• Title/Summary/Keyword: Surface composition

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Surface Photovoltage of $Al_{0.3}$$Ga_{0.7}$As/GaAs Multi-Quantum Well Structures ($Al_{0.3}$$Ga_{0.7}$As/GaAs 다중 양자 우물 구조의 표면 광전압에 관한 연구)

  • 이정열;김기홍;손정식;배인호;김인수;박성배
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.1
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    • pp.21-27
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    • 2000
  • We used the surface photovoltage spectroscopy(SPVS) for characterization of GaAs/Al\ulcornerGa\ulcornerAs multi-quantum well(MQW) structures grown by molecular beam epitaxy(MBE) method. Energy gap related transitions in GaAs and AlGaAs were observed. The Al composition(x=0.3) was determined by Sek's composition formula. Transition energies in MQW were determined using the differential surface photo-volatage spectroscopy)DSPVS) of the measured resonanced. In order to indentify the transitions, the experimentally observed energies were compared with results of the envelope function approximation for a rectangular quantum well. We have observed and interesting behavior of the temperature dependence(80K~300K) of the 11Hand 11L transition for sample.

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Surface and Interface Analysis with Medium Energy Ion Scattering Spectroscoppy

  • Moon, Dae-Wom
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.129-129
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    • 1998
  • Most of the surface/interface analysis tools have limited depth profiling c capability in terms of the profiling range and the depth resolution. However, M MEIS can profile the surface and subsurface composition and structure q quantitatively and non-destructively with atomic layer depth resolution. I In this presentation, the MEIS system developed at KRISS will be briefly d described with an introduction on the principle of MEIS. Recent MEIS r results on the surface and interface composition and structural change due to i ion bombardment will be presented for preferential sputtering of T:없Os and d damage depth profiles of SHooD, Pt(l11), and Cu(l1D due to Ar+ ion b bombardment. Direct observation of strained Si lattices and its distribution i in the SHool)-SiCh interface and the initial stage of Co growth on Pt(l11) w will be reported. H surfactant effects on epitaxial growth of Ge on Si(ooD w will be discussed with STM results from SND.

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Effect of Electrical Properties on the EPDM- $Al(OH)_3$ Composite by UV Accelerated weathering (Al(OH)3가 EPDM의 자외선 촉진열화에 미치는 전기적 특성평가)

  • Shim, Dae-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.243-247
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    • 2003
  • The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

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New Response Surface Approach to Optimize Medium Composition for Production of Bacteriocin by Lactobacillus acidophilus ATCC 4356

  • RHEEM, SUNGSUE;SEJONG OH;KYOUNG SIK HAN;JEE YOUNG IMM;SAEHUN KIM
    • Journal of Microbiology and Biotechnology
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    • v.12 no.3
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    • pp.449-456
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    • 2002
  • The objective of this study was to optimize medium composition of initial pH, tryptone, glucose, yeast extract, and mineral mixture for production of bacteriocin by Lactobacillus acidophilus ATCC 4356, using response surface methodology. A response surface approach including new statistical and plotting methods was employed for design and analysis of the experiment. An interiorly augmented central composite design was used as an experimental design. A normal-distribution log-link generalized linear model based on a subset fourth-order polynomial ($R^2$=0.94, Mean Error Deviance=0.0065) was used as an analysis model. This model was statistically superior to the full second-order polynomial-based generalized linear model ($R^2$=0.80, Mean Error Deviance=0.0140). Nonlinear programming determined the optimum composition of the medium as initial pH 6.35, typtone $1.21\%$, glucose $0.9\%$, yeast extract $0.65\%$, and mineral mixture $1.17\%$. A validation experiment confirmed that the optimized medium was comparable to the MRS medium in bacteriocin production, having the advantage of economy and practicality.

Investigation of Catalytic Activity Through Controlling Its Size and Composition of RhPt Bimetallic Nanoparticles (RhPt 이종금속 나노입자의 크기 및 조성 제어를 통한 촉매 활성도에 관한 연구)

  • Park, Jeong-Young;Kim, Sun-Mi
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.538-545
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    • 2011
  • This study shows that catalytic activity of bimetallic RhPt nanoparticle arrays under CO oxidation can be tuned by varying the size and composition of nanoparticles. The tuning of size of RhPt nanoparticles was achieved by changing concentration of rhodium and platinum precursors in one-step polyol synthesis. Two-dimensional RhPt bimetallic nanoparticle arrays in different size and composition were prepared through Langmuir-Blodgett thin film technique. CO oxidation was carried out on these two-dimensional nanoparticle arrays, revealing higher activity on the smaller nanoparticles compared to the bigger nanoparticles. X-ray photoelectron spectroscopy (XPS) results indicate the preferential surface segregation of Rh compared to Pt on the smaller nanoparticles, which is consistent with the thermodynamic analysis. Because the catalytic activity is associated with differences in the rates of $O_2$ dissociative adsorption between Pt and Rh, this paper suppose that the surface segregation of Rh on the smaller bimetallic nanoparticles is responsible for the higher catalytic activity in CO oxidation. This result suggests a control mechanism of catalytic activity via synthetic approaches of colloid nanoparticles, with possible application in rational design of nanocatalysts.

Compositional Study of Surface, Film, and Interface of Photoresist-Free Patternable SnO2 Thin Film on Si Substrate Prepared by Photochemical Metal-Organic Deposition

  • Choi, Yong-June;Kang, Kyung-Mun;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.1
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    • pp.13-17
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    • 2014
  • The direct-patternable $SnO_2$ thin film was successfully fabricated by photochemical metal-organic deposition. The composition and chemical bonding state of $SnO_2$ thin film were analyzed by using X-ray photoelectron spectroscopy (XPS) from the surface to the interface with Si substrate. XPS depth profiling analysis allowed the determination of the atomic composition in $SnO_2$ film as a function of depth through the evolution of four elements of C 1s, Si 2p, Sn 3d, and O 1s core level peaks. At the top surface, nearly stoichiometric $SnO_2$ composition (O/Sn ratio is 1.92.) was observed due to surface oxidation but deficiency of oxygen was increased to the interface of patterned $SnO_2/Si$ substrate where the O/Sn ratio was about 1.73~1.75 at the films. This O deficient state of the film may act as an n-type semiconductor and allow $SnO_2$ to be applied as a transparent electrode in optoelectronic applications.

Chemical Composition of Rice Hull and Morphological Properties of Rice Hull Fibers (왕겨의 화학적 조성 및 왕겨섬유의 형태적 특성)

  • Sung, Yong-Joo;Shin, Soo-Jeong;Oh, Min-Taek
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.3
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    • pp.22-28
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    • 2009
  • The rice hull could be the one of the most abundant agricultural waste in Korea. Since the efficient utilization of agricultural waste or byproducts of food industry would be critical for the sustainable growth, this study conducted the investigation of the chemical composition and the morphological properties of rice hull and rice hull fiber. It was found that there was big difference between the outer surface and the inner surface in the chemical composition and the morphological properties. Expecially, the outer surface showed the rugged patterns in which most of silica of rice hull existed. Little or no silica was found in the inner surface and rice hull fiber. The average fiber length of rice hull fiber was 0.45mm which was shorter than that of hardwood fiber. Rice hull fiber showed a round long shape which is typical shape of non-wood fibers

Identifying Factors Affecting Surface Roughness with Electropolishing Condition Using Full Factorial Design for UNS S31603 (UNS S31603에 대하여 완전요인설계를 이용한 전해연마조건에 따른 표면 거칠기의 유효인자 산출)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.4
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    • pp.314-324
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    • 2022
  • The objective of this investigation was to indentify major factors affecting surface roughness among various parameters of electropolishing process using the design of an experiment method (full factorial design) for UNS S31603. Factors selected included electrolyte composition ratio, applied current density, and electrolytic polishing time. They were compared through analysis of variance (ANOVA). Results of ANOVA revealed that all parameters could affect surface roughness, with the influence of electrolyte composition ratio being the highest. As a result of surface analysis after electropolishing, the specimen with the deepest surface damage was about 35 times greater than the condition with the smallest surface damage. The largest value of surface roughness after electropolishing was higher than that of mechanical polishing due to excessive processing. On the other hand, the smallest value of surface roughness after electropolishing was 0.159 ㎛, which was improved by more than 80% compared to the previous mechanical polishing. Taken all results together, it is the most appropriate to perform electrolytic polishing with a sulfuric acid and phosphoric acid ratio of 3:7, an applied current density of 300 mA/cm2, and anelectrolytic polishing time of 5 minutes.

Two New Species of Genus Suberites (Hadromerida: Suberitidae) from Korea

  • Shim, Eun-Jeong;Sim, Chung-Ja
    • Animal Systematics, Evolution and Diversity
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    • v.24 no.2
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    • pp.215-218
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    • 2008
  • Two new marine sponges in genus Suberites, S. hataedoensis n. sp and S. waedoensis n. sp have been collected from Hataedo Island and Waedo Island, Korea during 2005-2006. S. hataedoensis n. sp. is similar to S. durissimus in the spicule composition and texture. However, they differ in growth form, skeleton and surface. S. waedoensis n. sp. is similar to S. japonicus in spicule composition and skeleton. However, they differ in growth form, surface and texture.

Electroless Ni Plating on Pb-base Ceramics (Pb계 Ceramics 기지상의 무전해 Ni 도금)

  • 민봉기;유종수;최순돈;신현준
    • Journal of the Korean institute of surface engineering
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    • v.32 no.4
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    • pp.487-495
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    • 1999
  • In order to form metallic electrodes on PZT (Pb (Zr, Ti)O$_3$) ceramics, plating conditions for optimal electroless Ni deposition were investigated. Pb in PZT is the major component to inhibit the electroless deposition, because it plays a active role of catalytic poison in plating solution. Adhesion of the electroless Ni deposits is measured by push-pull scale test and peel test. Results such as deposition ability, deposition rate, and thickness of deposits showed in terms of concentration of etchant, composition of catalyzing solution, and composition and pH of electroless bath solution.

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