• 제목/요약/키워드: Super-Critical Water Oxidation

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슬러리형 돈사분뇨처리를 위한 초임계수 산화공정의 최적 조건 (Optimum Conditions of Super-critical Water Oxidation Process for Treatment of Slurry Piggery Wastewater)

  • 김은호;서정윤
    • 한국환경보건학회지
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    • 제34권4호
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    • pp.333-341
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    • 2008
  • In this study, the possibility and the optimal conditions for treating slurry type piggery wastewater using supercritical water oxidation were tested in the laboratory. The results could be summarized as follows; The slurry type piggery wastewater, which was diluted 50 times, was treated most effectively at the pressure of 300 bar, the temperature of $550^{\circ}C$ and the residence time of 10 minutes. The air saturated water was injected, as an oxidizing agent, and the removal efficiencies of $COD_{Cr}$, T-N, $NH_4^+$-N and T-Pattheoptimal conditions were 92, 40, 59 and 100%, respectively. Therefore, analte rnativemea suremu stbetaken to improve theremo valefficiency of the nitrogen compounds.

다양한 제조방법으로 제조된 V2O5-TiO2 촉매를 이용한 제련공정에서 발생한 황화수소 제거능 비교 (Performance of V2O5-TiO2 Catalyst Prepared by Various Methods for Removal of Hydrogen Sulfide Emitted from Steel Smelting Process)

  • 김문일
    • 한국환경과학회지
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    • 제30권6호
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    • pp.501-505
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    • 2021
  • V2O5-TiO2 catalysts were prepared by various methods. V2O5-TiO2 were prepared by sol-gel method with different drying conditions (aerogel and xerogel), and V2O5 supported on TiO2 obtained by sol-gel method with precipitation-deposition method and impregnation method. The performance of the V2O5-TiO2 catalysts was investigated for the selective oxidation of hydrogen sulfide in the stream containing both ammonia and excess water. All the catalysts showed good dispersion of vanadium and they had high H2S conversion with no or little production of sulfur dioxide. The V2O5-TiO2 aerogel catalyst prepared by sol-gel method with drying under super critical condition had the highest surface area which led to better catalytic activity compared to those by other synthesis methods.

초임계수 산화공정에 의한 원전 폐수지 처리기술 (Treatment of Spent ion-Exchange Resins from NPP by Supercritical Water Oxidation(SCWO) Process)

  • 김경숙;손순환;송규민;한주희;한기도;도승회
    • 방사성폐기물학회지
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    • 제7권3호
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    • pp.175-182
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    • 2009
  • 유동층 비중차 분리기를 이용하여 혼합 폐 이온교환수지에서 폐 양이온수지와 폐 음이온수지로 분리하였으며, 원소분석과 열분석으로 분리가 잘 되었음을 확인하였다. 비중차 분리를 통해 얻은 수백 미크론의 구형 알갱이 형태의 폐 양이온수지와 폐 음이온수지 각각을 볼밀로써 24시간 습식 분쇄하여 적정 입도 이하의 입자가 균일하게 분산된 고농도 슬러리를 얻은 다음, 희석하여 $COD_{cr}$, 농도 25,000ppm의 시료를 준비하였다. 실험실 규모의 소형 초임계수산화(Super Critical Water Oxidation, SCWO) 장치(반응기 용량 : 220 mL)로써 화력발전소에서 발생한 폐 양이온수지와 폐 음이온수지에 대해 최적의 분해조건을 확립한 다음, 파일럿플랜트(반응기 용량 : 24 L)로 scale-up 실험을 수행하였다. 우선 화력발전소의 폐수지로서 파일럿테스트를 실시한 다음, 원자력발전소의 폐수지로써 파일럿테스트를 수행하여 최적의 분해조건을 설정하였다. 실험실 규모의 소형 SCWO 장치와 파일럿플랜트의 설계 및 운전에서 얻은 경험을 바탕으로 원자력발전소 내에 설치 가능한 규모로 상용설비(처리용량 : 150kg/h)를 설계 중에 있다.

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Stability and antioxidant effect of rapeseed extract in oil-in-water emulsion

  • Zhang, Hua;Shin, Jung-Ah;Hong, Soon Taek;Lee, Ki-Teak
    • 농업과학연구
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    • 제43권2호
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    • pp.249-257
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    • 2016
  • In this study, rapeseed extracts were obtained by supercritical carbon dioxide fluid extraction of defatted rapeseed to evaluate the stability and antioxidant activity of an oil-in-water (O/W) emulsion system. The oil-in-water emulsions were prepared from stripped soybean oil with different concentrations (0.3, 0.4, 0.5, and 0.6%) of rapeseed extract as an emulsifier. Their emulsion stability was compared to that of emulsions prepared with the commercial emulsifier, Tween 20 (Polysorbate 20, 0.2%). After stripping the soybean oil, the total tocopherol content was reduced from 51.4 g/100 g to 1.1 g/100 g. Emulsion stability and oxidative stability of emulsions prepared with Tween 20 and rapeseed extract as emulsifiers were evaluated. For 30 days droplet sizes of emulsions containing rapeseed extract (0.4, 0.5, and 0.6%) were not significantly different (p > 0.05). Similar results were obtained for emulsion stability (ES) and Turbiscan analysis, suggesting that the addition of rapeseed extract increased emulsion stability. The addition of rapeseed extract at more than 0.4% resulted in an emulsion stability comparable to the addition of 0.2% Tween 20. The antioxidative ability of rapeseed extract increased with the amount added in the emulsion. Moreover, the addition of 0.6% rapeseed extract resulted in the lowest emulsion peroxide values (10.3 mEq/L) among all treatments. Therefore, according to the stability of its antioxidative and physical stability properties, rapeseed extract from super critical extraction could be successfully applied to the food and cosmetic industries.