• Title/Summary/Keyword: Sulfur oxides

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Effect of Sulfur Dioxide and Hydrogen Fluoride on Rice Plant Growth in Industrial Estate (공업단지 주변에서의 아황산가스 및 불화수소가 수도 생육에 미치는 영향)

  • Wan Cheol, Park;Kwang-Ho Kim;Ki Joon, Kim
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.1
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    • pp.17-21
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    • 1991
  • The study was performed to investigate the effects of gaseous emission of sulfur dioxide and hydrogen fluoride on the growth of rice plant under stressed field conditions. This study is specifically dealt with multiple effects of sulfur dioxide and hydrogen fluoride on various plant growth indicators such as leaf damage, weight of grain, panicles per hill, spikelets per panicle and percent fertility. It appears that there is a good correlation between ambient concentrations of sulfur oxides and sulfur contents found in leaves with an average correlation coefficient of 0.868 within a 1% significance level. A better multiple correlation was found between percent leaf damage and sulfur and fluorine contents found in leaf with a significance of 1% level. The correlation coefficient ranges from 0.807 to 0.978 with an average being 0.922. An evaluation of data observed has demonstrated that both panicles per hill and percent fertility are significantly affected by air pollutants. As expected, hydrogen fluorides have more effects than sulfur oxides. It is, however, interesting to note that spikelets per panicle has slightly been affected while no indication of effects on l000-grain weight has been observed. This may lead to a conclusion that a reduction in yield of rice under polluted field conditions may have more been caused by the diminution panicles per hill and percent fertility rather than by the diminution of spikelets per panicle and grain weight.

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An Ecological Study of Lung Cancer Mortality and Severe Air Pollution in the 1960s in an Industrial City in Japan

  • Shima, Masayuki;Yoda, Yoshiko
    • Asian Journal of Atmospheric Environment
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    • v.3 no.1
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    • pp.9-18
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    • 2009
  • This study aimed at assessing the association between exposure to severe air pollution in the past and the subsequent transition in lung cancer mortality among persons who lived in an industrial city. Vital statistics from 1983 to 2006 and the data on air pollution measurements from 1960 to 1990 in Amagasaki City, Japan, were used. Pearson correlation coefficients were calculated between the standardized mortality ratios (SMRs) for lung cancer and the air pollution levels in 6 wards of Amagasaki City. The associations between changes in air pollution levels and the annual SMRs were also evaluated in the light of a potential latency period. The levels of air pollution were extremely high in the 1960s, and they decreased since 1970. The SMRs for lung cancer in 1989-1993 among females for 6 wards were significantly associated with the amounts of both sulfur oxides and dust fall in the past for each ward. The positive associations were observed between the annual SMRs among females and the amounts of both pollutants when the lag time of 20-30 years was taken into account. These results suggest that severe air pollution in the 1960s in an industrial city affected the subsequent increase in lung cancer mortality.

Desulfurization Characteristics for Anthracite Coal Power Plant by Increasing Bituminous Coal Fuel (국내 무연탄 발전소 역청탄 사용시 탈황 특성 연구)

  • Kim, Jeong-You;Moon, Seung-Jae;Lee, Jae-Heon
    • Plant Journal
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    • v.4 no.4
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    • pp.71-77
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    • 2008
  • The sulfur oxides is one of important materials to come about air pollution at thermal plant consuming fossil fuel. The several flue gas desulfurization equipments are installed and operated to decrease sulfur oxides. The flue gas desulfurization of our thermal plant is designed for optimizing flue gas desulfurization technical development and research by Korea Electric Power Research Institute. We operate this desulfurization equipment. Now, our country imports nearly 97 percentage of the energy source and competes with the world for the energy because of the sudden rise of raw materials cost. The fuel cost decrease of power plants is the most important factor of the operation. The fuel used in the experiment is the domestic anthracite from Kangwon Taeback and the bituminous coal from Taldinsky Mine in Russia. This Study is experimental investigations of desulfurization characteristics for domestic anthracite power plant by increasing bituminous coal. We surveyed possible parameters and conducted the performance about desulfurization equipment in Yong Dong thermal power plant.

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Study of High Temperature of Inconel 740 Alloy in Air and Ar-0.2%SO2 Gas (대기 및 Ar-0.2%SO2가스에서 Inconel 740 합금의 고온부식 연구)

  • Lee, Dong Bok;Kim, Min Jung
    • Journal of the Korean institute of surface engineering
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    • v.54 no.2
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    • pp.43-52
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    • 2021
  • The Ni-based superalloy, Inconel 740, was corroded between 800 and 1100℃ for up to 100 hr in air and Ar-0.2%SO2 gas in order to study its corrosion behavior in air and sulfur/oxygen environment. It displayed relatively good corrosion resistance in both environment, because its corrosion was primarily dominated by not sulfidation but oxidation especially in Ar-0.2%SO2 gas. Such was attributed to the thermodynamic stability of oxides of alloying elements when compared to corresponding sulfides. The scales consisted primarily of Cr2O3, together with some NiAl2O4, MnCr2O4, NiCrMnO4, and rutile-TiO2. Sulfur from SO2 gas made scales prone to spallation, and thicker. It also widened the internal corrosion zone when compared to air. The corrosion resistance of IN740 was mainly indebted to the formation of protective Cr2O3-rich oxides, and suppression of the sulfide formation.

Current Status of Air Pollutants from Ships and Reduction Technologies (선박 기인 대기오염물질 현황 및 저감 기술 소개)

  • Jun-Seong Park;Seung-Ho Ham;Da-yeong Kang;Hee-Yeon Park;Jongkwan Park
    • Journal of the Society of Naval Architects of Korea
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    • v.61 no.2
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    • pp.135-142
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    • 2024
  • There is a lot of concern around the world about air pollution from ships. The majority of air pollution from ships comes from fuel combustion. The combustion process produces various air pollutants such as carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM), each of which has adverse effects on people and is a major environmental problem. To prevent this, the International Maritime Organization (IMO) has strengthened the regulation of pollutant emissions through the Convention for the Prevention of Marine Pollution. This paper discusses the types of air pollutants emitted by ships, their current status, and the latest technologies to reduce emissions of NOx and SOx.

Emission Prediction from Naval Ship Main Propulsive Diesel Engine under Steady Navigation (정속항해 시 함정 주 추진 디젤엔진의 배기가스 배출량 예측)

  • Lee, Hyung-Min;Park, Rang-Eun
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.6
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    • pp.788-793
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    • 2012
  • This study was focused on the estimations of air pollutants, such as PM(Particulate matters), SOx(Sulfur Oxides), $CO_2$(Carbon diOxides) and NOx(Nitrogen Oxides), from a diesel propulsion engine installed on a naval vessel. Legislative and regulatory actions for exhaust emissions from ships are being strengthened in international communities and national governments to protect human health and the environment. In this context, various technologies have been developed from all of the nations of the world to meet strict standards. These regulations are based on commercial ship applications and according to size, but are not suitable for military naval vessels, which have much different engine operating conditions and hull architectures. Additionally, there is no international emission control system for military ships. Emission factors have been updated for commercial ship types from work at various research institutes; however, it is difficult to develop emission factors for military vessels because of their characteristics. In this paper, exhaust emissions from diesel engines installed on naval vessels under steady navigation condition were estimated with emission inventory methodology applied to ocean going vessels using fuel-based methods and fuel sulfur content analysis.

Evaluation of Air Pollutant Adsorption Performance of Potassium and Calcium Ion-Exchanged Zeolite (칼륨 및 칼슘 이온으로 치환된 제올라이트의 대기오염물질 흡착 성능 평가)

  • Ye Hwan Lee;Sung Su Kim
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.313-317
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    • 2023
  • In this study, the physicochemical characterization and adsorption performance of air pollutants (VOCs, SO2, and CO2) were evaluated for the recycling of zeolite used in the ion exchange process. The surface characteristics of the zeolite used were confirmed through Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD) analysis, and the composition and specific surface area were measured through X-Ray Fluorescence (XRF) and Brunauer-Emmett-Teller (BET). There was no change in the surface properties of the used zeolite, but the content of potassium and calcium increased and the specific surface area decreased. The toluene, sulfur oxides, and carbon dioxide adsorption performance of the used zeolite was evaluated, and it was confirmed that the performance was improved compared to the fresh zeolite. In particular, for toluene and sulfur oxides, the adsorption amount increased by 2.6 times and 2.3 times, respectively, which might be due to the enhancement of the polymerization reaction and the increase of the base point, according to the composition of the used zeolite.

A Study on Public Nuisance in Seoul, Pusan and Daegu Cities Part I. Survey on Air Pollution and Noise Level (공해(公害)에 관(關)한 조사연구(調査硏究) 제일편(第一編) : 서울, 부산(釜山), 대구(大邱) 지역(地域)의 대기오염(大氣汚染) 및 소음(騷音)에 관(關)한 비교조사(比較調査) 연구(硏究))

  • Cha, Chul-Hwan;Shin, Young-Soo;Lee, Young-Il;Cho, Kwang-Soo;Choo, Chong-Yoo;Kim, Kyo-Sung;Choi, Dug-Il
    • Journal of Preventive Medicine and Public Health
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    • v.4 no.1
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    • pp.41-64
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    • 1971
  • During the period from July 1st to the end of November 1970, a survey on air pollution and noise level was made in Seoul, Pusan and Taegu, the three largest cities in Korea. Each city was divided into 4-6 areas; the industrial area, the semi-industrial area, the commercial area, the residential area, the park area and the downtown area. Thirty eight sites were selected from each area. A. Method of Measurement : Dustfall was measured by the Deposit Gauge Method, sulfur oxides by $PbO_2$ cylinder method, suspended particles by the Digital Dust Indicator, Sulfur dioxide ($SO_2$) and Carbon Monoxide (CO) by the MSA & Kitakawa Detector and the noise levels by Rion Sound Survey meter. B. Results: 1. The mean value of dustfall in 3 cities was $30.42ton/km^2/month$, ranging from 8.69 to 95.44. 2. The mean values of dustfall by city were $33.17ton/km^2/month$ in Seoul, 32.11 in Pusan and 25.97 in Taegu. 3. The mean values of dustfall showed a trend of decreasing order of semi-industrial area, downtown area, industrial area, commercial area, residential area, and park area. 4. The mean value of dustfall in Seoul by area were $52.32ton/km^2/month$ in downtown, 50.54 in semi-industrial area, 40.37 in industrial area, 24,19 in commercial area, 16.25 in park area and 15.39 in residential area in order of concentration. 5. The mean values of dustfall in Pusan by area were $48.27ton/km^2/month$ in semi-industrial area, 36.68 in industrial area 25.31 in commercial area, and 18.19 in residential area. 6. The mean values of dustfall in Taegu by area were $36.46ton/km^2/month$ in downtown area, 33.52 in industrial area, 20.37 in commercial area and 13.55 in residential area. 7. The mean values of sulfur oxides in 3 cities were $1.52mg\;SO_3/day/100cm^2\;PbO_2$, ranging from 0.32 to 4.72. 8. The mean values of sulfur oxides by city were $1.89mg\;SO_3/day/100cm^2\;PbO_2$ in Pusan, 1.64 in Seoul and 1.21 in Taegu. 9. The mean values of sulfur oxides by area in 3 cities were $2.16mg\;SO_3/day/100cm^2\;PbO_2$ in industrial area, 1.69 in semi-industrial area, 1.50 in commercial area, 1.48 in downtown area, 1.32 in residential area and 0.94 in the park area, respectively. 10. The monthly mean values of sulfur oxides contents showed a steady increase from July reaching a peak in November. 11. The mean values of suspended particles was $2.89mg/m^3$, ranging from 1.15 to 5.27. 12. The mean values of suspended particles by city were $3.14mg/m^3$ in Seoul, 2.79 in Taegu and 2.25 in Pusan. 13. The mean values of noise level in 3 cities was 71.3 phon, ranging from 49 to 99 phon. 14. The mean values of noise level by city were 73 phon in Seoul, 72 in Pusan, and 69 in Taegu in that order. 15. The mean values of noise level by area in 3 cities showed a decrease in the order of the downtown area, commercial area, industrial area and semi-industrial area, park area and residential area. 16. The comparison of the noise levels by area in 3 cities indicated that the highest level was detected in the downtown area in Seoul and Taegu and in the industrial area in Pusan. 17. The daily average concentration of sulfur dioxides ($SO_2$) in 3 cities was 0.081 ppm, ranging from 0.004 to 0.196. 18. The daily average concentrations of sulfur dioxides by city were 0.092 ppm in Seoul, 0.089 in Pusan and 0.062 in Taegu in that order. 19. The weekly average concentration of carbon monoxides(CO) was 27.59 ppm. 20. The daily average concentrations of carbon monoxides by city were 33.37 ppm. in Seoul, 25.76 in Pusan and 23.65 in Taegu in that order. 21. The concentration of $SO_2$ and CO reaches a peak from 6 p. m. to 8 p. m. 22. About 3 times probably the daily average concentration of CO could be detected in the downtown area probably due to heavy traffic emission in comparison with that in the industial area. 23. As for daily variation of the concentration of $SO_2$ and CO it was found that the concentration maintains relatively higher value during weekdays in the industrial area and on the first part of the week in the downtown area.

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Sulfide treatment of HgCdTe substrate for improving the interfacial characteristics of ZnS/HgCdTe heterostructure (HgCdTe 기판의 황화 처리에 따른 보호막 특성 향상)

  • Kim, Jin-Sang;Yoon, Seok-Jin;Kang, Chong-Yoon;Suh, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.973-976
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    • 2004
  • The results of numerous studies in III-V semiconductors show that sulfur treatment improves the electrical parameters of III-V compound devices. In this article, we examine the effects of sulfidation of HgCdTe surface on the interfacial characteristics of metal-ZnS-HgCdTe structures. Different from sulfidation in III-V material, S can not be act as an impurity because II-S compounds (ZnS, CdS) generally used as passivant for HgCdTe. Our studies of sulfur-treatment on HgCdTe surface show that sulfur agent forms the S- S, II-S bonds at the surface layer. These bonds are very effective to improve the electrical properties of ZnS layer on HgCdTe by reducing the possibility of native oxides formation. After the sulfidation process, MIS capacitors of HgCdTe show great improvement in electrical properties, such as low density of fixed charge and reduced hystereisis width.

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Effects of Sulfur Substitution on Chemical Bonding Nature and Electrochemical Performance of Layered LiMn0.9Cr0.1O2-xSx

  • Lim, Seung-Tae;Park, Dae-Hoon;Lee, Sun-Hee;Hwang, Seong-Ju;Yoon, Young-Soo;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1310-1314
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    • 2006
  • Sulfur-substituted $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$ $(0\;\leq\;x\;\leq\;0.1)$ layered oxides have been prepared by solid state reaction under inert atmosphere. From powder X-ray diffraction analyses, all the present lithium manganates were found to be crystallized with monoclinic-layered structure. Electrochemical measurements clearly demonstrated that, in comparison with the pristine $LiMn_{0.9}Cr_{0.1}O_2$, the sulfur-substituted derivatives exhibit smaller discharge capacities for the entire cycle range but the recovery of discharge capacity after the initial several cycles becomes faster upon sulfur substitution. The effect of the sulfur substitution on the chemical bonding nature of $LiMn_{0.9}Cr_{0.1}O_{2-x}S_x$has been investigated using X-ray absorption spectroscopic (XAS) analyses at Mn and Cr K-edges. According to Mn K-edge XAS results, the trivalent oxidation state of manganese ion remains unchanged before and after the substitution whereas the local structure around manganese ions becomes more distorted with increasing the substitution rate of sulfur. On the other hand, the replacement of oxygen with sulfur has negligible influence on the local atomic arrangement around chromium ions, which is surely due to the high octahedral stabilization energy of $Cr^{+III} $ ions. Based on the present experimental findings, we have suggested that the decrease of discharge capacity upon sulfur substitution is ascribable to the enhanced structural distortion of $MnO_6$ octahedra and/or to the formation of covalent Li-S bonds, and the accompanying improvement of cyclability would be related to the depression of Mn migration and/or to the pillaring effect of larger sulfur anion.