• Title/Summary/Keyword: Surface coating layer

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The Effect of Metal-Oxide Coating on the Electrochemical Properties in Thin-Film $LiCoO_2$ Cathodes (금속산화물 코팅을 통한 박막 $LiCoO_2$양극의 전기화학적 특성 향상)

  • 김혜민;김병수;김용정;조재필;박병우
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.124-124
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    • 2003
  • To improve the electrochemical properties of thin-film LiCoO$_2$ cathodes, metal oxides were coated on the LiCoO$_2$ thin films using f sputtering. Galvanostatic charge-discharge experiments showed the enhanced cycling behaviors in the metal-oxide coated LiCoO$_2$ thin films than the uncoated ones. These results are because the metal-oxide coating layer suppresses the degradation of Li-diffusion kinetics during cycling, which is related to the protection of cathode surface from the electrolytes [l-3]. The variation in the metal-oxide coating thickness ranging from 10 to 300 nm did not affect the electrochemical properties. Changes of lattice constants in the coated and bare LiCoO$_2$ thin films at different charged states will also be discussed.

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The Effect of Drawing Conditions on the Tensile Strength of Optical Fiber (광섬유의 인장강도에 미치는 Drawing Condition의 영향)

  • 한택상;최상삼
    • Journal of the Korean Ceramic Society
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    • v.19 no.1
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    • pp.44-50
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    • 1982
  • Drawing optical fibers in a graphite furnace is one of the most convenient and economical means of producing optical fiber. Since the flaw formation on optical fiber is mainly due to dust contaminations during drawing and surface corrosion by water vapor penetration through coating layer, the tensile strength of optical fiber drawn in a graphite furnace is greatly inflenced by the drawing conditions. The important factors found in this investigation were preform treatment (fire polishing), furnace interior environment (dust contamination, inert gas flows), primary coating condition (resin curing temperature, coating materials, method, thickness) and fiber pulling condition (furnace temperature, drawing speed, pulling tension). The tensile strength at optimum drawing conditions turned out to be 5 ~ 6 GPa.

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Development of Surface Improvement Technique of Japanese Larch Flooring Board(II) (낙엽송 마루판재의 표면강화 처리기술 개발(II))

  • Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.1
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    • pp.28-35
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    • 2000
  • This paper deals with a coating technique for hardening surface layer of softwood(Larix leptolepis) flooring board to improve its surface properties such as hardness and abrasion resistance, Two coating methods were applied for surface hardening of the wood in this study. First, several functional monomers were added in UV-curing epoxy acrylate varnish. Secondly, unsaturated polyester varnish was used as under coat and acryl varnish including anti-abrasive agent was used as top coat. The hardness of the treated wood was similar to that of high density hardwood such as keruing by the first coating method. The abrasion resistance of the coated wood was greatly improved by the second method. Adhesion properties and impact resistance of the coated wood surface were also good. It was suggested that the well-coated softwood could be used as interior flooring board for heavy walking as substitute for hardwood.

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HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate (고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층)

  • Nam, Dae-Geun
    • New & Renewable Energy
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    • v.4 no.1
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    • pp.31-36
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    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Numerical Investigation of Forming Limit of Clad Coated Sheet Metals (클래드코팅재의 성형성에 대한 수치적연구)

  • 정태훈
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.04a
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    • pp.340-345
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    • 2003
  • By the use of a similar numerical method as that in the previous paper, the forming limit strain by coating method of clad sheet metals is investigated, in which the FEM is applied and J2G(J2-Gotoh's corner theory) is utilized as the plasticity constitutive equation. Clad two-layer sheets and sheets bonded with dissimilar sheets on both surface planes are stretched in a plane-strain state, with various work-hardening exponent n-values and thicknesses of each layer. Processes of shear-band formation in such composite sheets are clearly illustrated. It is concluded that, in the clad state, the higher limiting strain of one layer is reduced due to the lower limiting strain of the other layer and vice versa, and does not necessarily obey the rule of linear combination of the limiting strain of each layer weighted according thickness.

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Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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The Study on the the P3HT:PCBM Bulk Heterojunction Solar Cells Utilizing $WO_3$ Nano-particle As a Hole Transporting Layer

  • Choe, Ha-Na;Kim, Seong-Hyeon;Kim, Gyeong-Gon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.321-321
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    • 2010
  • The PEDOT:PSS layer is usually used as hole transporting layer for the polymer bulk heterojunction solar cells. However, the interface between ITO and PEDOT:PSS is not stable and the chemical reaction between ITO and PEDOT can result in degraded device performance. We used the tungsten oxides as a hole transport layer by spin-coating. The $WO_3$ nanoparticles were well dispersed in ammonium hydroxide and deionized water and formed thin layer on the ITO anode. We found that $WO_3$ surface is more hydrophobic than the bare ITO or PEDOT:PSS-coated surfaces. The hydrophobic surfaces promote an ordered growth of P3HT films. A higher degree of P3HT ordering is expected to improve the hole mobility and the lifetime of the device using the tungsten oxide showed better stability compared to the device using the PEDOT:PSS.

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A Study on Protection of Stainless Steel Substrate against Corrosion in Molten Carbonate by Formation of Aluminum Diffusive Layer Using a Slurry Coating Method (슬러리 코팅법에 의한 스테인레스 스틸 표면에서의 알루미늄 확산막 제조 및 용융탄산염 내에서의 내식 특성 연구)

  • Nam S. W.;Hwang E. R.;Magtanyuk A. P.;Hong M. Z.;Lim T. H.;Oh I. -H.;Hong S. -A.
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.136-140
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    • 2000
  • A stainless steel separator for a molten carbonate fuel cell is usually coated with aluminum diffusive layer to protect its surface against corrosion by the molten carbonate at high temperatures. In this study, a relatively simple method was devised to form the aluminum diffusive layer on a stainless steel substrate. Slurry coating of aluminum on the substrate followed by heat treatment under reducing atmosphere at $650\~800^{\circ}C$ produced the aluminum diffusive layer of $25\~80{\mu}m$ thickness. The thickness of aluminum diffusive layer increased with increasing the temperature or duration of the heat-treatment. The corrosion resistance against molten carbonate under oxidizing atmosphere was significantly improved by aluminum diffusive layer formed by the sluny painting and heat treatment method. Moreover, the sample prepared in this study showed corrosion behavior similar to the sample with aluminum diffusive layer prepared by ion vapor deposition and heat treatment.

The Effect of Oxide Layer Thickness to the Scale Defects Generation during Hot finish Rolling (열연사상 압연시 스케일 결함발생에 미치는 산화피막 두께의 영향)

  • 민경준
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.08a
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    • pp.412-422
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    • 1999
  • Scale defects generated on the strip surface in a tandem finishing mill line are collected from the strip trapped among the production mills by freezing the growing scale on the strip by the melt glass coating and shutting down the line simultaneously. The samples observed of its cross sectional figure showed the process of scale defect formation where the defects are formed at the base metal surface by thicker oxidized scale during each rolling passes. The properties of the oxidized layer growth both at rolling and inter-rolling are detected down sized rolling test simulating carefully the rolling condition of the production line. The thickness of the oxidized layer at each rolling pass are simulated numerically. The critical scale thickness to avoid the defect formation is determined through the expression of mutual relation between oxidized layer thickness and the lanks of the strip called quality for the scale defects. The scale growth of scale less than the critical thickness and also to keep the bulk temperature tuning the water flow rate and cooling time appropriately. Two units of Inerstand Cooler are designed and settled among the first three stands in the production line. Two units of scale defect is counted from the recoiled strip and the results showed distinct decrease of the defects comparing to the conventionaly rolled products.

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Convenient Aluminizing Process of Steel by Using Al-Ti Mixed Powder Slurry (Al-Ti 혼합 분말 슬러리를 이용한 강의 알루미나이징처리 방법)

  • Lee, Young-Ki;Kim, Jung-Yeul;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.19 no.4
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    • pp.207-211
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    • 2009
  • In this study, we attempted to develop a convenient aluminizing process, using Al-Ti mixed slurry as an aluminum source, to control the Al content of the aluminized layer as a result of a one-step process and can be widely adopted for coating complex-shaped components. The aluminizing process was carried out by the heat treatment on disc and rod shaped S45C steel substrates with Al-Ti mixed slurries that were composed of various mixed ratios (wt%) of Al and Ti powders. The surface of the resultant aluminized layer was relatively smooth with no obvious cracks. The aluminized layers mainly contain an Fe-Al compound as the bulk phase. However, the Al concentration and the thickness of the aluminized layer gradually decrease as the Ti proportion among Al-Ti mixed slurries increases. It has also been shown that the Al-Ti compound layer, which formed on the substrate during heat treatment, easily separates from the substrate. In addition, the incorporation of Ti into the substrate surface during heat treatment was not observed.