• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3389-3394
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• 2011

Isomeric trimethylbenzyl radicals were generated and vibronically excited from precursor 1,2,3,5-tetramethylbenzene, isodurene, with a large amount inert carrier gas helium in a corona excited supersonic expansion (CESE) using a pinhole-type glass nozzle. A long-path monochromator was used to record the visible vibronic emission spectra of the jet-cooled benzyl-type radicals in the $D_1{\rightarrow}D_0$ electronic transition. From the analysis of the spectra, we identified the evidence of the presence of three isomeric trimethylbenzyl radicals in the corona discharge, and obtained the electronic energy and a few vibrational mode frequencies in the ground electronic state for each isomer.

• International Journal of Precision Engineering and Manufacturing
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• 제9권1호
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• pp.51-53
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• 2008

A new nano-particle deposition system (NPDS) was developed for a ceramic and metal coating process. Nano- and micro-sized powders were sprayed through a supersonic nozzle at room temperature and low vacuum conditions to create ceramic and metal thin films on metal and polymer substrates without thermal damage. Ceramic titanium dioxide ($TiO_2$) powder was deposited on polyethylene terephthalate substrates and metal tin (Sn) powder was deposited on SUS substrates. Deposition images were obtained and the resulting chemical composition was measured using X-ray photoelectron spectroscopy. The test results demonstrated that the new NPDS provides a noble coating method for ceramic and metal materials.

• Bulletin of the Korean Chemical Society
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• 제31권9호
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• pp.2479-2482
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• 2010

Using a pinhole-type glass nozzle equipped for a corona-excited supersonic expansion (CESE), precursor 2,6-dichlorotoluene seeded in a large amount of inert carrier gas helium was discharged to produce jet-cooled but electronically excited benzyl-type radicals. The visible vibronic emission spectrum was recorded with a long-path monochromator to observe vibronic bands in the $D_1{\rightarrow}D_0$ electronic transition of benzyl-type radicals. The spectral analysis revealed the generation of not only the 2,6-dichlorobenzyl radical as a typical product, but also the o-chlorobenzyl radical as an unexpected species, which indicates the possible molecular rearrangement in eliminating a chlorine atom from the benzene ring. A possible mechanism is proposed for the formation of the o-chlorobenzyl radical from the precurs or in the gas phase.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 1998년도 춘계 학술대회논문집
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• pp.35-42
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• 1998

Time marching algorithms applied to compressible Navier-Stokes equation have a convergence problem at low Mach number. It is mainly due to the eigenvalue stiffness and pressure singularity as Mach number approaches to zero. Among the several methods to overcome the shortcomings of time marching scheme, time derivative preconditioning method have been used successfully. In this numerical analysis, we adopted a preconditioner of K.H. Chen and developed a two-dimensional, axisymmetric Navier-Stokes program. The steady state driven cavity flow and backward facing step flow problems were computed to confirm the accuracy and the robustness of preconditioned algorithm for low Mach number flows. And the transonic and supersonic flows insice the JPL axisymmetric nozzle internal flow is exampled to investigate the effects of preconditioning at high Mach number flow regime. Test results showed excellent agreement with the experimental data.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.574-579
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• 2003

The present study addresses an analytical investigation to understand the characteristics of gas flow in the High-Velocity Oxy-Fuel(HVOF) thermal spray gun. One-dimensional analysis is extended to involve the effects of the wall friction and powder particle diameter. From the present analysis it is well known that the flow characteristics inside and outside the thermal spray gun is varied depending on the combustion chamber pressure. The thermal spray gun flow is characterized by six different patterns. The powder particle size and wall friction significantly influence the powder particle velocity. The particle velocity decreases with an increase in the powder particle size. This implies that the combustion chamber pressure should be increased to achieve a higher velocity of the powder particle.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2783-2785
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• 2010

Searching for new molecular radicals which are believed to play an important role as reaction intermediates in aromatic chain reactions, we have applied the technique of corona excited supersonic expansion employing a pinhole-type glass nozzle to obtain the vibronic spectrum from the corona discharge of precursor 3,5-difluorotoluene with a large amount of inert carrier gas helium. An analysis of the observed spectrum revealed that many vibronic bands are from other isomeric difluorobenzyl radicals generated in the jet by migration of the fluorine atom or methylene group to the adjacent position in the 3,5-difluorobenzyl radical. A possible mechanism was proposed for the formation of other isomers by using a bridged cyclic intermediate structure.

• 대한기계학회논문집B
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• 제32권12호
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• pp.931-937
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• 2008

A high motive pressure thermal vapor compressor(TVC) for a commercial multi-effect desalination(MED) plant is designed to have a high entraining performance and its robustness is also considered in the respect of operating stability at the abrupt change of the operating pressures like the motive and suction steam pressure which can be easily fluctuated by the external disturbance. The TVC having a good entraining performance of more than entrainment ratio 6.0 is designed through the iterative CFD analysis for the various primary nozzle diameter, mixing tube diameter and mixing tube length. And then for a couple of TVC having a similar entrainment ratio, the changes of the entrainment ratio are checked along the motive and suction pressure change. The system stability is diagnosed through the analyzing the changing pattern of the entrainment ratio.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년 영문 학술대회
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• pp.506-510
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• 2008

Ramjets are capable of much higher specific impulse than liquid rocket engines for high speed flight in the atmosphere. Ramjets, however, cannot generate thrust at low flight speed. Therefore, an additional propulsion device to accelerate the ramjet vehicle to a supersonic speed is required. In this study, we propose a novel ramjet propulsion system with a $H_2O_2$/Kerosene rocket as the accelerator for initial stage. In order to test the feasibility of this concept, consecutive reactors was built; one for the decomposition of $H_2O_2$ and the other for kerosene combustion. Decomposed $H_2O_2$ jet was injected to combustor through converging nozzle from gas generator and over this hot oxygen jet, kerosene was injected by spay injector. Through the various test cases, hypergolic ignition test was carried out and steady combustion was achieved.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년도 제31회 추계학술대회논문집
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• pp.439-441
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• 2008

유도무기의 사출모타에서 분출되는 초음속 배기화염을 해석하기 위하여 삼차원 전산유체역학 연구가 수행되었다. 이 연구의 목적은 작은 엄폐호에 있는 사수에 미치는 충격을 판단하기 위함이다. 이번 논문에서는 격자생성과 해법기술 등을 포함한 수치해석방법의 소개가 주를 이룬다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2012년도 제38회 춘계학술대회논문집
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• pp.238-238
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• 2012

Report is devoted to place and role of numerical simulation in design of rocket propulsion systems. In introduction advanced solutions in liquid propellant rocket engines design are presented. Further essence of design process described briefly. The central place of method of solution of direct problem in design process was shown. Numerical simulation for solving direct problem of fluid dynamic was used as the alternative to theoretical and experimental approaches. Main features of numerical models of processes in propulsion systems were observed. Some results of simulation and (or) design of different types of chemical propulsion system were presented also. The combined rocket engine, rocket engine with injection of after-turbine gas into supersonic part of the nozzle, solid propellant engine and hybrid propulsion engine are under consideration.