• 제목/요약/키워드: Surface Atmosphere

검색결과 1,562건 처리시간 0.025초

High Temperature Corrosion of Ni-17%W Coatings in Ar-0.2%SO2 Atmosphere

  • Lee, Dong-Bok;Kwon, Sik-Chol
    • 한국표면공학회지
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    • 제43권1호
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    • pp.31-35
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    • 2010
  • Coatings of Ni-17 at.%W were electroplated on a steel substrate, and their corrosion behavior was investigated between 600 and $800^{\circ}C$ in an Ar-0.2%$SO_2$ atmosphere. They delayed the corrosion of the steel substrate. They were corroded into an outer NiO-rich layer, and an inner ($WO_3+NiO+NiWO_4$)-mixed oxide layer. Below these oxide layers, a sulfide layer gradually formed.

황산용액 중에서 전해철표면상에 안연-니켈 합금도금에 관한 속도론적 연구 (A Kinetic Study on the Zinc-Nickel Plating on an Elstrolytic Sulface Bathe)

  • 이응조;노재호
    • 한국표면공학회지
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    • 제22권3호
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    • pp.118-127
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    • 1989
  • The rate of electrodeposition Zinc-nickel alloy on to electrolytic ione in sulface solution both under an inter and air atmospherss has studied by use of a rotating disc geometry. The kinetics shows 1st order reaction, and the rate constants are proportional to the square root of rpm, however, they are less than the valuse suggested by Levich. The rate constants of zinc deposition approach the total mass transfer rate constants with increasing potential and deviate with increasing rotaing speed, but those of nickel deposition are constant. Below $40^{\circ}C$ the activation engrgies of zinc deposition and nikel deposition were 4.4Kcal/mol and 6.3Kcal/mol respectively. There results show that overall reaction rate of zinc-nickel plaeting is controlled by mixed reaction and zinc deposotion is more affected by mass transfer reaction than nickel. The current density for the zinc-nickel plating was less in an air atmosphere than in a nitrogen atmosphere. The cathode efficiency increased with decreasing cathode rotating speeds, potentials, and increasing temperatures. Zzinc-nickel platings are more improved in microhardnss than zinc platings.

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산소 분위기에서 열처리시 ZnS 나노선의 발광 강도 변화 (Enhancement of Photoluminescence Intensity of ZnS Nanowires by Annealing in O2)

  • 권진업;이종우
    • 한국표면공학회지
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    • 제45권5호
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    • pp.193-197
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    • 2012
  • The influence of annealing process in an $O_2$ atmosphere on the photoluminescence (PL) spectra properties of ZnS nanowires has been investigated. ZnS nanowires with the diameters approximately 100 nm and the lengths a few tens micrometers were synthesized by evaporating ZnS powders on Si substrates while using an Au thin film as a catalyst. ZnS nanowires had an NBE emission band at 430 nm in the violet region. The emission intensity was improved drastically by a process in which ZnS nanowires were heat-treated at $500^{\circ}C$ in an $O_2$ atmosphere for 45 minutes.

Numerical Simulation of the Effects of Moisture on the Reinforcement of a Tropopause Fold

  • Lee, Hong-Ran;Kim, Kyung-Eak;Lee, Yong-Hee
    • 한국지구과학회지
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    • 제30권5호
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    • pp.630-645
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    • 2009
  • The tropopause fold event that took place on January 1, 1997 over mid-region on the Korean Peninsula is examined by means of a numerical simulation based on a Mesoscale Model (MM5). The purpose of this paper is to investigate the effects of moisture in reinforcing a tropopause fold linked to an explosive cyclone. Two types of simulations were carried out; 1) simulations for moist conditions in which full physical and dynamic processes are considered and 2) simulations for dry conditions in which cumulus parameterization and cloud microphysics process are excluded. The results of the moist condition simulations demonstrate that the intensity of the central pressure of the cyclone was overestimated compared with the observed values and that the location of the center and the pressure deepening rates (-17 hPa/12 hr) complied with the observed values. The potential vorticity (PV) anomaly on the isentropic surface at 305 K continued to move in a southeast direction on January 1, 1997 and thus created a single tube of tropopause fold covering the northern and the middle area of the Korean Peninsula and reaching the ground surface at 0300 UTC and 0600 UTC. The results of the dry condition simulations show that the tropopause descended to 500 and 670 hPa in 0300 and 0600 UTC, respectively at the same location for the moist condition simulation; however, there was no deep tropopause fold observed. A comparison of the simulated data between the moist and the dry conditions suggests that a deep tropopause fold should happen when there is sufficient moist in the atmosphere and significantly large PV in the lower atmosphere pulls down the upper atmosphere rather than when the tropopause descends itself due to dynamic causes. Thus, it is estimated that moisture in the atmosphere should have played a crucial role in a deep tropopause fold process.

레이더에서 고고도 표적물의 고도 예측 성능 향상을 위한 한국형 지수 모델 개발에 관한 연구 (Development of Exponential Model of Korea for Improved Altitude Estimation Performance of High-Altitude Target at Radar System)

  • 문현욱;전민현;김우중;오성근;이종현;권세웅;윤영중
    • 한국전자파학회논문지
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    • 제23권7호
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    • pp.831-839
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    • 2012
  • 본 논문에서는 레이더 이용 시 대기 굴절에 의한 고고도 표적물의 고도 오차를 최소화하기 위한 한국형 지수모델을 제안하였다. 이를 위해 한국 7개 기상 관측소에서 6년간 측정된 데이터를 바탕으로 표면 굴절도(surface refractivity)와 굴절도 감쇄율(refractivity gradient) 간의 상관 관계를 최소 자승법을 이용하여 도출하고, 이를 지수모델에 적용하였다. 또한, 제안된 모델의 검증을 위해 표준 대기(standard atmosphere) 모델, CRPL(Central Radio Propagation Lab.) 지수 모델, 제안된 한국형 지수 모델에 대한 고도 오차를 광선 추적법을 이용하여 도출하고, 그 특성을 분석하였다. 그 결과, 표준 대기 모델에 비해서는 50~60 %, CRPL 지수 모델에 비해서는 약 60 % 수준의 고도 오차를 나타내 제안된 모델을 적용 시 레이더의 고도 예측 성능을 향상시킬 수 있음을 확인하였다.

고강도 7xxx 알루미늄 합금의 응력부식균열에 미치는 부식환경과 응력속도의 영향 (Effect of Corrosion Atmosphere and Strain Rate on the Stress Corrosion Cracking of High Strength 7xxx Aluminum Alloy)

  • 윤여완;김상호
    • 한국표면공학회지
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    • 제41권3호
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    • pp.121-128
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    • 2008
  • High strength 7xxx aluminum alloys have been applied to automotive bump back beam of the some limited model for light weight vehicle. The aluminum bump back beam is manufactured through extrusion, bending and welding. The residual stress given on these processes combines with the corrosive atmosphere on the road spreaded with corrosive chemicals to melt snow to occur the stress corrosion cracking. The composition of commercial 7xxx aluminum has Zn/Mg ratio about 3 and Cu over 2 wt% for better strength and stress corrosion cracking resistivity. But this composition isn't adequate for appling to the automotive bump back beam with high resistance to extrusion and bad weldability. In this study the composition of 7xxx aluminum alloy was modified to high Zn/Mg ratio and low Cu content for better extrusion and weldability. To estimate the resistivity against stress corrosion cracking of this aluminum alloy by slow strain rate test, the corrosion atmosphere and strain rate separate the stress corrosion cracking from conventional corrosion must be investigated. Using 0.6 Mol NaCl solution on slow strain rate test the stress corrosion cracking induced fracture was not observed. By adding 0.3% $H_2O_2$ and 0.6M $Na_2SO_4$ to 1M NaCl solution, the corrosion potential and current density of polarization curve moved to active potential and larger current density, and on the slow strain rate test the fracture energy in solution was lower than that in pre-exposure. These mean the stress corrosion cracking induced fracture can be estimated in this 1M NaCl + 0.3% $H_2O_2$ + 0.6M $Na_2SO_4$ solution. When the strain rate was below $2{\times}10^{-6}$, the stress corrosion cracking induced fracture start to be observed.

The Error of the Method of Angular Sections of Microwave Sounding of Natural Environments in the System of Geoecological Monitoring

  • Fedoseeva, E.V.;Kuzichkin, O. R.
    • International Journal of Computer Science & Network Security
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    • 제21권6호
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    • pp.47-53
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    • 2021
  • The article deals with the problems of application of microwave methods in systems of geoecological monitoring of natural environments and resources of the agro-industrial complex. It is noted that the methods of microwave radiometry make it possible, by the power of the measured intrinsic radio-thermal radiation of the atmosphere, when solving inverse problems using empirical and semi-empirical models, to determine such parameters of the atmosphere as thermodynamic temperature, humidity, water content, moisture content, precipitation intensity, and the presence of different fractions of clouds.In addition to assessing the meteorological parameters of the atmosphere and the geophysical parameters of the underlying surface based on the data of microwave radiometric measurements, it is possible to promptly detect and study pollution of both the atmosphere and the earth's surface. A technique has been developed for the analysis of sources of measurement error and their numerical evaluation, because they have a significant effect on the accuracy of solving inverse problems of reconstructing the values of the physical parameters of the probed media.To analyze the degree of influence of the limited spatial selectivity of the antenna of the microwave radiometric system on the measurement error, we calculated the relative measurement error of the ratio of radio brightness contrasts in two angular directions. It has been determined that in the system of geoecological monitoring of natural environments, the effect of background noise is maximal with small changes in the radiobrightness temperature during angular scanning and high sensitivity of the receiving equipment.

대기/해양 접합 GCM을 이용한 지구 온난화의 추정 (Estimation of Global Warming by Coupled Atmosphere-Ocean GCM)

  • 김정우;박지업
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2000년도 춘계 학술대회논문집
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    • pp.14-19
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    • 2000
  • A coupled general circulation model (GCM) of the global atmosphere, oceans and lands is used for finding the future climate at times of doubled carbon dioxide concentration (DCDC) of the atmosphere. Two runs of the model were made in order to find the future change. Global changes at times of DCDC may be characterized by a global warmig of $1.4^{\circ}C$, a $3\%$ global precipitation increase, and an increase in the surface available water (SAW) over the global land among others. The estimated increase in SAW over the land implies that river discharge is likely to increase with increased chance of severe weather as a result of the future global warming.

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