• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.243-249
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• 2006

Porous polymer gel electrolytes (PGEs) based on poly(vinylidenefluoride-co-hexafluoropropylene) (P(VdF-co-HFP)) as a polymer matrix and polyvinylpyrolidone (PVP) as a pore-forming agent were prepared and electrochemical properties were investigated for an electric double layer capacitor (EDLC) in order to increase a permeability of an electrolyte into the PGE. Propylene carbonate (PC) and ethylene carbonate (EC) as plasticizers, and tetraethylammonium tetrafluoroborate ($TEABF_4$) as a supporting salt for the PGE were used. EDLC unit cells were assembled with the PGE and electrode comprising BP-20 and MSP-20 as activated carbon powders, Super P as a conducting agent, and P(VdF-co-HFP)/PVP as a mixed binder. Ion conductivity of PGEs increased with an increased PVP content and was the best at 7 wt% PVP, whereas electrochemical characteristics such as AC-ESR of unit cell were better in 3 wt%. And electrochemical characteristics of the unit cell with PGE were the best at a 33 : 33 weight ratio of PC to EC. Specific capacitance of a mixed plasticizer system of PE and EC was higher than that of pure PC. Ion conductivity of PGEs with a film thickness of $20{\mu}m$ was higher, but electrochemical characteristics of unit cells were higher for a $50{\mu}m$ membrane thickness. Also, the unit cell has shown the highest capacitance of 31.41 F/g and more stable electrochemical performance when PGE and electrode were hot pressed. Consequently, the optimum composition ratio of PGE for EDLCs was 23 : 66 : 11 wt% such as P(VdF-co-HFP) : PVP = 20 : 3 wt% and PC : EC = 44 : 22 wt%. In this case, $3.17{\times}10^{-3}S/cm$ of ion conductivity was achieved at the $50{\mu}m$ thickness of PGE for EDLCs. And the electrochemical characteristics of unit cells were $2.69{\Omega}$ of DC-ESR, 28 F/g of specific capacitance, and 100% of coulombic efficiency.

• Journal of the Korea Concrete Institute
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• v.20 no.3
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• pp.307-315
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• 2008

In this study, it is investigated the properties of high strength concrete using mineral admixture, on the purpose of use of meta kaolin for the substitutive materials to silica fume which is so expensive. The plain mixtures are 3 degrees which are ordinary portland cement, blast furnace slag cement and OPC included fly ash 20%, and silica fume and meta kaolin are substituted for the each plain mixtures in the range of 20%. The results of experiment showed as follows. In case of silica fume was only used, the viscosity and slump flow of fresh concrete were much decreased, on the contrary air content increased. But as usage of meta kaolin increased, to being increase the viscosity of fresh concrete, slump flow increased and air content and usage of super-plasticizer were decreased. Accordingly the workabilities of concrete were against tendency between silica fume and meta kaolin. The compressive strength, velocity of ultrasonic pulse and unit weight were increased according to usage of meta kaolin, the properties of hardened concrete were judged that they are affected with air content of fresh concrete, so it is very important to control air content of high strength concrete. Therefore, the use of meta kaolin is prospected to the substitutive material of silica fume, in case of using silica fume and meta kaolin, it is judged that the optimum usage of silica fume and meta kaolin is about 10% respectively, considering workability and strength of concrete.

• Tunnel and Underground Space
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• v.19 no.5
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• pp.373-387
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• 2009

Considering the current construction technology and research status of deep repository tunnels for radioactive waste disposal, it is inevitable to use cementitious materials in spite of serious concern about their long-term environmental stability. Thus, it is an emerging task to develop low pH cementitious materials. This study reviews the state of the technology on low pH cements developed in Sweden, Switzerland, France, and Japan as well as in Finland which is constructing a real deep repository site for high-level radioactive waste disposal. Considering the physical and chemical stability of bentonite which acts as a buffer material, a low pH cement limits to $pH{\leq}11$ and pozzolan-type admixtures are used to lower the pH of cement. To attain this pH requirement, silica fume, which is one of the most promising admixtures, should occupy at least 40 wt% of total dry materials in cement and the Ca/Si ratio should be maintained below 0.8 in cement. Additionally, selective super-plasticizer needs to be used because a high amount of water is demanded from the use of a large amount of silica fume.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.433-439
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• 2023

In this study, the bonding performance of repair materials was evaluated on concrete repair surface to develop concrete repair materials based on UHPC (Ultra High Performance Concrete) which has high mechanical and durability performance. The ten test variables were applied considering the roughness and wet condition of the concrete surface subject to repair, the addition of polymer, and the use PP and PVA fibers in repair materials. The addition of the polymer caused a significant decrease in strength, which was thought to be due to the effect of the additional super plasticizer used to adjust workability. Also, flow was reduced by up to 13.8 % with the use of plastic-based fibers. As a result of evaluating the bond strength of the repair material considering the condition of the surface subject to repair, it was thought that in the case of using UHPC-based repair material, high bonding performance could be secured without any additional surface treatment as long as the surface of the base material was sound. In addition, UHPC-based repair materials showed high bonding performance even when the attachment surface was wet. In the future, research will be conducted on shot-crete application and gradient pouring for the development of UHPC-based repair materials, and continuous improvement in the repair material mixing property will be carried out to ensure economic efficiency and performance as a concrete structural repair material.