• 제목/요약/키워드: Surface Functional Groups

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Effects of Dual Task Training on Balance and Functional Performance in High School Soccer Players with Functional Ankle Instability

  • Kwak, Kwang-Il;Choi, Bum-Jin
    • The Journal of Korean Physical Therapy
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    • 제28권4호
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    • pp.254-258
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    • 2016
  • Purpose: This study was conducted to identify the effects of dual task training on balance and functional performance in high school soccer players with functional ankle instability. Methods: Twenty high school soccer players with functional ankle instability were randomly assigned to a single task training group and a dual task training group. One participant who did not participate regularly in the training was excluded. The single task training group (n=9) received balance training on an unstable surface. The dual task training group (n=10) received balance training on an unstable surface and had to catch thrown balls during the balance training. Both groups were trained for 4 weeks, 3 days a week. The balance and functional performance of both groups was measured before and after training. Balance was measured using an anterior-posterior and medio-lateral balance. Functional performance was measured based on a figure-of-8 hop test, up-down hop test, and a single hop test. All data were analyzed by repeated two-way ANOVA tests. Results: A time by group interaction effect was not observed in the medio-lateral balance test, figure-of-8 hop test, or single hop test (p>0.05). A time by group interaction effect was observed in the anterior-posterior balance and up-down hop test (p<0.05). Conclusion: These results suggest that dual task training improved balance and functional performance better than single task training for some items.

피도금 탄소재의 산처리가 무전해 동도금에 미치는 영향 (Effects of Acid Treatment of Carbon on Electroless Copper Plating)

  • 신아리;한준현
    • 한국표면공학회지
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    • 제49권3호
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    • pp.265-273
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    • 2016
  • The effects of surface modification by nitric acid on the pre-treatment of electroless copper plating were investigated. Copper was electroless-plated on the nitric acid treated graphite activated by a two-step pre-treatment process (sensitization + activation). The chemical state and relative quantities of the various surface species were determined by X-ray photoelectron spectroscopy (XPS) after nitric acid modification or pre-treatment. The acid treatment increased the surface roughness of the graphite due to deep and fine pores and introduced the oxygen-containing functional groups (-COOH and O-C=O) on the surface of graphite. In the pre-treatment step, the high roughness and many functional groups on the nitric acid treated graphite promoted the adsorption of Sn and Pd ions, leading to the uniform adsorption of catalyst ($Pd^0$) for Cu deposition. In the early stage of electroless plating, a lot of tiny copper particles were formed on the whole surface of acid treated graphite and then homogeneous copper film with low variation in thickness was formed after 30 min.

Surface Properties of HCl Modified Ag-ACFs

  • Oh, Won-Chun;Ko, Young-Shin
    • Carbon letters
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    • 제6권4호
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    • pp.248-254
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    • 2005
  • Silver impregnated activated carbon fibers were post-modified using hydrochloric acid. Adsorption behaviors, SEM morphologies, and functional groups for the silver impregnated ACFs were compared with those of post-modified ACFs. Adsorption isotherms were used to characterize $S_{BET}$, the pore structure and volume of silver-activated carbon fibers (ACFs) before and after acid post-treatment. In order to the reveal the causes of the differences surface states after the samples were washed with hydrochloric acid, outer surface and pore structure were investigated by SEM. And the type and quality of various functional groups were studied from FT-IR spectra and Boehm titration method. Finally, the quantitative properties in silver contents were also examined by EDX spectra.

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Characterizations of Membrane for Water Treatment: Surface Charge Analysis by Electrophoresis and Acidity Measurements

  • Yongki Shim;Lee, Sangyoup;Moon, Seung-Hyeon;Jaeweon Cho
    • Korean Membrane Journal
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    • 제2권1호
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    • pp.56-59
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    • 2000
  • The surface charge properties of a polymeric NF and a ceramic UF membranes were characterized in terms of zeta potential and acidity. Both the negative zeta potential and acidity values increased as pH increases due to ionizable acidic functional groups. Increased ionic strength reduced the acidity of the negatively-charged membrane surface as anticipated. Through these results, it can be envisioned are used to reject solutes with ionizable functional groups. Fouling of the negatively-charged membrane with natural organic matter (NOM) having a negative charge density was also investigated with respect to the surface charge. The surface charge of the NF membrane increased negatively when greater NOM adsorption onto the membrane surface occured.

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Electrosorption of U(IV) by Electochemically Modified Activated Carbon Fibers

  • Jung, Chong-Hun;Oh, Won-Zin;Lee, Yu-Ri;Park, Soo-Jin
    • Carbon letters
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    • 제6권1호
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    • pp.25-30
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    • 2005
  • The electrosorption of U(VI) from waste water was carried out by using an activated carbon fiber (ACF) felt electrode in a continuous electrosorption cell. In order to enhance the electrosorption capacity at a lower potential, the ACF was electrochemically modified in an acidic and a basic solution. Pore structure and functional groups of the electrochemically modified ACF were examined, and the effects of the modification conditions were studied for the adsorption of U(VI). Specific surface area of all the ACFs was decreased by this modification. The amount of the acidic functional groups decreased with a basic modification, while the amount increased a lot with an acidic modification. The electrosorption capacity of U(VI) decreased on the acid modified electrode due to the shielding effect of the acidic functional groups. The base modified electrode enhanced the capacity due to a reduction of the acidic functional groups. The electrosorption amount of U(VI) on the base modified electrode at .0.3 V corresponds to that of the as-received ACF electrode at .0.9 V. Such a good adsorption capacity was due to a reduction of the shielding effect and an increase of the hydroxyl ions in the electric double layer on the ACF surface by the application of negative potential.

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Effect of Bridge Exercise Combined with Functional Electrical Stimulation on Trunk Muscle Activity and Balance in Stroke Patients

  • Kang, Jeongil;Jeong, Daekeun;Heo, Sinhaeng
    • 국제물리치료학회지
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    • 제12권2호
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    • pp.2323-2330
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    • 2021
  • Background: Stroke patients have weak trunk muscle strength due to brain injury, so a single type of exercise is advised for restoring functionality. However, even after intervention, the problem still lies and it is suggested that another intervention method should be applied with exercise in order to deal with such problem. Objectives: To Investigate the effect of bridge exercise combined with functional electrical stimulation (FES) on trunk muscle activity and balance in stroke patients. Design: Randomized controlled trial. Methods: From July to August 2020, twenty stroke patients was sampled, ten patients who mediated bridge exercises combined with functional electrical stimulation were assigned to experiment group I, and ten patients who mediated general bridge exercises were assigned to experiment groupII. For the pre-test, using surface EMG were measured paralyzed rectus abdominis, erector spinae, transverse abdominis/internal oblique muscle activity, and using trunk impairment scale were measured balance. In order to find out immediate effect after intervention, post-test was measured immediately same way pre-test. Results: Change in balance didn't show significant difference within and between groups, but muscle activity of trunk was significant difference rectus abdominis and erector spinae within groups I (P<.01), also between groups was significant difference (P<.05). Conclusion: Bridge exercise combined with FES could improve trunk function more effectively than general bridge exercise due to physiological effect of functional electrical stimulation.

탄소나노튜브/흑연펠트 전극의 산소작용기를 활용한 바나듐 레독스 흐름 전지의 수소발생 억제 효과 (Suppressing Effect of Hydrogen Evolution by Oxygen Functional Groups on CNT/ Graphite Felt Electrode for Vanadium Redox Flow Battery)

  • 김민성;고민성
    • 한국표면공학회지
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    • 제54권4호
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    • pp.164-170
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    • 2021
  • Vanadium redox flow batteries (VRFB) have emerged as large-scale energy storage systems (ESS) due to their advantages such as low cross-contamination, long life, and flexible design. However, Hydrogen evolution reaction (HER) in the negative half-cell causes a harmful influence on the performance of the VRFB by consuming current. Moreover, HER hinders V2+/V3+ redox reaction between electrode and electrolyte by forming a bubble. To address the HER problem, carbon nanotube/graphite felt electrode (CNT/GF) with oxygen functional groups was synthesized through the hydrothermal method in the H2SO4 + HNO3 (3:1) mixed acid solution. These oxygen functional groups on the CNT/GF succeed in suppressing the HER and improving charge transfer for V2+/V3+ redox reaction. As a result, the oxygen functional group applied electrode exhibited a low overpotential of 0.395 V for V2+/V3+ redox reaction. Hence, this work could offer a new strategy to design and synthesize effective electrodes for HER suppression and improving the energy density of VRFB.

Surface and Mechanical Interfacial Properties of Oxyfluorinated Carbon Fibers-reinforced Composites

  • Park, Soo-Jin;Seo, Min-Kang;Lee, Young-Seak
    • Carbon letters
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    • 제4권2호
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    • pp.69-73
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    • 2003
  • In this work, the effect of a direct oxyfluorination on surface and mechanical interfacial properties of PAN-based carbon fibers is investigated. The changes of surface functional groups and chemical composition of the oxyfluorinated carbon fibers are determined by FT-IR and XPS measurements, respectively. ILSS of the composites is also studied in terms of oxyfluorination conditions. As a result, FT-IR exhibits that the carboxyl/ester groups (C=O) at 1632 $cm^{-1} and hydroxyl group (O-H) at 3450 $cm^{-1} are observed in the oxyfluorinated carbon fibers. Especially, the oxyfluorinated carbon fibers have a higher O-H peak intensity than that of the fluorinated ones. XPS result also shows that the surface functional groups, including C-O, C=O, HO-C=O, and C-$F_x$ after oxyfluorination are formed on the carbon fiber surfaces, which are more efficient and reactive to undergo an interfacial reaction to matrix materials. Moreover, the formation of C-$F_x$ physical bonding of the carbon fibers with fluorine increases the surface polarity of the fibers, resulting in increasing ILSS of the composites. This is probably due to the improvement of interfacial adhesion between fibers and matrix resins.

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Effects of NaOH Treatment on the Adsorption Ability of Surface Oxidized Activated Carbon for Heavy Metals

  • Min-Ho Park;So-Jeong Kim;Jung Hwan Kim;Jae-Woo Park
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제28권6호
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    • pp.16-23
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    • 2023
  • Heavy metal (Zinc, Cadmium, Lead) adsorption onto surface modified activated carbon was performed in order to better understand the effect of sodium ion addition to activated carbon. Surface modification methods in this research included water washing, nitric acid washing, and sodium addition after nitric acid washing. These surface modifications generated oxygen functional groups with sodium ions on the surface of the activated carbon.. This caused the change of the specific surface area as well as in the ratio of the carboxyl groups. Heavy metal adsorption onto sodium-containing activated carbon was the most among the three modifications. After the adsorption of heavy metals, the carboxyl group ratio decreased and sodium ions on the surface of the activated carbon were almost non-existent after the adsorption of heavy metals onto sodium-containing activated carbon. The results from this research indicated that ion exchange with sodium ions in carboxyl groups effectively improved heavy metal adsorption rather than electrostatic adsorption and hydrogen ion exchange.

Electro-catalytic Performance of PtRu Catalysts Supported on Urea-treated MWNTs for Methanol Oxidation

  • 박정민;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.159-159
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    • 2009
  • In this work, nitrogen and oxygen functionalities was introduced to the graphite nanofibers (GNFs) and their effect on electrocatalytic performance of the GNF supports for direct methanol fuel cells (DMFCs) was invesigated. The nitrogen and oxygen groups were introduced through the urea treatments and acid treatment, respectively. And, PtRu catalysts deposited on modified GNFs were prepared by a chemical reduction method. The catalysts were characterized by means of elemental analysis, nitrogen adsorption, and X-ray photoelectron spetroscopy (XPS). The structure and morphological characteristics of the catalysts were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). As a result, the Pt-Ru nanoparticles were impregnated on GNFs with good formation in 3-5 nm. And, the cyclic voltammograms for methanol oxidation revealed that the methanol oxidation peak varied depending on changes of surface functional groups. It was thus considered that the PtRu deposition was related to the reduction of PtRu and surface characteristics of the carbon supports. The changes of surface functional groups were related to PtRu reduction, significantly affect the methanol oxidation activity of anode electrocatalysts in DMFCs.

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