• Title/Summary/Keyword: Surface composition

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Hot Corrosion Behavior of Plasma Sprayed 4 mol% Y2O3-ZrO2 Thermal Barrier Coatings with Volcanic Ash (플라즈마 용사법으로 제작된 4mol% Y2O3-ZrO2 열차폐코팅의 화산재에 의한 고온열화거동)

  • Lee, Won-Jun;Jang, Byung-Koog;Lim, Dae-Soon;Oh, Yoon-Suk;Kim, Seong-Won;Kim, Hyung-Tae;Araki, Hiroshi;Murakami, Hideyuki;Kuroda, Seiji
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.353-358
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    • 2013
  • The hot corrosion behavior of plasma sprayed 4 mol% $Y_2O_3-ZrO_2$ (YSZ) thermal barrier coatings (TBCs) with volcanic ash is investigated. Volcanic ash that deposited on the TBCs in gas-turbine engines can attack the surface of TBCs itself as a form of corrosive melt. YSZ coating specimens with a thickness of 430-440 ${\mu}m$ are prepared using a plasma spray method. These specimens are subjected to hot corrosion environment at $1200^{\circ}C$ with five different duration time, from 10 mins to 100 h in the presence of corrosive melt from volcanic ash. The microstructure, composition, and phase analysis are performed using Field emission scanning electron microscopy, including Energy dispersive spectroscopy and X-ray diffraction. After the heat treatment, hematite ($Fe_2O_3-TiO_2$) and monoclinic YSZ phases are found in TBCs. Furthermore the interface area between the molten volcanic ash layers and YSZ coatings becomes porous with increases in the heat treatment time as the YSZ coatings dissolved into molten volcanic ash. The maximum thickness of this a porous reaction zone is 25 ${\mu}m$ after 100 h of heat treatment.

Properties of Carbon-Rich Particles and Purified Ash Obtained from Countercurrent Column Flotation (부유분리법에 의해 분리한 고순도 정제석탄회와 고탄소 석탄회의 특성)

  • 이정언;안영철;김성찬;구재현;나성수;신진혁;이재근
    • Resources Recycling
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    • v.8 no.4
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    • pp.11-19
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    • 1999
  • Fly ash generated from (he pulverized coal power plant have caused the serious ocean pollution due to the disposal in the ash pond, the life reduction of a power plant and the waste of re-utilizable resource The research to reuse the unburned carbon and mineral composing of the ash has been progressed. In this study. the physical and chemical characteristics of high grade ash and unburned carbon particles obtained from countercurrent column flotation are investigated. The cleaned ash of the less 0,5% loss on Ignition(LOI) in carbon content is a spherical sphere and 39.8${\mu}m$ in size of MMD(Mass Median Diameter). 2.22 $m^2/g$ of specific area. The morphology of high LOI carbon particles is a amorphousness, 76.6 ${\mu}m$ of particle size and 15.2 $m^2/g$ of specific The high grade cleaned ash and the high LOI ash have some difference in the light of physical. chemical and morphological characteristics

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Correlation between Measured Resting Energy Expenditure and Predicted Basal Energy Expenditure in Female College Students (여대생을 대상으로 한 실측 휴식대사량과 예측 기초대사량의 상관관계에 관한 연구)

  • Chang, Un-Jae;Lee, Kyeong-Ryeong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.2
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    • pp.196-201
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    • 2005
  • The aim of this study was to confirm the validity of predictive equations for the calculation of basal energy expenditure (BEE). One hundred twenty female college students were participated in this study. The resting energy expenditure (REE) was measured by indirect calorimetry for 30 minutes following an 12 hour overnight fasting. Among the available equations for predict BEE, Harris-Benedict, WHO/FAO/UNU and Cunningham methods were selected. Body composition was estimated by bioelectrical impedance analysis (BIA) for the equation of predicted BEE. The mean of measured REE was 1257.2$\pm$147.9 kcal/day, while the predicted value by Harris-Benedict, WHO/FAO/UNU and Cunningham were 1373.3$\pm$45.4 kcal/day, 1290.0$\pm$61.7 kcal/day and 1187.6$\pm$49.2 kcal/day, respectively. The Cunningham equation was more closed to measured values than Harris-Benedict and WHO/FAO/UNU equation by the correlation coefficient. Comparing Pearson's correlation coefficients, fat-free mass (FFM), body surface area (BSA) and body weight were higher than others such as height, body mass index (BMI), fat and fat%. The FFM's correlation coefficient was the highest as 0.74. Thus, the conclusion of this study suggested that the main determinant of BEE was FFM, and we derived a prediction equation as follows: BEE=-569.86+48.27 (FFM).

Research Trend of Soft Magnetic Composite Materials with High Energy Efficiency (고에너지효율 연자성 복합 분말 소재의 연구개발 동향)

  • Kim, Hwi-Jun
    • Journal of the Korean Magnetics Society
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    • v.21 no.2
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    • pp.77-82
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    • 2011
  • The use of soft magnetic materials have been increasing in the various industrial fields according to the increasing demand for high performance, automatic, miniaturing equipments in the recent our life. In this study, we investigated the effect of factors on the core loss and magnetic properties of electrical steel and soft magnetic composites. Furthermore, we reviewed the major efforts to reduce the core loss and improve the soft magnetic properties in the two main soft magnetic materials. Domain purification which results from reduced density of defects in cleaner electrical steels is combined with large grains to reduce hysteresis loss. The reduced thickness and the high electrical conductivity reduce the eddy current component of loss. Furthermore, the coating applied to the surface of electrical steel and texture control lead to improve high permeability and low core loss. There is an increasing interest in soft magnetic composite materials because of the demand for miniaturization of cores for power electronic applications. The SMC materials have a broad range of potential applications due to the possibility of true 3-D electromagnetic design and higher frequency operation. Grain size, sintering temperature, and the degree of porosity need to be carefully controlled in order to optimize structure-sensitive properties such as maximum permeability and low coercive force. The insulating coating on the powder particles in SMCs eliminates particle-to-particle eddy current paths hence minimizing eddy current losses, but it reduces the permeability and to a small extent the saturation magnetization. The combination of new chemical composition with optimum powder manufacturing processes will be able to result in improving the magnetic properties in soft magnetic composite materials, too.

Fruit and seed morphology of Korean Ranunculaceae (한국산 미나리아재비과의 열매 및 종자 형태)

  • Jung, Woo-Chul;Heo, Kweon
    • Korean Journal of Plant Taxonomy
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    • v.47 no.2
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    • pp.137-153
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    • 2017
  • Fruit and seed morphological characteristics were investigated in 36 taxa of 20 genera of Korean Ranunculaceae. As a result, fruits were classified as the achene, berry, or follicle type. In the taxa with achene, the presence of trichomes and stoma on the surface of the fruit and a feature in which the endocarp distinctively develops into a one-layer sclereid were considered as useful characteristics. Moreover, in the taxa with follicles, the composition of the seed coat (bitegmic vs. unitegmic), the cell shape of the seed coat, the presence of trichomes, and the type of seed coat were useful for taxonomic characteristics in Korean Ranunculaceae. Based on the fruit and seed characteristics, Adonis is likely to be classified into Helleboroideae rather than Ranunculoideae, as it has bitegmic ovules. In addition, Enemion is similar to Eranthis in unitegmic ovule and the seed coat structure which has non-sclereid exotesta; therefore, it is reasonable to be placed in Helleboroideae. According to the results of this study, more in-depth research is needed regarding the taxonomic positions of Callianthemum and Actaea, which has the only berry fruit type.

Influence of Some Commercially Available Mouthwashes on Teeth (일부 시판 구강양치액이 치아에 미치는 영향)

  • Min, Ji-Hyun
    • Journal of dental hygiene science
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    • v.18 no.4
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    • pp.265-270
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    • 2018
  • The purpose of this study was to investigate the chemical properties of some commercially available mouthwashes and to ascertain whether the mouthwashes accelerated mineral loss in dental enamel. Five commercially available mouthwashes were selected from the three largest malls in Korea: Perio Total 7 Aqua Cool Mint Strong $Fresh^{TM}$ (PS; LG Household & Health Care Ltd.), Garglin $Original^{TM}$ (Dong-A Pharmaceutical Co., Ltd.), Garglin $Zero^{TM}$ (Dong-A Pharmaceutical Co., Ltd.), Listerine Naturals $Citrus^{TM}$ (LC; IDS Manufacturing Ltd.), and Listerine Cool $Mint^{TM}$ (LM; IDS Manufacturing Ltd.). The composition, pH, and titratable acidity of the mouthwashes were investigated. Six bovine teeth specimens were prepared for each mouthwash group. Each of the six specimens was individually immersed in 30 ml aliquots of mouthwash for 1 minute, 30 minutes, 90 minutes, and 120 minutes, and the samples were placed in a $36.5^{\circ}C$ stirred incubator. The degree of mineral loss (${\Delta}F$) of the tooth surface area exposed to mouthwash, compared with normal teeth, was analyzed by quantitative light-induced fluorescence-digital. The difference in ${\Delta}F$ among mouthwash groups was examined by the Kruskal-Wallis H test (${\alpha}=0.05$). The contents of mouthwashes differed between Listerine and other products, and the pH ranged from 4.09 to 6.75. The titratable acidity of PS was the lowest at 0.63 ml and highest at 9.25 ml for LM. Minor mineral loss was observed when dental specimens were immersed in the Listerine products (LC and LM) for more than 90 minutes, but the degree of mineral loss for Listerine products was not statistically significantly different from that for groups without mineral loss. In conclusion, all five commercially available mouthwashes showed no harmful effects on tooth enamel.

Synthesis and Characterization of Hybrid Nanocomposites of Pd Nanoparticles Containing POSS(Pd-POSS) and Poly(acrylic acid) via Ionic Interactions (실세스키옥세인을 포함한 팔라듐 나노입자와 폴리아크릴산과의 이온결합에 의한 나노복합체 제조 및 특성평가)

  • Jeon, Jong-Hwan;Lim, Jung-Hyurk;Chujo, Yoshiki;Kim, Kyung-Min
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.615-619
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    • 2009
  • Pd-POSS nanoparticles were produced from the reaction of palladium (II) acetate and octa(3-aminopropyl)octasilsesquioxane octahydrochloride (POSS-${NH_3}^+$) in methanol at room temperature. Pd-POSS nanoparticles with a mean diameter of 60-80 nm were the highly ordered spherical aggregates. In contrast, Pd nanoparticles with a size of 4.0 nm were obtained when POSS-${NH_3}^+$ was not introduced. Pd-POSS/PAA nanocomposites of Pd-POSS nanoparticles and poly(acrylic acid) (PAA) were fabricated by utilizing ionic interactions between positively charged Pd-POSS nanoparticles and negatively charged carboxylate groups of PAA. PAA was used as a cross-linker for the preparation of hybrid nanocomposites with the controlled organized structures of Pd-POSS nanoparticles. That is, the self-organization of Pd-POSS nanoparticles was formed into the shape of continuous lines by using PAA as a cross-linker. The composition, structure, surface morphology, and thermal stability of the Pd-POSS/PAA nanocomposites were studied by FE-SEM, AFM, TEM, FT-IR, and TGA.

Synthesis and Effect of Plasma Treatment of Acrylic Composite Particle Binder (아크릴계 복합입자 바인더의 제조와 플라즈마 처리영향)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.276-283
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    • 2008
  • Kind of monomer(MMA, EA, BA, St)and the monomer ratio(80/20 to 20/80) where changed in the preparation of the core shell binder, and property was improved the plasma processing. Each material changed by plasma treatment time($1{\sim}10\;s$) to change to measure the tensile strength, contact angle and adhesion peel strength for the core shell binder optimal conditions for handling the output of the surface treatment. The type of polymerization and composition of the binder is a regardless initiator of APS, the reaction temperature of $85^{\circ}C$ to 0.3 wt% of the surfactant used to indicate when the conversion rate was the highest, core shell composite particle binder got two glass temperature curves. Core shell binder after the plasma processing contact angle change is the PEA/PSt 38 percent of cases within five seconds to indicate slight decrease was a decline rapidly if not handled $0^{\circ}$ to reach. Tensile strength PSt/PMMA varies $46.71{\sim}46.27\;kg_f$/2.5 cm and adhesion strength PEA/PMMA varies $7.89{\sim}14.44\;kg_f$/2.5 cm increases. Overall, adhesion strength of core shell composite particle is in the order of order PEA>PBA>PSt for shell monomer MMA.

Properties and Provenance of Loess-paleosol Sequence at the Daebo Granite Area of Buan, Jeonbuk Province, South Korea (전북 부안 화강암지역 뢰스-고토양 연속층의 퇴적물 특성과 기원지)

  • Park, Chung-Sun;Hwang, Sang-Ill;Yoon, Soon-Ock
    • Journal of the Korean Geographical Society
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    • v.42 no.6
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    • pp.898-913
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    • 2007
  • We examined soil properties and provenance of loess-paleosol sequences at the Daebo Granite area of Buan, Jeonbuk Province, South Korea. The section consists of the surface layer, Layer 1(paleosol), Layer 2(loess), Layer 3(paleosol), Layer 4(loess), and Layer 5(paleosol), from top to bottom and thickness of the exposed section is approximately 280cm. The magnetic susceptibility values show the distinct variations between the loess- and the paleosol layer. Even though pH, ORP, water content, and soil hardness do not display the obvious differences in the section, the organic content indicates the variation similar to those of the magnetic susceptibility. In the respect of the soil colors measured under 3 conditions, although the variations of the wet soil color exceedingly reflect the difference of the layers, these variations are obscure in some points in the section due to the characteristics of the Munsell color system. Based on the geomorphological properties, sedimentary structure, the difference of the major element composition and the condrite-normalized rare earth element(REE) patterns showing the clear difference from the adjacent bedrocks and stream sediments and the similarity to those of the Chinese Loess Plateau, it is suggested that the section was formed by the material originated from the Chinese Loess Plateau and peripheral areas. However, because the material experienced the alteration after sedimentation under the environment of the sediment area, it has the properties different from the material in the provenance areas. This phenomenon may result in the climatic condition of Korea, especially in precipitation.

Geochemistry of Mn Scales Formed in Groundwater in the Damyang Area (담양 지역 음용 지하수에 형성된 망간 스케일에 대한 지구화학)

  • Park, Cheon-Young;Kim, Seoung-Ku;Shin, In-Hyun;Ahan, Kun-Sang;Kim, Young-In
    • Journal of the Korean earth science society
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    • v.27 no.3
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    • pp.313-327
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    • 2006
  • This study investigated the geochernical characteristics of Mn scale formed in groundwater wells at the Damyang area. The composition of Mn scale consists mainly of MnO and $SiO_2$. The content of Mn ranges from56.61wt.% to 68.69wt.%, and $SiO_2$ content ranges from 1.56wt.% to 10.45wt.%. The contents of Mo and Ba in Mn scale increased with increased depth; whereas, the content of Zn and Pb decreased with increased depth. Birnessite, quartz and feldspars were identified in Mn scales using x-ray powder diffraction studies. The IR absorption bands for Mn scales show major absorption band due to OH stretching, adsorbed molecular water, and birnessite stretching, respectively. In the SEM and EDS analysis, the Mn scale consists of botryoidal, spherical, spherulite, and empty straw structure. Those structure may be precipitated simply due to oversaturation with concentrated Mn content or may be formed through biogenic precipitation by Lepthothrix discophora. Under microanalysis using EDS on those structure surface of Mn scales, the Mn atomic percent range from 28 to 44, and such elements revealed the presence of Si, K, Na, Ca, Cl, Cu, Zn, and Ba.