 to $20.4{\AA}$ for $30^{\circ}C$ and $70^{\circ}C$, respectively. The pore size distribution of ACF was also studied. It is also concluded that the final ACF strength is dependent on the concentration of impregnant.

A Study for Characteristics of Water that Penetrates Wood Flour due to Changes of Concentration of BDG (BDG 농도변화에 따른 용수의 목분 침투특성 연구)

  • Kong, Il-Chean;Park, Il-Gyu;Lim, Kyung-Bum;Rie, Dong-Ho
    • Journal of the Korean Society of Safety
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    • v.28 no.3
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    • pp.74-79
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    • 2013
  • As the feature of fire, it is hard for deep-seated fire to spread to the deeper site, and it also has danger for being re-ignited cause of recontacting with oxygen after being put off. Now it is ruled in the certification criteria of wetting agent used for extinguishing deep-seated fire that the criteria for surface tension is below 33[mN/m] in Korea. For figuring out how much water for fire-fighiting can permeate into combustibles, in this research, the permeating performance is analyzed by measuring the speed of permeating and transmission quantity released after that, by pouring solution whose surface tension is changed by adjusting concentration of surfactant BDG(Butyl Di Glycol) in column From this result, it is can be determined that transmission quantity becomes less and wet area goes wider as surface tension is lower, and it is also able to be analyzed as quantity of absorbed liquid and wet area is increased because fluid permeates into the core.

A study of CuCl$_{x}$ growth mechanism and etching with Cl$_2$ plasma and PEt$_3$(Tri-ethyl phospine) (Cl$_2$ 플라즈마를 인가한 CuCl$_{x}$성장 및 PEt$_3$를 이용한 CuCl$_{x}$의 식각에 대한 연구)

  • 박성언;김기범
    • Journal of the Korean institute of surface engineering
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    • v.30 no.2
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    • pp.111-120
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    • 1997
  • The growth kinetion of $CuCl_x$ layer on Cu was investigated using $Cl_2$ gas with/without plasma. The etching kinetics ofit was also studied, in which PEt3 gas as well as $Cl_2$ gas were used. when plasma and DC bias were applied, not only the growth rate of $CuCl_x$ layer but also the surface concentration of Cl in $CuCl_x$ layer drastically increased. The growth mode is divided into three regimes, where the thinkness $CuCl_x$ layer ise proportional to t, lo9g $T^{1/2}$ , respectively, whether plasma, is applied or not. These three regime. It is also identified that the eath rate of Cu is drastically increased as the $Cl_2$ pressure is increased. However, when plasma and DC bias were applied, the etching rate is decreased, and ClCu-P-U layer is formed. in addition, as the etching time is increased, the surface concentration of Cl is increased and $CuCl_2$ formed partially.

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Establishment of Best Management Indicator for Sustainable Agricultural Water Quality using Delphi Survey Method

  • Kim, Min-Kyeong;Jung, Goo-Bok;Hong, Seong-Chang;Kim, Myung-Hyun;Choi, Soon-Kun;Kwon, Soon-Ik;So, Kyu-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.5
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    • pp.379-383
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    • 2015
  • Indicators of environmental conditions describe the state of the environment and the quantity and quality of natural resources. This study deduced the evaluation items to assess each sub-indicator for agricultural water quality and conducted the surveying using the Delphi method based on agricultural water quality experts. Considering its importance, environmental, state, and management indicators showed that state indicator such as COD concentration for surface water and $NO_3-N$ concentration for groundwater was ranked as first and followed by amount of fertilizer. Its indicators were correlated with state and environmental indicators in surface water and groundwater. The best management indicators were calculated to assess the agricultural surface water and ground water quality. The indicator could be used in established policies for management and conservation of water resources.

Optimization of ultrasound-assisted extraction of glycyrrhizic acid from licorice using response surface methodology

  • Jang, Seol;Lee, A. Yeong;Lee, A. Reum;Choi, Goya;Kim, Ho Kyoung
    • Integrative Medicine Research
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    • v.6 no.4
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    • pp.388-394
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    • 2017
  • Background: The present study optimized ultrasound-assisted extraction conditions to maximize extraction yields of glycyrrhizic acid from licorice. Methods: The optimal extraction temperature ($X_1$), extraction time ($X_2$), and methanol concentration ($X_3$) were identified using response surface methodology (RSM). A central composite design (CCD) was used for experimental design and analysis of the results to obtain the optimal processing parameters. Results: Statistical analyses revealed that three variables and the quadratic of $X_1$, $X_2$, and $X_3$ had significant effects on the yields and were followed by significant interaction effects between the variables of $X_2$ and $X_3$ (p<0.01). A 3D response surface plot and contour plots derived from the mathematical models were applied to determine the optimal conditions. The optimum ultrasound-assisted extraction conditions were as follows: extraction temperature, $69^{\circ}C$; extraction time, 34?min; and methanol concentration, 57%. Under these conditions, the experimental yield of glycyrrhizic acid was 3.414%, which agreed closely with the predicted value (3.406%). Conclusion: The experimental values agreed with those predicted by RSM models, thus indicating the suitability of the model employed and the success of RSM in optimizing the extraction conditions.