• 제목/요약/키워드: Sulfur oxides

검색결과 124건 처리시간 0.027초

인도네시아 서부자바 땅긍(Tanggueng)지역 열수광상의 지질, 유체포유물 및 황동위원소 연구 (Geologic, Fluid Inclusion, and Sulfur Isotopic Studies of Hydrothermal Deposit in the Tanggueng District, West Java, Indonesia)

  • Jae-Ho Lee;In-Joon Kim
    • 자원환경지질
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    • 제36권5호
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    • pp.321-328
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    • 2003
  • 인도네시아 반둥시(Bandung)의 남서부에 위치하는 땅긍(Tanggueng)지역의 금 및 비철금속(base-metal)의 광화작용은 Jampang Formation(올리고신-마이오신)의 결정질 및 암편질 응회암의 열극을 충진한 천열수성 맥상광체로 Celak, Cilangkap, Cigodobras 및 Pasirbedil 등의 주요 4개 석영맥으로 구성된다. 주요 광석광물로는 황철석, 황동석, 섬아연석, 방연석 및 반동석 등이 산출된다. 광화작용과 관련된 열수변질작용은 규화작용이 지배적이며, 견운모화(phyllic), 점토화(argillic) 및 산점상의 황철석을 포함하는 프로필리틱화작용(Propylitic)이 관찰된다. 관찰되는 맥석광물은 스멕타이트-일라이트의 혼합층광물, 녹니석, 견운모 및 카올리나이트 등이다. 광석광물의 침전은 0.0∼8.3 wt.%의 상당염농도를 갖는 광화유체로부터 약 34$0^{\circ}C$에서 약 19$0^{\circ}C$에 걸쳐 진행되었다. 상대적인 고염농도의 유체는 (1)기상 유체포유물의 존재로부터 확인된 비등현상과 (2)황동위원소연구 결과로부터 열수 유체내 마그마 유체의 혼합으로 기인된 것으로 사료된다. 광화작용시의 압력은 약 120∼200 bar로 추정되며, 이는 열수계가 정암압에서 정수압 환경으로 전이되었음을 지시하여 주고 광화심도가 약 750∼1,200 m에 해당됨을 나타낸다. 유체포유물의 균질화온도와 공생관계로부터 추정된 온도를 적용하여 계산된 열수 유체내 $H_2S$${\gamma}^{34}$값은 -0.2∼l.8$\textperthousand$로서, 이는 광화유체내 황의 기원이 마그마임을 지시한다.

저온 디젤 연소에서 발생하는 탄화수소 종 분석 (Hydrocarbon Speciation in Low Temperature Diesel Combustion)

  • 한만배
    • 대한기계학회논문집B
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    • 제34권4호
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    • pp.417-422
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    • 2010
  • 1.7L 커먼 레일 직접 연료분사 디젤엔진과 초저유황 스웨덴 디젤 연료를 이용하여 연료분사시기 8.5CA BTDC~0.5CA BTDC 와 배기가스 재순환률 37%, 43%, 48% 영역에서 실험을 수행하였다. 각각의 배기가스 재순환률에 대하여 연료분사시기가 지각됨에 따라 매연과 질소산화물이 동시에 저감되나 탄화수소와 일산화탄소는 증가하는 저온 디젤 연소영역에 있음을 확인하였다. 탄화수소를 가스크로마토그래프와 불꽃 이온 검출기를 사용하여 종 분석을 수행하였으며, 연료분사시기가 지각될수록, 그리고 배기가스 재순환률이 증가할수록 Partially burned HC, 알켄의 비율이 증가하였다. Partially burned HC 중에서 에텐이, 그리고 Unburned HC 중에서 노말 운데케인이 가장 많이 배출되었다. 이 두 개의 탄화수소 종은 촉매 연구에 사용되는 벤치 플로우리액터 시험에서 대표적인 탄화수소 종으로 사용할 수 있다.

동원광산의 금-은 광화작용 (Gold and Silver Mineralization in the Dongweon Mine)

  • 박희인;박영록
    • 자원환경지질
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    • 제23권2호
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    • pp.183-199
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    • 1990
  • Ore deposits of Dongwon mine are composed of numerous gold and silver veins emplaced in sedimentary rocks of Cambrian Choseon Supergroup and granitoids of Cretaceous age. Ore veins of the mine can be divided into gold and silver veins on the base of vein structure, mineral assemblage and vein trends. Mutual relationships between gold and silver veins are uncertain. Gold veins are simple veins which are composed of base-metal sulfides, and electrum with quartz and ankerite. On the other hand, silver veins are complex veins which reveal three distinct stages of mineral deposition based on vein structure; stage I, deposition of small amounts of oxides and pyrite with quartz; stage II, deposition of base-metal sulfides, small amounts of Ag-bearing minerals, calcite and quartz; stage III, deposition of base metal sulfides, electrum, Ag-sulfosalts, native silver, carbonates and quartz. Homogenization temperature and salinity of fluid inclusion from quartz of gold vein are as follows; $229^{\circ}$ to $283^{\circ}C$, 4.7 to 6.4 wt.% equivalent NaCI. The ore mineralogy suggests that temperature(T) and sulfur fugacity($fs_2$) of the formation of the gold vein and stage III of silver vein are estimated as T ; $294^{\circ}$ to $318^{\circ}C$, $fs_2\;10^{-9.4}$ to $10^{-10.1}$ atm. and T; $240^{\circ}$ to $279^{\circ}C$, $fs_2;10^{-11.1}$ to $10^{-17.3}$ atm. respectively. Pressure condition during gold vein formation estimated from data of ore mineralogy and fluid inclusion range 500 to 750 bar.

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MBE growth and magnetic properties of epitaxial FeMn2O4 film on MgO(100)

  • Duong, Van Thiet;Nguyen, Thi Minh Hai;Nguyen, Anh Phuong;Dang, Duc Dung;Duong, Anh Tuan;Nguyen, Van Quang;Cho, Sunglae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.318.2-318.2
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    • 2016
  • FeM2X4 spinel structures, where M is a transition metal and X is oxygen or sulfur, are candidate materials for spin filters, one of the key devices in spintronics. Both the Fe and M ions can occupy tetrahedral and octahedral sites; therefore, these types of compounds can display various physical and chemical properties [1]. On the other hand, the electronic and magnetic properties of these spinel structures could be modified via the control of cation distribution [2, 3]. Among the spinel oxides, iron manganese oxide is one of promising materials for applications. FeMn2O4 shows inverse spinel structure above 390 K and ferrimagnetic properties below the temperature [4]. In this work, we report on the structural and magnetic properties of epitaxial FeMn2O4 thin film on MgO(100) substrate. The reflection high energy electron diffraction (RHEED) and X-ray diffraction (XRD) results indicated that films were epitaxially grown on MgO(100) without the impurity phases. The valance states of Fe and Mn in the FeMn2O4 film were carried out using x-ray photoelectron spectrometer (XPS). The magnetic properties were measured by vibrating sample magnetometer (VSM), indicating that the samples are ferromagnetic at room temperature. The structural detail and origin of magnetic ordering in FeMn2O4 will be discussed.

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황토를 지지체로 사용한 중온건식 아연계 탈황제의 반응특성 연구 (A Study on the Reactivity of Zinc-based Sorbents Using Yellow Earth as Support at Middle Temperatures)

  • 박노국;정용화;이종대;류시옥;이태진
    • 에너지공학
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    • 제12권4호
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    • pp.302-308
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    • 2003
  • 본 연구에서는 황토를 지지체로 사용한 고온연료가스 정제용 아연계 탈황제의 성능시험을 수행하였다. 산화아연과 황토를 75:25의 비율로 혼합하여 탈황제를 제조하였고 황화/재생 반응속도, 황수용능력, 내마모성을 조사하였다. 탈황 및 재생반응실험은 중온(황화/재생 : 48$0^{\circ}C$/58$0^{\circ}C$)에서 수행되었다. 황토를 지지체로 사용한 아연계 탈황제는 장기사이클실험중에 나타나는 급속한 비활성화가 억제되었으며 반응속도, 황수용능력, 내구성 그리고 내마모성이 개선되었다. 황수용능력은 약 19gS/100g sorbent정도로 10 cycle 까지 유지되었으며, 내마모도는 AI=19.1%정도였다. 아연계 탈황제의 성능개선은 황토에 함유된 금속산 화물(Fe$_2$O$_3$, $Na_2$O, MnO$_2$)의 영향으로 판단된다. 이들 결과로부터 황토를 지지체로 사용하여 중온건식 아연계 탈황제의 특성을 개선할 수 있음을 확인하였다.

서울시 대기중 오존의 오염도와 그 영향인자 분석 (An Analysis of Influencing Factors on Ozone Concentration in the Ambient Air in Seoul)

  • 정용;장재연;권숙표
    • 한국대기환경학회지
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    • 제2권1호
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    • pp.73-79
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    • 1986
  • This study is carried out to determine the concentration of the ozone and the factors affecting the variation of ozone concentration in the ambient air in Seoul. The one-hour average concentration of ozone $(O_3)$, sulfur dioxide $(SO_2)$, nitrogen oxides (NO and $NO_2$), suspended particulate (TSP), carbon monoxide (CO) and non-methane hydrocarbon (NMHC) at 5 sites in Seoul measured from September to October in 1983 and 1984 were analysed statistically along with meteorological data for the same period. The results were as follows; 1. The average concentrations of ozone at 5 sites during the period ranged from 3.3 to 9.1 ppb, they were below 20 ppb of the ambient air quality standard of Korea. 2. The maximum hourly concentration of ozone occurred between 2 and 3 p.m. in a day and concentration at night were very low but higher concentrations were observed at around 4 a.m. 3. The concentration ratio between NO and $NO_2$ in Seoul was relatively lower than that for the cities of foreign countries reported so far. 4. The ozone concentration has negative correlationships with the concentration of other primary pollutants$(SO_2, NO, NO_2, CO and NMHC)$ in simple regression analyses. 5. The ozone concentration was positively correlated to wind speed, temperature and insolation intensity but negatively correlated to relative humidity. 6. Stepwise multiple regression analysis of the ozone concentration to the pollutants and meteorological factors indicate that insolation intensity and $[NO_2]/[NO]$ were the primary influencing factors. 7. The three factors of insolation intensity, $[NO_2]/[NO] and NO_2$ concentration had a significant combined effect on the ozone concentration $(r^2 = 0.47-0.57)$.

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고분자전해질형 연료전지 발전시스템의 안전운전을 위한 고성능 전력변환기에 관한 연구 (A Study on High Efficiency Power Conditioning System for Safety Operation of PEMFC_type Fuel Cell Generation System)

  • 곽동걸
    • 마이크로전자및패키징학회지
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    • 제13권1호통권38호
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    • pp.57-61
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    • 2006
  • 연료전지는 연료(수소)의 화학적 반응에 의해 축적된 화학에너지를 전기에너지로 변환하여 직류 전기를 발생시키는 에너지원이다. 연료전지는 질소나 유황산화물 등의 유해한 물질을 방출하지 않으며 기계적 동력부가 없고 거의 무소음으로 운전되는 이점을 가진다. 수소연료에 의한 연료전지는 그들의 부산물로써 열과 물을 방출한다. 연료전지를 이용한 응용분야의 확대로 인해 화석연료나 수입 석유의 의존도를 현저히 감소시킬 수 있다. 본 논문에서는 이러한 연료전지 (PEMFC, Proton Exchange Membrane Fuel Cell)의 출력을 치대한 활용하고 발전시스템의 안전운전을 위한 전력변환기(PCS, Power Conditioning System)에 대해 연구하였다. 본 논문에서는 고효율로 운전하는 새로운 전력변환 회로토폴로지를 설계하고, 발전시스템에 적용하여 각종 실험을 통하여 그 타당성을 입증하였다. 그 결과 연료전지 발전시스템은 고성능으로 동작되는 전력변환기에 의해 발전시스템의 효율과 성능을 향상시키게 된다.

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수도권 대기오염물질 배출권거래제에 대한 고찰 및 총량제 확대 시행을 위한 제언 (Study of the cap-and-trade system against the air pollutants in the Seoul Metropolitan Area and suggestion for its enforcement throughout South Korea)

  • 박민하;김용표
    • 한국입자에어로졸학회지
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    • 제15권4호
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    • pp.159-171
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    • 2019
  • The cap-and-trade system against the air pollutants in the Seoul Metropolitan Area (SMA), Korea has been implemented since 2008 and will be implemented other areas in Korea on 2020. In this study, to identify the outcome and effectiveness of the cap-and-trade system in the SMA, (1) the rate of change for NOx and SOx emissions, (2) differences between the real emission and allocated amount, and (3) the status of trading are reviewed. It was found that the NOx and SOx emissions from the sources under the cap-and-trade system decreased in the SMA but the reduction was mainly due to the reduction of fuel usage not related to the system. It was found that the average percentage of annual emission in the SMA to the allocated amount between 2008 and 2018 was 66.9% for NOx and 69.3% for SOx, respectively. It suggests that there was over allocation of the emission amounts. The average trading prices in the SMA were 0.193 $/kg for NOx and 0.128 $/kg for SOx, far lower than those in RECLAIM, 131.942 $/kg and 81.677 $/kg, respectively. It was suggested that (1) the cap system for NOx and SOx emissions should be implemented only for the area with high emission ratio from large point sources, (2) the trade system is not suitable for the effective implementation of the cap system, and (3) Korean government should not allow over allocation in order to ensure sound market function without delaying the introduction of technology.

9% Nickel강이 적용된 Type-B LNG 연료탱크 선상가열의 물성 변화에 관한 연구 (A Study on the Variation of Physical Properties of Line-heated for Type-B LNG Fuel Tank with 9% Nickel Steel Plate)

  • 최경신;이지한;홍지웅;정원지
    • 한국기계가공학회지
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    • 제19권7호
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    • pp.89-97
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    • 2020
  • Container vessels continue to grow in size, led by global shipowner. Large ships can be loaded more cargo at a time, reducing the cost of transportation per teu. this eventually leads to economies of sale, in which the production cost per unit decreases with increasing output. in accordance with the 70th Convention of the Marine Environment Protection Committee of the International Maritime Organization, as of January 1, 2020, MARPOL Annex VI Regulation 14.1.3 will be effective. All vessels must be meet these criteria to reduce Sox emissions and reduce NOx emissions by reducing the content of manned sulfur oxides from 3.5% to less than 0.5%, otherwise IACS Member States Entry to the port is denied. in order to do that need to LNG storage tank. in this study characteristic of the material after line heating (600℃,700℃,800℃,900℃) of 9% Ni steel used in the manufacture of LNG fuel tank of ship were verified using by mechanical test. In the heating method by line heating. The initial properties of steel are changed by variables such as temperature, time, speed. The experimental data of line heating presented in this paper confirmed that the initial change of 9% Ni steel could be minimized.

일부지역의 실내공기오염도와 건강에 미치는 영향에 관한 연구 (A Study on the Indoor Air Pollution Level and Its Health Significance in Working and Living Spaces)

  • 신동천;이효민;김종만;정용
    • 한국대기환경학회지
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    • 제6권1호
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    • pp.73-84
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    • 1990
  • The study was carried out to investigate the extent of indoor air pollution in living rooms of apartment houses(residential area) and offices(traffic area A : no smoking space, B : smoking space) in Seoul and to determine the health significance of indoor air pollution. Indoor and outdoor concentrations of major air pollutants were observed simultaneously from February 13 to 17, and July 24 to 28, 1988. The concentrations of carbon monoxide(CO), nitrogen oxides(NOx), sulfur dioxide($SO_2$), carbon dioxide($CO_2$) and total suspended particulate(TSP) in living room and offices were measured and the results were summarized as follows: 1. Both in summer and in winter, the indoor concentrations of CO, $CO_2$, and TSP in offices were higher than the outdoor concentrations, on the other hand, $SO_2$ was higher in the outdoors and NOx was lower than the outdoor concentration only in office A where smoking is not permitted. 2. The indoor and outdoor pollution of offices in winter was significantly higher than that in summer, and the concentrations of CO, NOx and $SO_2$ in indoor and outdoor air in living room in winter were also higher than those in summer. These results suggest that indoor levels of air pollutants are affected by smoking and winter heating systems.

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