• Title/Summary/Keyword: Surface color change

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Study About Filling-Material for Clay Layer Restoration of Seated Amitabha Triad at Muwisa Temple (Treasure No. 1312) (보물 제1312호 무위사 아미타여래삼존좌상 소조층 보수 충전제에 관한 연구)

  • Lee, Su Yea
    • Journal of Conservation Science
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    • v.31 no.1
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    • pp.1-11
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    • 2015
  • Seated Amitabha Triad at Muwisa Temple (Treasure No. 1312) had been known as wooden Buddha statue, but a precise safety inspection revealed that the statue is terracotta Buddha statue made with clay. The clay layer of Amitabha Triad was conserved due to its severe damage. In this study, experiments were conducted to produce the most appropriate filler for the conservation treatment of the seated Amitabha Triad. Mixed clay samples with various ratios were produced and surface hardening state, crack, color change, and shrinkage of the samples during dry process were measured. Loess, fine sand powder, and cotton were used to produce the mixed clay for the filler with six different ratios and then 12 different concentration glues made with glutinous rice glue, Pachymeniopsis Elliptica glue, and animal glue were added as adhesives. Total 72 types of samples were prepared and comparative study was conducted. As a result, when the mixed clay contains 2.5% cotton compared to the weight per cent of loess and fine sand powder and also loess and fine sand in the mixed clay have a 15:1 ratio, the mixed clay had the lowest shrinkage. Animal glue is considered as an appropriate glue since it had small color change, low physical property change and shringkage. Therefore, mixed clay (loess:fine sand=15:1) mixed with 15ml animal glue is likely to be a suitable filler for conservation treatment of the seated amitabha triad at the Muwisa Temple.

A Study of Weather Resistance on Dancheong Ground Treatment of Tranditional Wooden Building in Korea (한국 목조건축물 단청 바탕처리에 대한 내후성 연구)

  • Kim, Young Kyun;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.480-493
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    • 2019
  • In this study, the method for processing glue and glue-alum sizing from the dancheong ground treatment was evaluated with respect to weather resistance, and its effect on the conservation of dancheong was analyzed. Viscosity and pH of the glue and glue-alum specimen were measured and classified into three categories(none layer, glue layer, and glue-alum layer), which were further classified according to low concentration(four times for 2%) and high concentration(once for 10%). The base layer formation was subsequently classified into three categories based on pigment adoption, namely, Noerok(celadonite), Seokganju(terra rossa), and Jangdan(red lead). The completed specimen was subjected to a changing-environment experiment for evaluating weather resistance and observing the surface. Color variations were analyzed before and after the experiment. The results indicate that glue-alum sizing comprising 5% alum or 7% alum has strong acidity that can affect the life of dancheong, and the high level of 7% alum makes it difficult to create a solid coating layer. After ultraviolet irradiation, the specimen with 7% alum changes its color to yellow. Furthermore, after moisture absorption and drying, cracks can be observed on the entire specimen surface that corroborate the physical change. Additionally, gas-based corrosion causes marginal surface changes. Hence, the formation of a stable coating layer can be achieved by incorporating a low concentration glue solution that is almost neutral, and the application of glue-alum sizing having 2% concentration can aid in the conservation of dancheong.

The Fabrication of HCD Ion Plating Apparatus and XPS Analysis on the Fine Color Changes of TiN Films on Stainless Steel (HCD 이온플레이팅 장치 제작 및 Stainless Steel 위에 TiN 박막의 미세색상변화에 따른 XPS분석)

  • Park, Moon Chan;Lee, Jong Geun;Choi, Kwang Ho;Cha, Jung Won;Kim, Eung Soon;Park, Jin Hong
    • Journal of Korean Ophthalmic Optics Society
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    • v.15 no.4
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    • pp.361-366
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    • 2010
  • Purpose: HCD ion plating apparatus by hollow cathod discharge method was fabricated and TiN films were deposited on stainless steel by this apparatus with increasing in $N_2$ gas flow and the fine color changes of TiN films were analyzed. Methods: The spectroradiometer and spectrophotometer were used to observe optically the fine color changes of TiN thin films, and XPS was used to analyze the compositions of TiN thin films with increasing in $N_2$ gas flow. Results: The color coordinate of TiN thin film with $N_2$ 120 sccm gas flow showed (0.382, 0.372) which had the mixed colors of gold and silver, and the color coordinate changed to the increasing value of (x,y) with increasing in $N_2$ gas flow which indicated the deep gold color. It was found that the slopes of the reflectances at 550nm were increased with increasing in $N_2$ gas flow. And from the Ti scans using XPS, it was found that the peak heights of 455 eV derived from TiN composition were increased with increasing in $N_2$ gas flow, while the peak heights of 459 eV from $TiO_2$ composition were decreased. Conclusions: The results obtained above were that the color of TiN film with 120 sccm $N_2$ gas flow had been observed from the mixed color of silver and gold due to TiC, $N_2$, TiN on the surface and TiN, $N_2$ inside film, and the color of TiN films changed a deep gold color with increasing in $N_2$ gas flow due to increasing TiN composition.

A Study on the Development of Improved Artificially Soiled Cloth and its Detergency (새로운 인공오염포의 제작과 그 세척성에 관한 연구)

  • Chung Doo Jin;Kim Mi Hyung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.3 s.31
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    • pp.207-222
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    • 1989
  • New process for the preparation of the artificially soild cloth (ASC) used for detergency evaluation was developed and its detergency was also studied. ASC was prepared by the dipping of cotton cloth in the water in which oily soil, protein (gelatine), carbon black and clay had been dispersed. The clay used for this ASC was red yellowish soil around Mt. Kumjung and was a typical soil in Pusan area. Adhesive status of soil at prepared ASc was examined by an electron microscope, and crystallyzation and color change of used clay were evaluated with the determination of X-ray diffraction and surface reflectance. For the evaluation of detergency by the washing with commercial and model detergents, the behavior of soil removal from this ASC comparing with naturally soiled collar cloth was examined. Those results are summerized as followings; 1) Adhesive ststus of soil at prepared ASc was very similar to that of naturally soiled collar cloth. 2) A crystalline of clay calcined at $800^{\circ}C$ was disappeared in part and color of calcined clay changed into reddish yellow by the decomposition of organic matters. 3) More uniform ASc was prepared with clay calcined at $800^{\circ}C\;that\;200^{\circ}C$ however its detergency prepared from clay calcined at $800^{\circ}C$ was poor 4) A significant relationship between the content of inorganic matter in ASc and K/S value was found, however no significant result between the content of protein contaminated and K/S value was observed. 5) Detergency of prepared ASc had a very similar to that of naturally soiled collar cloh.

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Heat Treatment and UV-Spectral Characteristics of Blue Sapphires from Shantung, China (청색(靑色) 사파이어의 열처리(熱處理)와 분광학적(分光學的) 특성(特性))

  • Na, Kyung-Ju;Kim, Won-Sa;Kim, Mun-Young;Bae, In-Kook;Jang, Young-Nam
    • Economic and Environmental Geology
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    • v.26 no.1
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    • pp.107-114
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    • 1993
  • For the blue sapphires from Santung, China, the color change before and after has been investigated by UV-Visible spectrophotometry method. The blue sapphires from Shantung show four groups of absorption bands: the bands A (374, 386 and 450 nm) being attributed to single $Fe^{3+}$ ion, the band B (560, 579 and $704n{\breve{m}}$) to $Fe^{2+}$/$Ti^{4+}$ pairs, the band C (-800 nm) to $Fe^{2+}$/$Fe^{3+}$ pairs, and the D (528 nm) to $Ti^{3+}$ dd transitions. From those UV-VIS characteristics the origin of blue color of the sapphires is confirmed to be attributed by the factors such as $Fe^{2+}$/$Fe^{3+}$ and $Ti^{3+}$/$Ti^{4+}$. The absorption spectra of natural blue sapphires before and after heat treatment show distintive features, comparing with those of sapphires from other localities: the bands of 689 nm and of $Cr^{3+}$ are not recorded on the spectra of sapphires from Shantung. The band (492 nm), which resulted from $Ti^{3+}$, is not shown and the intensity of the band 528 nm decreases after the heat treatment. Decoloration of ink-blue sapphires are found to be successful by heat treatment with the control of annealing and atmosphere. During the diffusion process the excess components of impurities contained originally in the host crystal were expelled to the surface of crystals, enhancing the transparency of the crystals noticeably.

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Development of IR Reflective Cool Pigment and Paint (차열도료용 Cool Pigment 및 Paint 개발)

  • Kwon, Myon-Joo;Do, Young-Woong;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.8
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    • pp.3800-3805
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    • 2012
  • Infrared(IR) reflective black cool pigment and paint which is used for interior/exterior materials(IR reflectance >30%) to prevent heat island effect and to increase energy efficiency were studied. Cool pigment was synthesized using mixture of $Fe_2O_3$ and $Cr_2O_3$ with calcination from 900 to $1,200^{\circ}C$. Cool paint was prepared by formulation of cool pigment, acrylic resins, and other additives. Results showed that optimum color fixation of pigment obtained by mole ratio of Fe to Cr was 0.9 with calcination temperature at $1,000^{\circ}C$. The cool paint formulated by 20% pigment and 1.5% dispersive additive with $125{\mu}m$ thickness of coated layer showed optimum IR reflectance. Temperature difference on surface between cool paint and ordinary paint(STD) was $36.5^{\circ}C$ and IR reflectance(TSR) was 39.3% at wavelength from 700 to 2,500nm. And color change was not detected during 500hrs weathering test.

Removing Sapstain of Radiata Pine by Bleaching (표백에 의한 라디에타소나무의 청변 제거)

  • Kim, Gyu-Hyeok;Kim, Hyung-Jun;Ra, Jong-Bum;Kim, Jae-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.1
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    • pp.46-51
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    • 2003
  • The feasibility of using bleaching treatments for removing fungal stain was evaluated on heavily stained raiadta pine sapwood. Sodium chlorite and sodium hypochlorite appeared to destain fungal discoloration by providing proper treatment conditions (chemical concentration, treatment temperature, and treatment time), while hydrogen peroxide did not remove fungal stain under the bleaching regimes evaluated. The addition of sodium silicate and sodium hydroxide in the hydrogen peroxide solution as a buffer could remove fungal discoloration completely; however, the color of wood surface turned faint green after bleaching, thereby reducing the lightness of bleached samples. The results suggest that hydrogen peroxide bleaching could be a feasible method for removing fungal discoloration of stained radiata pine sapwood, although further research is needed to solve the problem of color change after bleaching. Also, further tests under field conditions are recommended.

Taxonomic Review of a Rare Butterfly Ray Gymnura japonica (Gymnuridae, Chondrichthyes), in Korea (한국의 희귀 나비가오리[Gymnura japonica (나비가오리과, 연골어강)]의 분류학적 재검토)

  • Kim, Jin-Koo;Ryu, Jung-Hwa;Jang, Seo-Ha;Han, Kyeong-Ho;Kim, Byeong-Yeob
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.55 no.1
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    • pp.30-36
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    • 2022
  • We collected a total of four butterfly ray specimens (Gymnura japonica, 213.4-695.0 mm in total length) in Korea from 2016 to 2021 and investigated their morphological and molecular characteristics in order to clarify their taxonomic status. These features are summarized as follows. Disc lozenge-shaped, 1.8-2.0 times broader than long. Tail very short, post-cloaca length 23.9-28.2% in disc width. Snout short, no rostral cartilage. Clasper short, no hook. Dorsal surface uniform yellow or brownish grey, with or without rounded light yellow spots. An analysis of 434 base-pair sequences of mitochondrial DNA cytochrome c oxidase subunit I showed that all four specimens corresponded to G. japonica from Japan (Kimura-2-parameter distance = 0-0.2%), suggesting that the color patterns found may be due to intraspecific color variation. G. japonica resembles Gymnura poecilura but differs in that it has a shorter tail length to disc width (23.9-28.2% in G. japonica vs. 40.1-48.3% in G. poecilura). This study revealed that G. japonica occurred in areas affected by the Tsushima Warm Current, tentatively suggesting that G. japonica may be an indicator species for monitoring marine ecosystem changes due to climate change.

Conservation of Chungjeong-Kwan, Joseon Dynasty (조선시대(朝鮮時代) 충정관(忠靜冠)의 보존처리(保存處理))

  • Lee, Mee-sik;Song, Mee-kyung;Bae, Soon-wha;Hong, Moon-kyung
    • Conservation Science in Museum
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    • v.3
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    • pp.29-36
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    • 2001
  • The hat excavated from the tomb of Hojeo-myon Wonsung-gun in Kangwon province was dry-cleaned and restored. The hat was made of wool felt and decorated with several strands of silk cord. It was very dirty and moth-eaten. After getting rid of the particle soils on a surface with painting brush, the hat was dry-cleaned using perchloroethylene applying the minimum force, and blotting paper was used for drying. During cleaning, it was supported by the stainless steel net. The weight loss was 7.94% after cleaning. The soils sticked on the hat was removed clearly. The texture of the hat became softer after cleaning. Color difference(∆E) was 2.57, which is a noticeable change. The color became clear and changed to the red and yellow range. After dry-cleaning, the hat was repaired. Dislocated silk cords were fixed to the right place by stitching with silk yarn. To keep the shape of the hat, it should be supported by a hat-shaped stiff net during exibition and storing.

Fabrication of functional nanoparticles by layer-by-layer self-assembly method (LBL 법을 이용한 기능성 나노 입자 제조)

  • Kim, Jin-Ho;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Sae-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.6
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    • pp.305-310
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    • 2009
  • $TiO_2$ thin films consisting of positively charged poly (diallyldimethylammonium chloride) (PDDA) and negatively charged titanium (IV) bis (ammonium lactato) dihydroxide (TALH) were successfully fabricated on a poly (methyl methacrylate) (PMMA) by layer-by-layer (LBL) self-assembly method. By the measurement of quartz crystal microbalance (QCM), it was found that as the solution pH of TALH decreased, the deposition volume of TALH increased and the thickness of (PDDA/TALH) thin film coated on the surface of PMMA particles increased. The PMMA particles coated with the coating sequence of (PDDA/TALH)n showed the variation of color changes as a function of the number of bilayer. The number of bilayer (n) of (PDDA/TALH) thin films was 10 and 20, the values of $a^*$ and $b^*$ decreased from those of PMMA particles without coating films and the color changes was shifted to green and blue direction in the $a^*$, $b^*$ chromaticity diagram. And then, the number of n increased to 30 and 40, the values of $a^*$ and $b^*$ increased and the color changes was shifted to red and yellow direction, respectively. Finally the PMMA particles coated with $(PDDA/TALH)_{50}$ thin film showed a little same value of $a^*$ and $b^*$ with the PMMA particles without (PDDA/TALH) thin film.