• Title/Summary/Keyword: Surface Atmosphere

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Effect of Perovskite Surface Treatment Using Oxygen Atmospheric Pressure Plasma (산소분위기의 상압플라즈마를 이용한 페로브스카이트 표면 처리 효과)

  • Kim, Kyoung-Bo;Lee, Jongpil;Kim, Moojin
    • Journal of Convergence for Information Technology
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    • v.11 no.6
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    • pp.146-153
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    • 2021
  • Recently, research on perovskite semiconductor materials has been performed, and the evaluation of properties using surface treatment for this material is the basis for subsequent studies. We studied the results of surface treatment of perovskite thin films exposed to air for about 6 months by generating oxygen plasma with an atmospheric pressure plasma equipment. The reason for exposure for 6 months is that the perovskite thin film is made of organic and inorganic substances, so when exposed to air, the surface changes through reaction with oxygen or water vapor. Therefore, this change is to investigate whether it is possible to restore the original film. The surface shape and the ratio of elements were analyzed by varying the process time from 1 s to 1200 s in an oxygen plasma atmosphere. It was found that the crystal grains change over a process time of 5 s or more. In order to maintain the properties of the deposited film, it is the optimal process condition between 2 s and 5 s.

Epitaxial Growth of GaAs Thin Films Using MOCVD (MOCVD를 이용한 GaAs 박막의 에피성장)

  • So, Myoung-Gi
    • Journal of Industrial Technology
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    • v.24 no.B
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    • pp.59-64
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    • 2004
  • GaAs thin films were grown epitaxially by MOCVD method on (001) GaAs substrate. And as a surfactant, Bi(bismuth) thin films were deposited on GaAs buffer layer by using TMBi(trimethylbismuth) source. In-situ reflectance difference spectroscopy(RDS) was used to monitor the surface reconstruction of GaAs and Bi thin films. As the results, under the exposure of TBAs(tertiarybuthylarsine) and hydrogen atmosphere, the surface reconstruction of GaAs was changed from As-rich c($4{\times}4$) to As-rich ($2{\times}4$), which was due to the adsoption and desorption of As dimers. The first bismuth surface related RDS signal was reported. At the deposition temperature of $450^{\circ}C$, Bi-terminated GaAs surface showed the RDS spectrum similar to that of Sb-terminated GaAs surface, possibly a ($2{\times}4$) surface. And Bi surface layers were rapidly evaporated with increasing the deposition temperature($550^{\circ}C$), finally becoming As-terminated ($2{\times}4$) surface.

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Surface Characteristics of Hydroxyapatite Coated Surface on Nano/Micro Pore Structured Ti-35Ta-xNb Alloys

  • Jo, Chae-Ik;Choe, Han-Choel
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.185-185
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    • 2014
  • In this study, we investigated surface characteristics of hydroxyapatite coated surface on nano/micro pore structured Ti-35Ta-xNb alloys. This paper was focus on morphology and corrosion resistance of Anodic oxidation. To prepare the samples, Ti-35Ta-xNb (x= 0, 10 wt. %) alloys were manufactured by arc melting and heat-treated for 12 h at $1050^{\circ}C$ in Ar atmosphere at $0^{\circ}C$ water quenching. Micro-pore structured surface was performed using anodization with a DC power supply at 280 V for 3 min, nanotube formed on Ti-35Ta-xNb alloys was performed using DC power supply at 30 V in 60 min at room temperature. Surface morphology and structure were examined by field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction.

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Surface Modification of Polypropylene Meltblown(PPMB) Nonwovens by Plasma Treatment (초극세형 폴리프로필렌부직포의 플라즈마를 이용한 표면개질)

  • Lee, Youn-Eung;Joo, Chang-Whan
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.20-27
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    • 2006
  • On the purpose of surface modifications of polypropylene meltblown(PPMB) nonwovens, PPMB nonwovens were treated in the plasma system by oxygen atmosphere with different treatment time and discharge power. Dimensional change and physical properties of the treated nonwovens were evaluated. Contact angles onto PPMB nonwovens about water and methyleneiodide were measured and surface energies were calculated by Owen's method. As the results, microcraters were observed on the surface of treated nonwovens. Tenacity and breaking strain of PPMB nonwovens decreased with increasing treatment time and discharge power. Surface energy of PPMB nonwovens increased by plasma treatment. Meanwhile, the friction static voltage and dyeability of PPMB nonwovens have enhanced to some extent by oxygen plasma treatment due to the improvement of surface hydrophilicity.

The Effect of $C_2Cl_6$ Addition on Surface Ignition and Oxidation of Molten AM100A Mg alloy (마그네슘 합금 용탕 표면 산화 및 발화에 대한 $C_2Cl_6$의 영향)

  • Choi, Seung-Hwa;Kim, Dae-Hwan;Kim, Hee-Kyung;Shim, Sung-Young;Lim, Su-Gun
    • Journal of Korea Foundry Society
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    • v.30 no.6
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    • pp.231-234
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    • 2010
  • The effect of $C_2Cl_6$ for preventing to the surface oxidation and ignition of molten Mg alloy was studied with metallographic analysis, X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The alloy used for this study was AM100A Mg casting alloy with high strength. In order to investigate the surface protective characteristic of this molten alloy by $C_2Cl_6$ addition, we added them into molten AM100A alloy at $700^{\circ}C$ and then the melts were slowly cooled under a protective atmosphere of air containing Ar gas and $C_2Cl_6$ flux addition. The result found that the surface oxidation and ignition reaction of molten AM100A Mg alloy by adding $C_2Cl_6$ flux was more slowly occurred than that of the only a protective atmosphere of containing Ar gas with increasing time. This result was due to a dense protective film formed containing $MgCl_2$ on surface of molten Mg alloy during casting and solidification. The $MgCl_2$ was formed by a reaction of $C_2Cl_6$ with molten Mg.

Marine Meteorological Characteristics in 2006-2007 : Sea Surface Wind (2006-2007년 해양기상 특성 : 해상풍)

  • You, Sung Hyup;Kwon, Ji Hye;Kim, Jeong-Sik
    • Atmosphere
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    • v.19 no.2
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    • pp.145-154
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    • 2009
  • This study compared the sea surface wind pattern between model results from KMA operational model (RDAPS) and retrieved results from QuickSCAT in the 2006-2007 year. The mean spatial distributions of sea surface wind of RDAPS and QuikSCAT show the prominent seasonal patterns of summer and winter season adjacent to Korean Peninsular. The magnitude of sea surface wind predicted by RDAPS is weaker than that of QuikSCAT in most north Pacific ocean. In summer of 2006 positive bias with the maximum of 1 m/s is appeared in broad region of north Pacific ocean, however. the positive bias region is decreased to small region in 2007. Even though the predicted sea wind by RDAPS is stronger(weaker) than observed one by QuikSCAT in summer (winter), the RDAPS model simulate well the sea surface wind adjacent to Korean peninsular.

SPECTRAL LINE-DEPTH RATIO AS A PRECISE EFFECTIVE TEMPERATURE AND SURFACE GRAVITY INDICATOR FOR WARM STARS

  • Kim, Chul-Hee
    • Journal of The Korean Astronomical Society
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    • v.39 no.4
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    • pp.125-128
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    • 2006
  • In order to determine the precise effective temperature and surface gravity of warm stars, all synthetic spectral lines in the wavelength range of $4000-5700{\AA}$ with T=6000-7750 K, and log g=3.5, 4.0, and 4.5 for [M/H]=0.0, $V_{rot}$=10 km $s^{-1}$, and $V_{tubl}$=2 km $s^{-1}$ were calculated using the SYNSPEC package(Hubeny, et al., 1995) and the Kurucz(1995) model. Then, the depth-ratios for all line pairs were investigated and we selected two and six depth-ratios appropriate for the surface gravity and temperature indicators, respectively. We plotted six grids with X- and Y-axes for the depth-ratios of surface gravity and temperature, respectively, for the simultaneous estimation of these two atmospheric parameters. This method was applied to the spectum of $\delta$ Scu for the determination of its temperature and surface gravity simultaneously.

Evaluation of ultrasonic reflection characteristics on an interface surface using Simulated Annealing (Simulated Annealing기법을 이용한 초음파의 계면 반사 특성평가)

  • 은길수;김노유;나환선
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2002.04a
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    • pp.395-400
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    • 2002
  • Epoxy coating and sealing used in nuclear plants for the protection of radiation degrades with aging and hazardous atmosphere. In order to evaluate the degradation of the epoxy, dependence of the acoustic impedance on the change of mechanical properties has been used. Unlike metals, the surface of the epoxy coating on a concrete liner is so wavy that the acoustic impedance is difficult to measure by using the reflectivity of the ultrasound on the interface surface because of the irregular reflection and propagation from the epoxy surface. SA(simulated annealing) algorithm is applied to calculate the acoustic impedance using a reflection wave from the rough epoxy surface. The surface waviness and acoustic impedance are taken into account and determined by SA method to evaluate the state of degradation quantitatively.

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Surface Modification of a Mild and Stainless Steel by Alumina Spraying (아루미나 용사에 의한 연강 및 스테인레스강의 표면개질)

  • 배종규;박승옥;정인상
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.185-196
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    • 1989
  • The surface modification of a mild and stainless steel by alumina sprayed coating were studied. The effects of surface roughness and bond coating layer on the adhesive strengthy and durability of sprayed specimens were also investiated. The adhesive strength of ceramic coating was affected by surface roughness and bond coating layer thinkness. That showed excellent undergrit blast time and bond coating layer; 60 sec and 0.15-0.33mm, respectively. The adhesive strength and densification of sprayed coating with air pressure were superior to those of without and fracture was mainly occured at alumina-bond coating interface. Under ambient atmosphere at $800^{\circ}C$, the oxides existed within bond coating layer promote diffusion of oxygen to lower durability of sprayed specimens. In this case, fracure was occured at sudstrate-bond coating interface.

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Thermodynamics of Simultaneous Chromizing and Aluminizing of the Mild Steel (연강에 Cr과 Al의 동시 확산 침투 피복의 열역학적 연구)

  • 김선규;신원순
    • Journal of the Korean institute of surface engineering
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    • v.25 no.4
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    • pp.161-164
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    • 1992
  • Thermodynamic calculations were made to find an optimum condition of simultaneous chromizing and aluminizing of mild steel. Results of calculations showed that Cr-Al alloy powder should be used and the optimum composition was 90~95wt% Cr and 5~10wt% Al. Simultaneous chromizing and aluminizing of a mild steel was achieved using 95Cr-5Al wt% alloy powders as a masteralloy, NH4Cl as an activator at $1273^{\circ}$K under Ar atmosphere.

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