• Title/Summary/Keyword: Surface carbon content

Search Result 515, Processing Time 0.024 seconds

Plasma Resistance and Etch Mechanism of High Purity SiC under Fluorocarbon Plasma

  • Jang, Mi-Ran;Paek, Yeong-Kyeun;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
    • /
    • v.49 no.4
    • /
    • pp.328-332
    • /
    • 2012
  • Etch rates of Si and high purity SiC have been compared for various fluorocarbon plasmas. The relative plasma resistance of SiC, which is defined as the etch rate ratio of Si to SiC, varied between 1.4 and 4.1, showing generally higher plasma resistance of SiC. High resolution X-ray photoelectron analysis revealed that etched SiC has a surface carbon content higher than that of etched Si, resulting in a thicker fluorocarbon polymer layer on the SiC surface. The plasma resistance of SiC was correlated with this thick fluorocarbon polymer layer, which reduced the reaction probability of fluorine-containing species in the plasma with silicon from the SiC substrate. The remnant carbon after the removal of Si as volatile etch products augments the surface carbon, and seems to be the origin of the higher plasma resistance of SiC.

Properties of Anti-static Material Using Carbon Nanotube (탄소나노튜브를 이용한 폴리우레탄 코팅소재의 대전방지성)

  • Kim, Jong-Won;Song, Sun-Hye;Yoon, Seok-Han;Song, Byung-Kab;Chu, Gyo-Jin;An, Hun-Ju
    • Textile Coloration and Finishing
    • /
    • v.19 no.4
    • /
    • pp.26-31
    • /
    • 2007
  • Nanocomposite resin(PUD-CNT) composed of Carbon nanotube(CNT) and Polyurethane Dispersion (PUD) was prepared by different contents of CNT($0{\sim}5%$). PUD-CNT was coated on samples, and their electrical conductivity was investigated. With increasing CNT content, static change, half life and surface resistance decreased. Composites having 5% CNT showed $10^9{\Omega}/cm$(surface resistance), and 40V (stactic charge). Respectively, From this results, PUD-CNT can be used as a antistatic material.

Effects of Hear Teratment on the Insulation Layer of Non-oriented Silicon Steel Sheets (열처리 조건이 무\ulcorner향성 규소강판의 절연피막에 미치는 영향)

  • 유영종;신정철
    • Journal of the Korean institute of surface engineering
    • /
    • v.22 no.3
    • /
    • pp.109-117
    • /
    • 1989
  • The effect of heft treatment on the characteristic properties of insulation layer is studied for two kinds of non-oriented silicon steels, which were insulation-coates with various kinds of inorganic and inorganic-organic complex coating solutions. In addition, how the carbon contained in the insulation layer would affect the carbon content and the magnetic properties of the steel substrates is examined. Lower temperature heat treftment ($480^{\circ}C$ for 0.5hr) is found to render morw favorable surface qualities, wheras higher temperature heat treatment ($790^{\circ}C$ for 2hr) better core loss due to grin growt occurred during the heat treatment. Decarburization of the steel substrate is also found unaffectrd by the presence of carbon in the insulation layer.

  • PDF

Roles of Nickel Layer Deposition on Surface and Electric Properties of Carbon Fibers

  • Kim, Byung-Joo;Choi, Woong-Ki;Bae, Kyong-Min;Moon, Cheol-Whan;Song, Heung-Sub;Park, Jong-Kyoo;Lee, Jae-Yeol;Im, Seung-Soon;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.5
    • /
    • pp.1630-1634
    • /
    • 2011
  • Electroless plating of metallic nickel on carbon fiber surfaces was carried out to control specific electric resistivity of the fibers, and the effects of the nickel content and coating thickness on the electric properties were studied. The structural and surface properties of the carbon fibers were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The specific resistivity of the fibers was measured using a four-point probe testing method. From the XPS results, the oxygen and Ni atomic ratio of the fibers was greatly enhanced as the plating time increased. Additionally, it was observed that the specific electric resistivity decreased considerably in the presence of metallic nickel particles and with the formation of nickel layers on carbon fibers.

Characterization of composite prepared with different mixing ratios of TiO2 to activated carbon and their photocatalytic activity

  • Chen, Ming-Liang;Bae, Jang-Soon;Ko, Young-Shin;Oh, Won-Chun
    • Analytical Science and Technology
    • /
    • v.19 no.5
    • /
    • pp.376-382
    • /
    • 2006
  • In this work, pitch/activated carbon/$TiO_2$ composite were prepared by $CCl_4$ solvent method with different mixing ratios. The BET surface area of pitch/activated carbon/$TiO_2$ composite has a significantly increase with increasing activated carbon content in pitch/activated carbon/$TiO_2$ composite. The surface structure and elemental compositions of the composite were studied by SEM and EDX, respectively. The SEM results were presented to the characterization of porous texture on the pitch/activated carbon/$TiO_2$ composite. And EDX data was shown the presence of C, O, S, Ti and other elements. The structural properties of the composite were studied in XRD measurements. The $TiO_2$ crystal phases of the pitch/activated carbon/$TiO_2$ composite had lots of rutile-type structure which transforms from anatase-type with a little of anatase-type structure. The photocatalytic activities of the composite were evaluated using a photo-decomposition method under UV lamp. The pitch/activated carbon/$TiO_2$ composites were observed better photocatalytic activity than that of pristine $TiO_2$.

Relationship Between Exothermic Heat and Carbon Contents of Pitch-based Carbon Fiber

  • Lee, Jae-Young;Oh, Jong-Hyun;Yang, Xiao Ping;Ryu, Seung-Kon
    • Carbon letters
    • /
    • v.10 no.3
    • /
    • pp.202-207
    • /
    • 2009
  • Pitch-based carbon fiber tows were prepared from naphtha cracking bottom oil by reforming and carbonization. The relationship between exothermic heat and carbon contents of the fiber was investigated by changing the carbonization conditions. The carbon contents and the crystallinities of isotropic pitch-based carbon fibers were 86.8~93.8 wt% and 33.7~40.1%, respectively, which were linearly proportional to the increase of carbonization temperature from 700 to $1000^{\circ}C$. The exothermic heat (temperature increase) of fiber tows was measured in a short time, which was also linearly proportional to the increase of carbon contents due to the increase of crystallinity, even though the crystallinity was low. Therefore, the carbon contents or carbonization degree of fibers can rapidly and indirectly be estimated by measuring the surface temperature increase of fibers.

Distribution Characteristics of Organotin Compounds in Sediments inside Jeju Harbor of Jeju Island (제주도 제주항내 퇴적물 중의 유기주석화합물의 분포 특성)

  • Kam, Sang-Kyu;Kim, Hyun-Jeong;Lee, Min-Gyu
    • Journal of Environmental Science International
    • /
    • v.20 no.3
    • /
    • pp.385-394
    • /
    • 2011
  • Organotin compounds (OTs), namely butyltins compounds (BTs) and phenyltin compounds (PhTs), were measured in surface and core sediments collected in Jeju harbor. The horizontal and vertical distribution was examined and the relationship between the concentration of OTs and organic matter content and particle size distribution was also studied. BTs were detected in significant concentrations in sediments inside Jeju harbor. PhTs were detected in very low concentrations, compared to BTs. The main species in BTs and PhTs were dibutyltin (DBT) and monobutyltin (MBT), monophenyltin (MPhT), respectively. In the relationships between the concentrations of total BTs and organic carbon content, the significant correlations ($r^2$=0.4898 in surface sediments, $r^2$=0.53 in one core sediments) and no correlation in another core sediments obtained, which is estimated that the distribution of BTs in sediments were affected by several factors, such as their physicochemical properties including organic carbon content, and a tide, etc. In the relationships between the concentrations of total BTs and particle size (mud, sand, and gravel) in sediments, the concentrations of total BTs were higher in the sediments with higher mud content, indicating that higher BTs were distributed with increasing sediments of fine granules.

Effects of Steel Chemistry, Annealing and Galvannealing Conditions on Bake Hardenability of Hot-Dip Galvannealed Sheet Steels (합금화 용융아연 도금강판의 강성분, 소둔 및 합금화 열처리가 소부경화성에 미치는 영향)

  • 이호종;김종상
    • Journal of the Korean institute of surface engineering
    • /
    • v.34 no.3
    • /
    • pp.247-257
    • /
    • 2001
  • In an effort to improve the dent resistance of exterior body panels at a reduced steel thickness, the bake hardenable steels added Ti or Nb with tensile strength of 35Kgf/$\textrm{mm}^2$ were investigated. The bake hardenability increased with the annealing temperature and solute carbon content. Bake hardening of 3 to 5Kgf/$\textrm{mm}^2$ was obtained in steels with a controlled solute carbon concentration range from 6 to 10ppm. The galvannealing temperature and time had little influence on the bake hardenability. The Fe-Zn alloying reaction of 35Kgf/$\textrm{mm}^2$ BH steel was remarkably retarded due to a 0.07%P addition. The optimum galvannealing temperatures of 35Kgf/$\textrm{mm}^2$ BH steel were ranged from 520 to 56$0^{\circ}C$ in view of the Fe content and powdering resistance. The cross-section and planar views of the galvannealed coatings to characterize morphology development were discussed.

  • PDF

Electrochemical Oxidation of Carbon Felt for Redox Flow Battery (Redox flow battery용 carbon felt 전극의 전기화학적 산화)

  • Jung, Young-Guan;Hwang, Gab-Jin;Kim, Jae-Chul;Ryu, Cheol-Hwi
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.22 no.5
    • /
    • pp.721-727
    • /
    • 2011
  • All vanadium redox-flow battery (VRFB) has been studied actively as one of the most promising electrochemical energy storage systems for a wide rage of applications such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants at night time. In this study, carbon felt electrodes were treated by electrochemical oxidation with KOH, and the cyclic voltammetry were studied in order to investigate redox reactivity of vanadium ion species with carbon felt electrodes. Besides the effect of electrochemical oxidation on the surface chemistry of carbon felt electrodes were investigated using the X-ray photoelectron spectroscopy (XPS). After electrochemical oxidation, XPS analysis of PAN based GF20-3 carbon felt electrode revealed on increase in the overall surface oxygen content of the carbon felts after electrochemical oxidation. Redox reaction characteristics using cyclic voltammetry (CV) were ascertained that the electrochemical treated electrode were more reversible than the untreated electrode.

Improvement of Physical Properties for Carbon Fiber/PA 6,6 Composites (탄소섬유/폴리아마이드 6,6 복합재료의 기계적 물성 향상)

  • Song, Seung A;On, Seung Yoon;Park, Go Eun;Kim, Seong Su
    • Composites Research
    • /
    • v.30 no.6
    • /
    • pp.365-370
    • /
    • 2017
  • Mechanical properties of carbon fiber reinforced thermoplastic composites (CFRTPs) are affected by various factors. One of the them are poor compatibility of the epoxy sizing layer on the carbon fiber surface with thermoplastic matrix, which causes the inferior interfacial strength between fibers and matrix. In addition, the high molten-viscosity of thermoplastics attributes to the poor impregnation state. Consequently, many voids in the composite materials were generated, which leads to poor mechanical properties of the thermoplastic composites. In this study, the epoxy sizing on the carbon fiber surface was removed and the polyamide 6,6 solution was coated on the de-sized carbon fiber surface to improve the impregnation state and mechanical properties. Interlaminar shear strength (ILSS) of CFRPTs was estimated by implementing short beam shear tests. In addition, flexural strength was measured and the impregnation state of the composites was evaluated by calculating void content.