• 제목/요약/키워드: Surface Properties Test

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Physico-chemical Characteristics of Ammonia Adsorbed Fly Ash (AAFA)

  • Kim, Jae-kwan;Park, Seok-un;Hong, Jin-pyo
    • KEPCO Journal on Electric Power and Energy
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    • v.4 no.1
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    • pp.39-45
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    • 2018
  • Ammonia Adsorbed Fly Ash (AAFA) samples produced from coal fired plants equipped with SNCR (Selective Non-Catalytic Reduction) of nitrogen oxides with urea have been chemically analyzed, and their physical and dissolution properties have been investigated. XRD results for the ammonia component in AAFA ascertained that ABS (ammonium bisulfate) and AS (ammonium sulfate) were deposited on fly ash as $SO_3$ reacted with unreacted ammonia at SNCR. SEM and EDS images showed that fine ashes on large fly ash surface of sphere type were agglomerated, due to adhesive role of ammonium salts attached fly ashes. Dissolution test results of ammonium salts absorbed on AAFA in distilled water or sea water showed that the proportion of un-ionized $NH_3$ to $NH_4{^+}$ were primarily a function of pH and temperature. Increasing pH and temperature causes an increase in the fraction of un-ionized $NH_3$. At pHs of 9.6 and 10.7, un-ionized $NH_3$ and $NH_4{^+}$ ions are present in equal amounts at distilled water and sea water, respectively.

Development of Hot die Forging Process for Large-size Titanium Alloy Container (대형 티타늄 합금 용기의 고온 금형 성형 공정 개발)

  • Kwon, I.K.;Kim, D.S.;Park, T.D.;Park, H.S.;Hong, S.S.;Shim, I.O.
    • Transactions of Materials Processing
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    • v.19 no.1
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    • pp.50-58
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    • 2010
  • In order to successfully implement hot die forging process for the large-size titanium alloy products, it is necessary to devise a customized heating method for the billets and the die tools, as well as the die tool design. This study aims at establishing a hot die forging process of the large-size titanium alloy container products by applying the warm die, semi-hot die and hot die forging process step-wise. To accomplish this purpose, forging mechanism and the die tools were designed considering the strength of die materials at the given die heating temperature. The movable heating devices for the billet and the die tools were also introduced to prevent overcooling of billet and die tools. To verify the applicability of the designed forging process, real-size forging tests were carried out and the quality of forged products, including dimension, surface condition, microstructure and the mechanical properties was evaluated.

Electrochemical Properties of Activated Polyacrylonitrile/pitch Carbon Fibers Produced Using Electrospinning

  • Kim, Bo-Hye;Bui, Nhu-Ngoc;Yang, Kap-Seung;dela Cruz, Marilou E.;Ferraris, John P.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.1967-1972
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    • 2009
  • The electrospinnability of pitch was improved by blending in a solution of polyacrylonitrile (PAN) resulting in the reduction of the average fiber diameter from 2000 to 750 nm. Activated carbon fibers (ACFs) derived by stabilization, carbonization and steam activation at 700, 800, and 900 ${^{\circ}C}$ of the PAN/pitch electrospun fibers for 60 min were investigated as electrodes for supercapacitors. The Brunauer, Emmett, Teller (BET) specific surface area ranged from 732 to 1877 $m^2g^{-1}$ and the specific capacitance from 75.5 to 143.5 $Fg^{-1}$, depending on the activation conditions. Electrodes from the electrospun web activated at 900 ${^{\circ}C}$ exhibited a particularly quick response showing a high frequency of 5.5 Hz at a phase angle of ‒$45^o$ of the impedance spectroscopy.

Removal Effects of Pb(II) using Natural Clays from Domestic (국내산 천연점토를 이용한 Pb(II)의 제거효과)

  • Oh, Se-Young;Hwang, Seong-Kwy;Yoon, Cheol-Hun;Lee, Ki-Chang;Jang, Kwan-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.3
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    • pp.13-19
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    • 1998
  • This study was carried out to investigate characteristics and Pb(II) removal effect of natural Muan, Seosan, Kangjin clays in the batch mode test to develope the low-priced treatment agent of wastewater which contain heavy metals in order structural, optical properties and chemical compositions of natural clays from domestic have been investigated to have high specific surface area and have minerals such as $SiO_2$ and $Al_2O_3$. As a result, removal effects of Pb(II) ions on clays were reached at equilibrium in aqueous solutions by stirring about 20minutes. The removal effect of Pb(II) ions was best for Seosan clay than Muan or Kangjin clays in terms of fixed time. The results show the possibility of continuous treatment system of wastewater which contain heavy metals by using natural clays from domestic.

Understanding Hydrogeologic Characteristics of a Well Field of Pyosun in Jeju Volcanic Island of Korea

  • Lee, Jin-Yong;Lee, Gyu-Sang;Song, Sung-Ho
    • Journal of the Korean earth science society
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    • v.29 no.5
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    • pp.396-407
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    • 2008
  • Hydrogeologic properties of a well field around middle mountainous areas in Pyosun, Jeju volcanic island were examined based on water level monitoring, geologic logging and pumping test data. Due to the alternating basaltic layers with varying permeability in the subsurface, it is difficult to analyze the hydraulic responses to artificial pumping and/or natural precipitation. The least permeable layer, detrital materials with clay, is found at a depth of 200 m below surface, but it is not an upper confining bed for lower main aquifer. Nevertheless, this layer may serve as a natural barrier to vertical percolation and to contaminant migration. Water levels of the production wells are dominantly affected by pumping frequently, while those of the remote observation wells are controlled by ambient precipitation. Results of pumping tests revealed a possible existence of horizontal anisotropy of transmissivity. However, some results of this study include inherent limitations enforced by field conditions such as the consistent of groundwater production and the set of time periods for the cessation of the pumping prior to pumping tests.

A Fundamental Study on the Performance of Spalling Resistance of High Performance Concrete with Material of Lateral Confinement Subjected to Fire (화재시 횡구속재 변화에 따른 고성능 콘크리트의 폭열방지성능에 관한 기초적 연구)

  • 배정렬;황인성;홍상희;한민철;한천구
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.05a
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    • pp.47-50
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    • 2002
  • This paper presents the results of fire resistance properties of high performance concrete varying with fiber kinds and the size of metal lath in order to verify the validities of fiber on the spatting resistance by fire. Metal lath, glass fiber and carbon fiber are used to confine the concrete. According to test results, plain concrete without lateral confinement and confined concrete with glass fiber and carbon fiber show entire failure after exposed to fire, while confined concrete with metal lath take place in the form of slight surface spatting by fire, which has favorable spatting resistance of concrete. As for the effect of the size of metal lath, when the size of metal lath is more than 1.2mm of thickness, the residual strength of concrete exposed to fire maintains more than 80% of its original strength. However, glass fiber and carbon fiber does not perform desirable spatting resistance by fire due to loss of lateral confinement of fiber exposed to fire caused by melting of fiber and reducing bond strength between concrete and fiber.

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Interfacial and Nondestructive Evaluation of Single Carbon Fiber/Epoxy Composites by Fiber Fracture Source Location using Acoustic Emission (Acoustic Emission 의 섬유파단 Source Location을 이용한 Carbon Fiber/Epoxy Composites의 계면특성 및 비파괴적 평가)

  • Kong, Jin-Woo;Kim, Jin-Won;Park, Joung-Man;Yoon, Dong-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.116-120
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    • 2001
  • Fiber fracture is one of the dominant failure phenomena to determine total mechanical properties in composites. Fiber fracture locations were measured by optical microscopic method and acoustic emission (AE) as functions of matrix toughness and surface treatment by the electrodeposition (ED), and then two methods were compared. Two AE sensors were attached on the epoxy specimen and fiber fracture signals were detected with elapsed time. The interfacial shear stress (IFSS) was measured using tensile fragmentation test and AE system. In ED-treated case, the number of the fiber fracture measured by an optical method and AE was more than that of the untreated case. The signal number measured by AE were rather smaller than the number of fragments measured by optical method, since some fiber fracture signals were lost while AE detection. However, one-to-one correspondence between the x-position location by AE and real break positions by optical method was generally established well. The fiber break source location using AE can be a valuable method to measure IFSS for semi- or nontransparent matrix composites nondestructively (NDT).

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A Comparative Study on Thermal Efficiency Between the Present Floor and a Ceramic Floor (기존온돌과 세라믹구들의 열효율 비교 연구)

  • Kim, Young Man;Kim, Kyung Sung;Choi, Beom Suk;Ko, Jae Sik;Park, Seung Ku
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.166-170
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    • 1999
  • A ceramic floor with improved thermal conductivity and efficiency has been developed in this study. The new ceramic floor minimizes the shrinkage rate to below 0.07% and shows almost no cleavage. There is no need to repaire the ceramic floor because its bottom surface is flat. It especially shows an excellent perfomance in the test of a compressive strength ($300kg/cm^2$ based on 28 days), a flexural strength ($64kg/cm^2$ based on 28 days), and a convenient pressing. It is lighter than the present floor and it is expected to be applicable for a self-leveling ceramic motar in the residences and apartments. It shows an excellent character in the thermal conductivity and other physical properties compare to the present cement mortar.

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Optimization of arc brazing process parameters for exhaust system parts using box-behnken design of experiment

  • Kim, Yong;Park, Pyeong-Won;Park, Ki-Young;Ryu, Jin-Chul
    • Journal of Welding and Joining
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    • v.33 no.2
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    • pp.23-31
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    • 2015
  • Stainless steel is used in automobile muffler and exhaust systems. However, in comparison with other steels it has a high thermal expansion rate and low thermal conductivity, and undergoes excessive thermal deformation after welding. To address this problem, we evaluated the use of arc brazing in place of welding for the processing of an exhaust system, and investigated the parameters that affect the joint characteristics. Muffler parts STS439 and hot-dipped Al coated steel were used as test specimens, and CuAl brazing wire was used as the filler metal for the cold metal transfer (CMT) welding machine, which is a low heat input arc welder. In addition, a Box-Behnken design of experiment was used, which is a response surface methodology. The main process parameters (current, speed, and torch angle) were used to determine the appropriate welding quality and the mechanical properties of the brazing part was evaluated at the optimal welding condition. The optimal processing condition for arc brazing was 135A current, 51cm/min speed and $74^{\circ}$ torch angle. The process was applied to an actual exhaust system muffler and the prototype was validated by thermal fatigue, thermal shock, and endurance limit tests.

Improvements in the Physical Properties of Hanji by Using Red Algae Pulp

  • Seo, Yung-Bum;Kim, Young-Wook;Lee, Min-Woo;Jung, Sun-Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.5
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    • pp.33-37
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    • 2009
  • Hanji is a traditional Korean handmade paper, made of bast fibers of the paper mulberry. Its fiber furnish is much more expensive than wood fiber furnish. Hanji with a low basis weight requires additional opacity and smoothness for better writing and printing. Filler such as calcium carbonate can not be used to raise the opacity of Hanji because of its low retention in low basis weight paper and the high freeness of the Hanji fiber furnish. Addition of red algae pulp, which is prepared from marine red algae to the Hanji fiber furnish negated retention problems happening in the case of mineral filler addition, and produced a substantial improvement in the opacity and smoothness of Hanji. The higher retention was due to the much larger size of the red algae fibers compared to the mineral fillers. The improvement in opacity and smoothness were also due to the shape of the red algae fibers: that red algae fibers are narrower in widths and shorter in lengths than wood fibers results in increased surface area and smoothness.