• 제목/요약/키워드: Surface concentration

검색결과 6,123건 처리시간 0.037초

염소화 반응조건이 SBR의 표면마찰 특성에 미치는 영향 (The Effects of Chlorination on the Friction Properties of SBR)

  • 박차철;김호정
    • 한국의류산업학회지
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    • 제10권1호
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    • pp.101-105
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    • 2008
  • This study was concerned with the influence of reaction conditions on the surface friction properties of Syrene-Butadiene Rubber(SBR) sheet when it was chlorinated by chemical treatment method using the sodium hypochlorite and sulfuric acid. The results of this study were as follows. SEM photographs of chlorinated SBR surface showed uneven etching caused by the chlorination. In the FTIR spectra, the intensity of C=C peak of SBR was decreased with increasing the concentration of sodium hypochlorite. Otherwise there was no trace of C=C peak in spectrum of SBR treated with 5 wt% NaOCl with pH 0.1 for 90 seconds. EDX spectra showed that relative content of chlorine of SBR was increased with increasing the amount of sodium hypochlorite, and also affected with pH condition of acid solution. Friction angle and friction coefficient of SBR were influenced with concentration of sodium hypochlorite, but were not with pH condition of acid solution.

Hot-Spot 응력을 이용한 하중전달형 십자형 필렛 용접재의 피로강도 평가 (Fatigue Strength of the Load-Carrying Cruciform Fillet Welded Joints Using the Hot-Spot Stress)

  • 박종민;최원식;권순홍;노병욱
    • 한국기계가공학회지
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    • 제6권1호
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    • pp.20-26
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    • 2007
  • In this study, fatigue strength of load-carrying cruciform fillet welded joints were evaluated using a new method proposed by Yamada, for geometric or structural stress in welded joint, that is, one-millimeter stress below the surface in the direction corresponding to the expected crack path. Validity of the method is verified by analyzing fatigue test results for load-carrying cruciform welded specimens has different size of weld toe radius, leg length and plate thickness reported in literature. Structural stress concentration factor for 1mm below the surface was calculated by finite element analysis for each specimen respectively. When compared to the basic fatigue resistance curve offered by BS7608, the one-millimeter stress method shows conservative evaluation for load-carrying cruciform fillet welded joints.

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Ferrography에 의한 마멸분 정량분석

  • 오성모;이봉구
    • 대한기계학회논문집A
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    • 제24권10호
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    • pp.2420-2427
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    • 2000
  • In contacting between surface, there is wear and the generation of wear particles. The particles contained in the lubricating oil carry detailed and important information about the condition monitoring of the machine. Therefore, This paper was undertaken for Ferrography system of wear debris generated from lubricated moving machine surface. The lubricating wear test was performed under different experimental conditions using the Falex wear test of Pin and V-Block type by Ti(C,N) coated. It was shown from the test results that wear particle concentration(WPC) ; wear severity Index(IS) and size\distribution have come out all the higher value by increases sliding friction time. By the Ferrogram a thin leaf wear debris as well as ball and plate type wear particles was observed.

Oxidation of Chromium(III) to Chromium (VI) by Manganese Oxides : Variability in Mineralogy

  • Kim, Jae Gon
    • 한국암석학회:학술대회논문집
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    • 한국암석학회 1999년도 춘계학술대회
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    • pp.25-29
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    • 1999
  • Manganese (Mn) oxides in soils and sediments differ in structure and composition. The influence of that diversity on the chromium (Cr) oxidation is the subject of this report. Oxidation of Cr(III) to Cr(VI) by coarse clay size Mn oxides (synthetic pyrolusite and natural lithiophorite, todorokite, and bimessite) was studied. Chromium oxidation by Mn oxides was initially fast and followed by a slow reaction. More Cr was oxidized by the Mn oxides at lower pH and higher initial Cr(III) concentration in solution. Birnessite had the highest chromium oxidation capacity per unit external surface area (COCUESA) and lithiophorite had the lowest COCUESA. The kinetics of Cr oxidation and COCUESA of Mn oixdes were apparently controlled by reactivity of surface Mn, mineralogy, and solution properties (pH and Cr(III) concentration).

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염분침투에 의한 해안 콘크리트 구조물의 철근부식에 관한 실험적 연구 (A Exprimental Study on the Corrosion of Reinforcing Steel in a Coastal Concrete Structure due to the Attack of Chloride Ions)

  • 안상섭;김은겸;신치범;조원일;이윤한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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    • pp.263-268
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    • 1997
  • One of the principal causes of the deterioation of coastal concrete structures is the corrosion of reinforcing steel induced by the attack of chloride ions. An experimental study was performed to investigate the distribution of concentration of chloride ions in a coastal concrete structure and to measure the half-cell potential of embedded steel by using the copper-copper sulfate reference electrode. Quantitative analysis showed that the concentration of chloride ion in the aqueous phase near the surface of embedded steel exceeded a threshold value for corrosion, 0.05% by weight in concrete. The absolute value of half-cell potential at some members of embedded steel was measured to be higher than 350mV, indicating that the probability of corrosion is more than 90%. The prediction on corrosion based on the experimental measurements was confirmed by the observation of corrosion on the surface of steel bars in the concrete core taken out of the concrete structure.

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PECVD법에 의해 제조된 Sb-doped $SnO_2$ 박막의 증착거동 및 전기적 특성 (Deposition Behaviors and Electrical Properties of Sb-doped $SnO_2$ Films by Plasma Enhanced Chemical Vapor Deposition)

  • 김근수;서지윤;이희영;김광호
    • 한국세라믹학회지
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    • 제37권2호
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    • pp.194-200
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    • 2000
  • Sb-doped tin oxide films were deposited on Corning glass 1737 substrate by plasma enhanced chemical vapor deposition(PECVD) technique using a gas mixture of SnCl4/SbCl5/O2/Ar. The deposition behaviors of tin oxide films by PECVD were compared with those by thermal CVD, and effects of deposition temperature, r.f. power and Sb doping on the electrical properties of tin oxide films were investigated. PECVD technique largely increased the deposition rate and smoothed the surface of tin oxide films compared with thermal CVD. Electrical resistivity decreased with doping of Sb due to the increase of carrier concentration. However, large doping of Sb diminished carrier concentration and mobility due to the decrease of crystallinity, which resulted in the increase of electrical resistivity. As the deposition temperature and r.f. power increased, Cl content in the film decreased.

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청정지역과 도시지역의 오존농도 특성 연구 (A Study on the Characteristics of Rural and Urban Surface Ozone Conentrations)

  • 서명석;박경윤;이호근;장광미;강창희;허철구;김영준
    • 한국대기환경학회지
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    • 제11권3호
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    • pp.253-262
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    • 1995
  • A study has been performed on the characteristics of rural and urban surface ozone concentration for the period of March 1992 to February 1993. The monitoring station of rural ozone is located at Kosan, Cheju and other urban monitoring stations are located at Seoul, Pusan and Kwangju. Rural's and urban's ozone data exhibit a distinct features in many ways. First, annual mean of rural ozone concentration os very high(42 ppbv) but urban's are very low(10 .sim.15 ppbv). Second, rural ozone data shows a seasonal variation with it's maximum in spring, and minimum in summer, but urban's show a seasonal variation with it's maximum in spring, and minimum in winter. Third, diurnal variation of rural data is very small but that of urban's are very large. Fourth, urban's data are extremely low(< 3 ppbv) and have no seasonal variations.

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질화후 붕사욕 침적에 의한 강의 내마모성 피복층 형성에 관한 연구 (Formation of Wear Resistant Layer on Steel by Immersion in Borax Bath After Nitriding)

  • 김선규;유정광
    • 한국표면공학회지
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    • 제28권6호
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    • pp.361-367
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    • 1995
  • When steels are heated at $1000^{\circ}C$ in a fused borax bath containing $V_2O_5$ and $B_4C$powders, vanadium carbide layers are formed on the steel surfaces. Since a decrease in carbon concentration and in microhardness in the substrate just below the carbide layer has been observed, gas nitrocarburizing and vanadium carbide forming processes were combined to form a V(C,N) type layer which prevented the decrease in carbon concentration in the substrate. EPMA analysis was done for this V(C,N) type layer. Hardness just below the layer and wear resistance properties of such treated specimens were investigated.

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황산크롬(III) 착화합물 수용액으로부터의 크롬전착 (Electrodeposition of Chromium from Chromiun(III) Sulfate Complexes in Aqueous Solutions)

  • 고석수;송진태
    • 한국표면공학회지
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    • 제21권4호
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    • pp.149-159
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    • 1988
  • Electrodeposition of chromium from low concentration chromjum (III) sulfate complexess in aqueous using sodium formate-glycine mixtures as a complexing agent was studied. In the bath formation, it is found that the optimum again temperature and time for equilibration of the electrolytes are nrcessary for 24 hrs at 45$^{\circ}C$and the optimum elecrical charge for low current electrolysis which might be produced Cr(II) ions in the electrolytes is necessary for minum 2Ah/$\ell$. The optmun concentration off standard electrolyte for main composition is 0.05M chromium(III) sulfate, 0.2M sodium formate-0.2M glycine, and I mMNaSCN as a catalysea, respectivwly. The standard electrolyte is shows good covering, good throwing power, and 6% of current efficiency (Cr(III)basis). The oppearance of electrodeposits shows att active bright chromium. The SEM morphology of the chromjum coating is observed as smooth surfaces and dispersed micro prcro pores. X-ray diffraction analysis shows a bcc structure which the perferred orintation of the chromium electrodeposits is strongin(200)plane.

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염 추출법에 의한 폴리락틱산 다공성 지지체 가공 (Preparation of Poly(lactic acid) Scaffolds by the Particulate Leaching)

  • 이지혜;이종록;강호종
    • 한국응용과학기술학회지
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    • 제20권4호
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    • pp.324-331
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    • 2003
  • Particulate leaching method for the preparation of porous PLLA scaffolds was carried out and especially, the effect of PLLA/$CHCl_3$ solution concentration on the salt leaching rate and the pore structure of PLLA scaffolds were considered. It was found that maintaining lower PLLA/$CHCl_3$ concentration and higher $CHCl_3$ evaporation temperature in the preparation of PLLA/NaCl mixtures resulted in the enhancement of salt leaching rat e and higher porosity. This is understood that those conditions could minimize the formation of dense PLLA layer on the surface of PLLA/NaCl mixture as well as introducing better porosity on the surface. Higher salt leaching temperature accelerated the salt leaching rate but it seems that there is no influence on the porosity of PLLA scaffolds.