• Title/Summary/Keyword: Surface concentration

Search Result 6,117, Processing Time 0.034 seconds

Ferrography에 의한 마멸분 정량분석

  • O, Seong-Mo;Lee, Bong-Gu
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.24 no.10 s.181
    • /
    • pp.2420-2427
    • /
    • 2000
  • In contacting between surface, there is wear and the generation of wear particles. The particles contained in the lubricating oil carry detailed and important information about the condition monitoring of the machine. Therefore, This paper was undertaken for Ferrography system of wear debris generated from lubricated moving machine surface. The lubricating wear test was performed under different experimental conditions using the Falex wear test of Pin and V-Block type by Ti(C,N) coated. It was shown from the test results that wear particle concentration(WPC) ; wear severity Index(IS) and size\distribution have come out all the higher value by increases sliding friction time. By the Ferrogram a thin leaf wear debris as well as ball and plate type wear particles was observed.

Oxidation of Chromium(III) to Chromium (VI) by Manganese Oxides : Variability in Mineralogy

  • Kim, Jae Gon
    • Proceedings of the Petrological Society of Korea Conference
    • /
    • 1999.06a
    • /
    • pp.25-29
    • /
    • 1999
  • Manganese (Mn) oxides in soils and sediments differ in structure and composition. The influence of that diversity on the chromium (Cr) oxidation is the subject of this report. Oxidation of Cr(III) to Cr(VI) by coarse clay size Mn oxides (synthetic pyrolusite and natural lithiophorite, todorokite, and bimessite) was studied. Chromium oxidation by Mn oxides was initially fast and followed by a slow reaction. More Cr was oxidized by the Mn oxides at lower pH and higher initial Cr(III) concentration in solution. Birnessite had the highest chromium oxidation capacity per unit external surface area (COCUESA) and lithiophorite had the lowest COCUESA. The kinetics of Cr oxidation and COCUESA of Mn oixdes were apparently controlled by reactivity of surface Mn, mineralogy, and solution properties (pH and Cr(III) concentration).

  • PDF

A Exprimental Study on the Corrosion of Reinforcing Steel in a Coastal Concrete Structure due to the Attack of Chloride Ions (염분침투에 의한 해안 콘크리트 구조물의 철근부식에 관한 실험적 연구)

  • 안상섭;김은겸;신치범;조원일;이윤한
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 1997.10a
    • /
    • pp.263-268
    • /
    • 1997
  • One of the principal causes of the deterioation of coastal concrete structures is the corrosion of reinforcing steel induced by the attack of chloride ions. An experimental study was performed to investigate the distribution of concentration of chloride ions in a coastal concrete structure and to measure the half-cell potential of embedded steel by using the copper-copper sulfate reference electrode. Quantitative analysis showed that the concentration of chloride ion in the aqueous phase near the surface of embedded steel exceeded a threshold value for corrosion, 0.05% by weight in concrete. The absolute value of half-cell potential at some members of embedded steel was measured to be higher than 350mV, indicating that the probability of corrosion is more than 90%. The prediction on corrosion based on the experimental measurements was confirmed by the observation of corrosion on the surface of steel bars in the concrete core taken out of the concrete structure.

  • PDF

Deposition Behaviors and Electrical Properties of Sb-doped $SnO_2$ Films by Plasma Enhanced Chemical Vapor Deposition (PECVD법에 의해 제조된 Sb-doped $SnO_2$ 박막의 증착거동 및 전기적 특성)

  • 김근수;서지윤;이희영;김광호
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.2
    • /
    • pp.194-200
    • /
    • 2000
  • Sb-doped tin oxide films were deposited on Corning glass 1737 substrate by plasma enhanced chemical vapor deposition(PECVD) technique using a gas mixture of SnCl4/SbCl5/O2/Ar. The deposition behaviors of tin oxide films by PECVD were compared with those by thermal CVD, and effects of deposition temperature, r.f. power and Sb doping on the electrical properties of tin oxide films were investigated. PECVD technique largely increased the deposition rate and smoothed the surface of tin oxide films compared with thermal CVD. Electrical resistivity decreased with doping of Sb due to the increase of carrier concentration. However, large doping of Sb diminished carrier concentration and mobility due to the decrease of crystallinity, which resulted in the increase of electrical resistivity. As the deposition temperature and r.f. power increased, Cl content in the film decreased.

  • PDF

A Study on the Characteristics of Rural and Urban Surface Ozone Conentrations (청정지역과 도시지역의 오존농도 특성 연구)

  • 서명석;박경윤;이호근;장광미;강창희;허철구;김영준
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.11 no.3
    • /
    • pp.253-262
    • /
    • 1995
  • A study has been performed on the characteristics of rural and urban surface ozone concentration for the period of March 1992 to February 1993. The monitoring station of rural ozone is located at Kosan, Cheju and other urban monitoring stations are located at Seoul, Pusan and Kwangju. Rural's and urban's ozone data exhibit a distinct features in many ways. First, annual mean of rural ozone concentration os very high(42 ppbv) but urban's are very low(10 .sim.15 ppbv). Second, rural ozone data shows a seasonal variation with it's maximum in spring, and minimum in summer, but urban's show a seasonal variation with it's maximum in spring, and minimum in winter. Third, diurnal variation of rural data is very small but that of urban's are very large. Fourth, urban's data are extremely low(< 3 ppbv) and have no seasonal variations.

  • PDF

Formation of Wear Resistant Layer on Steel by Immersion in Borax Bath After Nitriding (질화후 붕사욕 침적에 의한 강의 내마모성 피복층 형성에 관한 연구)

  • 김선규;유정광
    • Journal of the Korean institute of surface engineering
    • /
    • v.28 no.6
    • /
    • pp.361-367
    • /
    • 1995
  • When steels are heated at $1000^{\circ}C$ in a fused borax bath containing $V_2O_5$ and $B_4C$powders, vanadium carbide layers are formed on the steel surfaces. Since a decrease in carbon concentration and in microhardness in the substrate just below the carbide layer has been observed, gas nitrocarburizing and vanadium carbide forming processes were combined to form a V(C,N) type layer which prevented the decrease in carbon concentration in the substrate. EPMA analysis was done for this V(C,N) type layer. Hardness just below the layer and wear resistance properties of such treated specimens were investigated.

  • PDF

Electrodeposition of Chromium from Chromiun(III) Sulfate Complexes in Aqueous Solutions (황산크롬(III) 착화합물 수용액으로부터의 크롬전착)

  • 고석수;송진태
    • Journal of the Korean institute of surface engineering
    • /
    • v.21 no.4
    • /
    • pp.149-159
    • /
    • 1988
  • Electrodeposition of chromium from low concentration chromjum (III) sulfate complexess in aqueous using sodium formate-glycine mixtures as a complexing agent was studied. In the bath formation, it is found that the optimum again temperature and time for equilibration of the electrolytes are nrcessary for 24 hrs at 45$^{\circ}C$and the optimum elecrical charge for low current electrolysis which might be produced Cr(II) ions in the electrolytes is necessary for minum 2Ah/$\ell$. The optmun concentration off standard electrolyte for main composition is 0.05M chromium(III) sulfate, 0.2M sodium formate-0.2M glycine, and I mMNaSCN as a catalysea, respectivwly. The standard electrolyte is shows good covering, good throwing power, and 6% of current efficiency (Cr(III)basis). The oppearance of electrodeposits shows att active bright chromium. The SEM morphology of the chromjum coating is observed as smooth surfaces and dispersed micro prcro pores. X-ray diffraction analysis shows a bcc structure which the perferred orintation of the chromium electrodeposits is strongin(200)plane.

  • PDF

Preparation of Poly(lactic acid) Scaffolds by the Particulate Leaching (염 추출법에 의한 폴리락틱산 다공성 지지체 가공)

  • Lee, Ji-Hae;Lee, Jong-Rok;Kang, Ho-Jong
    • Journal of the Korean Applied Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.324-331
    • /
    • 2003
  • Particulate leaching method for the preparation of porous PLLA scaffolds was carried out and especially, the effect of PLLA/$CHCl_3$ solution concentration on the salt leaching rate and the pore structure of PLLA scaffolds were considered. It was found that maintaining lower PLLA/$CHCl_3$ concentration and higher $CHCl_3$ evaporation temperature in the preparation of PLLA/NaCl mixtures resulted in the enhancement of salt leaching rat e and higher porosity. This is understood that those conditions could minimize the formation of dense PLLA layer on the surface of PLLA/NaCl mixture as well as introducing better porosity on the surface. Higher salt leaching temperature accelerated the salt leaching rate but it seems that there is no influence on the porosity of PLLA scaffolds.

Environmental Pollutants Drained From Highway Pavement Road

  • Takemura, Shinsaku;Goto, Naoshige;Mitamura, Osamu
    • Korean Journal of Ecology and Environment
    • /
    • v.38 no.spc
    • /
    • pp.58-61
    • /
    • 2005
  • Environmental polluting materials from road surface drainage are a significant nonpoint source influenced to the eutrophication of lake and ecosystems with a transport development in recent years. To elucidate the discharge characteristics, the changing patterns in concentrations of polluting materials such as suspended solid (SS), chemical oxygen demand (COD), nitrogenous and phosphorus nutrients in drainage waters, were investigated during rainfall. Load variation of COD concentration in drainage water samples was closely related to that of SS concentration. This indicates that SS contained a greater part of organic matter. A quite difference between the past pavement and the new well-drainage pavement system was observed in the concentrations of SS and COD in drainage waters. Appreciable concentrations of nitrite and nitrate were determined in drainage waters. The present results indicate that the drainage water from road surfaces is a significant nonpoint source, and that the well-drainage pavement system introduced to skid prevention has an effect on the decreases of pollutants.

유성지역 소유역에서 추적자(Cl)를 이용한 강우사상에 따른 지표수로부터 기저유출의 분리

  • Jo Seong-Hyeon;Ha Gyu-Cheol;Go Dong-Chan;Jo Min-Jo;Song Mu-Yeong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2005.04a
    • /
    • pp.352-358
    • /
    • 2005
  • This study aims to separate hydrograph into baseflow and event water to calculate baseflow rate during a rainfall in small catchments, Yuseong, Daejeon, The hydrograph of stream during a period with no excess rainfall will decay. The discharge is composed entirely of groundwater contributions. During the period, the Cl concentration of the stream water can be regarded as being in equilibrium with that of the groundwater. Using Cl as a conservative tracer, two-component hydrograph separations were performed from end point of the period to next end point. The required data were obtained by monitoring of the surface water table, along with discharge rate of stream. Cl concentration of rainfall, surface water were measured and recorded. Hydrograph separation, a mixing model using chemical tracer is applied to chemical hydrograph separation technique. These results show that baseflow rates are 31.6% of rainfall in the catchments during study period.

  • PDF