• Title/Summary/Keyword: Sulphur content

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Effect of S on Arc Stability of MAG Welding (MAG용접의 Arc안정성에 미치는 S의 영향)

  • 안영호;이종봉;엄동석
    • Journal of Welding and Joining
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    • v.17 no.1
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    • pp.55-61
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    • 1999
  • The effect of S content in welding wires on the arc stability was investigated, in the region of short circuit transfer and spray transfer. In the region of short circuit transfer, with increasing S content, average arcing time and average short circuit time were decreased. Therefore, droplet transfer frequency was increased, due to the reduction of arcing time and peak current at the moment of arc-reiginition was decreased, due to the decrease of short circuit time. In the region of spray transfer, the fluctuation degree of arc current and arc voltage became more stable, with increasing S content.

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Experimental investigation for partial replacement of fine aggregates in concrete with sandstone

  • Chandar, K. Ram;Gayana, B.C.;Sainath, V.
    • Advances in concrete construction
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    • v.4 no.4
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    • pp.243-261
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    • 2016
  • This research study focuses on utilizing sandstone which is overburden waste rock in coal mines to use in concrete as a replacement of fine aggregate. Physical properties of sandstone like water absorption, moisture content, fineness modulus etc., were found to be similar to conventional fine aggregate. Scanning Electron Microscope (SEM) analysis was carried out for analysing elemental composition of sandstone. There was no sulphur content in sandstone which is a good sign to carry the replacement. Fine aggregate was replaced with sandstone at 25%, 50%, 75% and 100% by volume and moulds of concrete cubes and cylinders were prepared. Compressive strength of concrete cubes was tested after 3, 7 and 28 days and split tensile & flexural strength was determined after 28 days. The strength was found to be increasing marginally with increase in sandstone content. Fine aggregate that was replaced by 100% sandstone gave highest strength among all the replacements for the compressive, split tensile and flexural strengths. Though increase in strength was marginal, still sandstone can be an effective replacement for sand in order to save the natural resource and utilize the waste sandstone.

The effect of carbon content on hot cracking of low carbon steel weld (저탄소성 용접금속의 응고균열에 미치는 탄소함량의 영향)

  • ;;Masumoto, I.
    • Journal of Welding and Joining
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    • v.6 no.4
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    • pp.16-26
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    • 1988
  • The effect of carbon content on hot cracking of welded carbon steel was investigated Eight steel plates whose carbon content range from 0.02 to 0.23 percent were welded by autogeous gas tungsten are process. Constant strain was applied to the hot crack test specimen under the strain rate of 0.15 mm per second during welding. The hot cracking susceptibility ws high in the rnage of 0.02-0.05 and 0.12-0.23 percent carbon contents. The critical carbon content immune to hot cracking is in the range from 0.07 to 0.12 percent carbon. By electron probe microanalyser, amanganese segregation was not seen significantly in the whole carbon range. But segregation of silicon was higher in the region of low carbon contents. However, sulphur was segregated remarkably in the region betwen 0.18 and 0.23 percent carbon by peritectic reaction. Very smal lamount of dnedritic structure was observed in the region from 0.02 to 0.05 percent carbon by peritectic reaction. Very small amount of dendritic structure was observed in the region from 0.02 to 0.05 percent carbon but the predominant solidification structure was smooth by cellular growth. The higher the carbon content is, the more the columnar dendritic structure was observed.

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Compositional Variation of Arsenopyrites in Arsenic and Polymetallic Ores from the Ulsan Mine, Republic of Korea, and their Application to a Geothermometer (울산광산산(蔚山鑛山産) 유비철석(硫砒鐵石)의 조성변화(組成變化) 및 지질온도계(地質溫度計)에 대(對)한 적용(適用))

  • Choi, Seon-Gyu;Chung, Jae-Ill;Imai, Naoya
    • Economic and Environmental Geology
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    • v.19 no.3
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    • pp.199-218
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    • 1986
  • Arsenopyrite in arsenic and polymetallic ores from calcic Fe-W skarn deposit of the Ulsan mine, Republic of Korea, has been investigated by means of electron microprobe analysis and X-ray diffractometry. As a result, it is revealed that the Ulsan arsenopyrite may be classified into the following three species with different generation on the basis of its mode of occurrence, chronological order during polymetallic mineralization and chemical composition; arsenopyrites I, II and III. 1) Arsenopyrite I-(Ni, Co)-bearing species belonging to the oldest generation, which has crystallized together with (Ni, Co)-arsenides and -sulpharsenides in the early stage of polymetallic mineralization. In rare cases, it contains a negligible amount of antimony. It occurs usually as discrete grains with irregular outline, showing rarely subhedral form, and is diffused in skarn zone. The maximum contents of nickel and cobalt are 10.04 Ni and 2.45 Co (in weight percent). Occasionally, it shows compositional zoning with narrow rim of lower (Ni+Co) content. 2) Arsenopyrite II-arsenian species, in which (Ni+Co) content is almost negligible, may occur widely in arsenic ores, and its crystallization has followed that of arsenopyrite I. It usually shows subhedral to euhedral form and is closely associated with $l{\ddot{o}}llingite$, bismuth, bismuthinite, chalcopyrite, sphalerite, bismuthian tennantite, etc. It is worthy of note that arsenopyrite II occasionally contains particles consisting of both bismuth and bismuthinite. 3) Arsenopyrite III-(Ni, Co)-free, S-excess and As-deficient species is close to the stoichiometric composition, FeAsS. It occurs in late hydrothermal veins, which cut clearly the Fe-W ore pipe and the surrounding skarn zone. It shows euhedral to subhedral form, being extremely coarse-grained, and is closely associated with pyrite, "primary" monoclinic pyrrhotite, galena, sphalerite, etc. Among three species of the Ulsan arsenopyrite, arsenopyrite I does not serve as a geothermometer, because (Ni+Co) content always exceeds 1 weight percent. In spite of the absence of Fe-S minerals as sulphur-buffer assemblage, the presence of $Bi(l)-Bi_2S_3$ sulphur-buffer enables arsenopyrite II to apply successfully to the estimation of either temperature and sulphur fugacity, the results are, $T=460{\sim}470^{\circ}C$, and log $f(S_2)=-7.4{\sim}7.0$. With reference to arsenopyrite III, only arsenopyrite coexisting with pyrite and "primary" monoclinic pyrrhotite may serve to restrict the range of both temperature and sulphur fugacity, $T=320{\sim}440^{\circ}C$, log $f(S_2)=-9.0{\sim}7.0$. These temperature data are consistent with those obtained by fluid inclusion geothermometry on late grandite garnet somewhat earlier than arsenopyrite II. At the beginning of this paper, the geological environments of the ore formation at Ulsan are considered from regional and local geologic settings, and physicochemical conditions are suspected, in particular the formation pressure (lithostatic pressure) is assumed to be 0.5kb (50MPa). The present study on arsenopyrite geothermometry, however, does not bring about any contradictions against the above premises. Thus, the following genetical view on the Ulsan ore deposit previously advocated by two of the present authors (Choi and Imai) becomes more evident; the ore deposit was formed at shallow depth and relatively high-temperature with steep geothermal gradient-xenothermal conditions.

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Effect of Simulated Acid Rain on Crops (농작물(農作物)에 대(對)한 인공산성(人工酸性)비의 영향(影響))

  • Kim, Bok-Young;Kim, Kyu-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.2
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    • pp.161-167
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    • 1988
  • Studies were carried out to examine the effects of simulated acid rain on the various crops of rice, peper, tomato, pumpkin, egg plant, potato, soybean, radish, cucumber, common pea, sweet potato, corn, lettuce, chinse cabbage, spinach, under the condition of the rains of pH 3.0. The rain was adjusted to pH 4.0, 3.0, 2.0 with sulfuric acid, and soybeans were exposed with the various pH levels, eighteen times every other days. The symptoms of damage, ratios of destroyed leaf and sulphur content by leaves were investigated. The results obtained were as follows. 1. The exposure to the rain resulted in the reddish brown or white pigment spots in the leaves surface and the colour was developed red and darker along the edge of spots. 2. Most crops were affected with acid rain of pH 3.0 at which the amount of chlorophyl was decreased. 3. The spinach, chinese cabbage, lettuce were sensitive to the acid rain, however, the peper, tomato pumpkin were resistance to it. 4. The content of chlorophyl was decreased with increasing leave injury. 5. The sulphur content in leave was increased with increasing acidity of the rain, however the yield was decreased.

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Removal of Impurities from Waste Carbon Sludge for the Recycling (폐 카본슬러지의 재활용을 위한 不純物 분리 제거)

  • 이성오;국남표;오치정;김선태;신방섭
    • Resources Recycling
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    • v.10 no.3
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    • pp.51-59
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    • 2001
  • Impurities removal from waste carbon black was carried out to produce high-grade carbon black. A large amount of hydrophilic carbon black is produced as a byproduct of the hydrogen production process by flame decomposition of water. Due to its impurities content such as sulphur, iron, ash, etc., it can only be used as low-grade carbon or burnt out. High-grade hydrophilic carbon black is 3~5 times more expensive than oil-based carbon black because of high production cost associated with process complexly and pollutant treatment. Hydrophilic carbon is normally used for conductive materials for batteries, pigment for plastics, electric wire covering, additives for rubber, etc. In these applications, impurity content must be blow 1 fe. In this study, magnetic separation, froth flotation and ultrasonic treatment were employed to remove impurities from the low-grade hydrophilic carbon black. Results showed that the ash, iron and sulphur content of product decreased to less than 0.01 wt.%, 0.01 wt.% and 0.3 wt % respectively and the surface area of product was about 930 $m^2$/g for conductive materials.

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Chemical Properties of Sediment and Increase of Reed (Phragmites australis) Stands at Suncheon Bay (순천만 갈대군락의 면적 증가와 저토의 이화학적 특성)

  • Lee, Yeon Gyu;Kim, Shin;Lee, Hye Won;Min, Byeong Mee
    • Journal of Wetlands Research
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    • v.10 no.3
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    • pp.9-26
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    • 2008
  • To clarify the reed (Phragmites australis) stand's effects on the sediment properties and its increasing pattern, breaths of reed stands in 1999 and 2000, and sediment properties - water, salt, organic matter, sulphur, nitrogen, carbon and hydrogen contents - along th depth at the three stands in 2007 were surveyed at Suncheon Bay. Regardless of reed stand, the more distance from the land was long, the more water and salt contents of sediment were high. Organic matter content of sediment was high and increased with the reed biomass at the upper layer but low regardless of biomass at the lower layer. Sulphur content of sediment was higher at old reed stand (0.33%) than at new stand (0.21%) or non-vegetated stand (0.23%). Carbon, nitrogen and hydrogen contents of sediment were similar at three stands in mean values. However, their contents were high at upper layer and low at lower layer in a stand. Therefore, the changing pattern of organic matter content with the depth was similar to but not coincided to the inorganic nutrients' ones. The mean breadth of reed stands increased $2.33{\pm}0.73m$ in 1999 and $3.65{\pm}1.64m$ in 2000. However, the increase of reed stands' breadth a year varied along the direction, year or stands, so that there was not a trend in increasing pattern. It was thought that this increasing pattern made the reed's patch round. The height and density of reed shoot in newly formed stand decreased with the distance from the center of stand. In the newly formed peripheral area of a reed stand, the shoot density was not related with the land (north) or sea (south) direction, however, the shoot height was higher in the sea (south) than in the land (north) direction.

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A Study on the Technical Strategy on the IMO Air Pollution Prevention (IMO의 대기오염규제에 따른 기술적 대응전략에 관한 연구)

  • Kim, Jong Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.69-69
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    • 1996
  • As conservation of global environment has becoming a major outstanding issue of the world, the International Maritime Organization(IMO) has been legislation a convention for prevention of air pollution from ships. By the new convention, use of air pollutants such as SOx, NOx, Freon and Halon Gas shall be restricted. In this regards, analysing these requirements of the convention is required as the convention will also be applied on restriction of discharging exhaust gases from ships by establishing a requirement of SOx and NOx discharged. The purposed of this study is as follows ; 1) Introducing of the backgrounds of legislating the convention for prevention of air pollution from ships and major contents of the convention and a countermeasures on the convention by Korea. 2) Reviewing by analyzing the influence on domestic industies concerned by restriction of SOx, NOx in exhaust gases and sulphur content of fuel oil. 3) Preparing a countermeasure on the convention properly.

A Study on the Technical Strategy on the IMO Air Pollution Prevention (IMO의 대기오염규제에 따른 기술적 대응전략에 관한 연구)

  • 김종헌
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.1-6
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    • 1996
  • As conservation of global environment has becoming a major outstanding issue of the world, the International Maritime Organization(IMO) has been legislation a convention for prevention of air pollution from ships. By the new convention, use of air pollutants such as SO/sub x/, NO/sub x/, Freon and Halon Gas shall be restricted. In this regards, analysing these requirements of the convention is required as the convention will also be applied on restriction of discharging exhaust gases from ships by establishing a requirement of SO/sub x/ and NO/sub x/ discharged. The purposed of this study is as follows ; 1) Introducing of the backgrounds of legislating the convention for prevention of air pollution from ships and major contents of the convention and a countermeasures on the convention by Korea. 2) Reviewing by analyzing the influence on domestic industies concerned by restriction of SO/sub x/, NO/sub x/ in exhaust gases and sulphur content of fuel oil. 3) Preparing a countermeasure on the convention properly.

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Studies on Alumina Cement from Alunite (I) (Synthesis of monocalcium aluminate) (명반석을 이용한 알루미나 시멘트의 제조(I) (Monocalcium Aluminate의 합성))

  • 한기성
    • Journal of the Korean Ceramic Society
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    • v.15 no.4
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    • pp.199-204
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    • 1978
  • In the present investigation, refined alumina obtained from alunite locally available was used as a aluminous source to synthesize monocalcium aluminate $(CA)_3$ the major mineral constituent of alumina cement. The influence of $SiO_2$ and $Fe_2O_3$ contents on the formation of monocalcium aluminate was studied by X-ray diffraction analysis mainly. About 0.8-1.0 of $Al_2O_3/C_3O$ mol ratio and less than 4 percent of $SiO_2$ were desirable for the effective formation of CA. The small amount of alkali and sulphur contents contained in refined alumina from alunite as the impurities were affected to form $C_4A_3S$ and $C_3S_2$, disadvantageous compounds for the alumina cement, therefore the impurities should be restricted in minimum content as possible.

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