• Title/Summary/Keyword: Sulfur dioxide effect

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The Numerical Study on Effect of the Droplet Sizes on Internal Mass Transfer in the Spray Type Scrubber (분무형 스크러버에 내에서 액적크기에 따른 물질전달에 관한 전산해석적 연구)

  • Lee, Chanhyun;Chang, Hyuksang
    • Clean Technology
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    • v.25 no.1
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    • pp.19-32
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    • 2019
  • As regional air pollution gets worse by the sulfur oxides emitted from various types of vessels passing through the many countries, the International Maritime Organization establishes the emission control areas and regulates sulfur dioxide in those areas. In order to satisfy these regional regulations, the fuel selection method and the exhaust gas post-treatment device are applied to the ships. Due to the economic reasons, the post-treatment method of exhaust gas for reducing the amount of sulfur oxides discharged is mainly preferred. The scrubber which is dominantly used in the ships are the spray type system where the sprayed liquid drops used for capturing the soluble sulfur dioxides in the exhaust gas. The performance of the spray type system depends on the size distribution of the sprayed droplets. In order to evaluate this performance, we designed counterflow type scrubber and cyclone scrubber and evaluated the desulfurization efficiency and the amount of droplet evaporation according to the size of each droplet by using computational fluid dynamics. The Eulerian-Eulerian analysis method was used because the scrubber had a gas-liquid two-phase flow inside the scrubber. When the diameter of the droplet was $100{\mu}m$, $300{\mu}m$, $500{\mu}m$ and $700{\mu}m$. As a result, both of scrubbers showed high desulfurization efficiency and low evaporation amount at $500{\mu}m$ and $700{\mu}m$.

A Experimental Study on Nitrous Oxide Formation in Direct Injection Diesel Engine (직접분사식 디젤엔진에서 아산화질소의 생성에 관한 실험적 연구)

  • Yoo, Dong-Hoon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.2
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    • pp.188-193
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    • 2015
  • It has been generally recognized that $N_2O$(Nitrous Oxide) emission from marine diesel engines has a close correlation with $SO_2$(Sulfur Dioxide) emission, and diversity of fuel elements using ships affects characteristics of the $N_2O$ emission. According to recent reports, in case of existence of an enough large NO(Nitric Oxide) generated as fuel combustion, effect of the $SO_2$ emission in exhaust gas on the $N_2O$ formation is more vast than effect of the NO. Therefore, $N_2O$ formation due to the $SO_2$ element operates on a important factor in EGR(Exhaust Gas Recirculation) systems for NOx reduction. An aim of this experimental study is to investigate that intake gas of the diesel engine with increasing of $SO_2$ flow rate affects $N_2O$ emission in exhaust gas. A test engine using this experiment was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition was set up at a 75% load. A standard $SO_2$ gas with 0.499%($m^3/m^3$) was used for changing of $SO_2$ concentration in intake gas. In conclusion, the diesel fuel included out sulfur elements did mot emit the $SO_2$ emission, and the $SO_2$ emission in exhaust gas according as increment of the $SO_2$ standard gas had almost the same ratio compared with $SO_2$ rate in mixture inlet gas. Furthermore, the $N_2O$ element in exhaust gas was formed as $SO_2$ mixture in intake gas because increment of $SO_2$ flow rate in intake gas increased $N_2O$ emission. Hence, diesel fuels included sulfur compounds were combined into $SO_2$ in combustion, and $N_2O$ in exhaust gas should be generated to react with NO and $SO_2$ which exist in a combustion chamber.

Reduction Effect of Airborne Pollutants in Pig Building by Air Cleaner Operated with Plasma Ion (플라즈마 이온 방식의 공기정화기를 이용한 돈사내 공기오염물질 저감 효과)

  • Kim, Yoon-Shin;Kim, Ki-Youn;Cho, Man-Su;Ko, Moon-Suk;Ko, Han-Jong;Jung, Jin-Won;Oh, Mi-Seok;Youn, Baek;Kim, Jung-Ho
    • Journal of Environmental Health Sciences
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    • v.36 no.4
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    • pp.306-312
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    • 2010
  • This field study was performed to evaluate the efficiency of a plasma ion-operated air cleaner in temporal reduction of airborne pollutants emitted from a pig housing facility. In the case of gaseous pollutants, the plasma ion air cleaner was not effective in reducing levels of ammonia, hydrogen sulfide, nitrogen dioxide, or sulfur dioxide (p>0.05). In the case of particulate pollutants, however, the air cleaner was effective in reducing levels of particulate matter ($PM_{2.5}$ and $PM_1$) by 79(${\pm}6.1$) and 78(${\pm}3.0$)%, respectively. Unlike the case of these fine particle fractions, the reduction of total suspended particles (TSP) and $PM_{10}$ following treatment was almost negligible. In the case of biological pollutants, the mean reduction efficiencies for airborne bacteria and fungi were relatively low at 22(${\pm}6.6$) and 25(${\pm}8.7$)%, respectively. Taken together, these results indicate that in terms of air pollutants released from this pig housing facility, the plasma ion air cleaner was primarily effective in reducing levels of $PM_{2.5}$ and $PM_1$.

Varietal Responses of Ten Soybean(Glycine max L.) to Sulfur Dioxide Tolerance : A Comparison of Foliar Injuries and Yields in Relation to Physiological Properties of Leaves. (아황산가스에 대한 주요 콩 품종간의 내성 비교)

  • Park, Ki-Sun;Ku, Ja-Hyeong
    • Korean Journal of Environmental Agriculture
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    • v.15 no.4
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    • pp.455-463
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    • 1996
  • Studies were carried out to determine the effect of sulfur dioxide on leaf injury and yield of ten soybean cultivars. Plants were fumigated with 2.0 ppm of $SO_2$ for 4 or 8 h in a closed-top field chamber. In the comparison of foliar injury, Paldalkong and Eunhakong were more susceptible to $SO_2$ than Bogwangkong, Jangsukong, and Jangkeungkong. Correlations between chlorophyll contents, peroxidase activity, and stomatal resistance of leaves and foliar susceptibility were insignificant. However, significant correlations $(r=-0.611^{\ast})$ were found between superoxide dismutase activity and foliar injury rates. Dry weight, number of pods and total grains were significantly reduced by $SO_2$ fumigation but plant height, number of nods and weight of 100 grains were not affected. Yield reduction rates were higher in Eunhakong and Paldalkong than in Bogwangkong and Jangkeungkong. A liniar relationship was found between foliar injury rate and the percent crop loss with a significant coefficient of b=-1.17 in the susceptible cultivar of Paldalkong, but Bogwangkong, insusceptible cultivar, showed lower value of -0.165.

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The Study on the Migration of Sulfite in Commercial Wooden Chopsticks (국내 유통 나무젓가락 중 이산화황 이행량에 관한 연구)

  • Park, Na-Young;Yun, Hae-Jung;Jeon, Dae-Hoon;Choi, Hyun-Cheol;Eom, Mi-Ok;Kim, Hyung-Il;Sung, Jun-Hyun;Choi, Hyun-Rock;Lee, Young-Ja
    • Journal of Food Hygiene and Safety
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    • v.23 no.3
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    • pp.218-221
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    • 2008
  • The levels of sulfites in wooden chopsticks were analyzed using two different methods, distillation-alkali titration and ion chromatography. According to the two methods, Sulfur dioxide($SO_2$) was validated by 0.6 and 0.2 ${\mu}ml$ of limit of detection(LOD), 1.8 and 0.5 ${\mu}ml$ of limit of quantification, (LOQ) and a $R^2>0.998$ for linearity, respectively. The recoveries of $SO_2$ from food simulants spiked ar levels of 100 ppm were 70.2-100.2%. 158 samples of wooden chopsticks were monitored the migrated amounts of sulfites. Sulfites were detected in 30 samples in ranged of 0.6 to 15.5 ppm. Maximum migration level, 15.5 ppm of sulfites was considered giving no harmful effect to human since it was reached 5.5% of estimated SML.

Effects of Morus alba L. and Natural Products Including Morusin on In Vivo Secretion and In Vitro Production of Airway MUC5AC Mucin

  • Lee, Hyun Jae;Ryu, Jiho;Park, Su Hyun;Woo, Eun-Rhan;Kim, A Ryun;Lee, Sang Kook;Kim, Yeong Shik;Kim, Ju-Ock;Hong, Jang-Hee;Lee, Choong Jae
    • Tuberculosis and Respiratory Diseases
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    • v.77 no.2
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    • pp.65-72
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    • 2014
  • Background: It is valuable to find the potential activity of regulating the excessive mucin secretion by the compounds derived from various medicinal plants. We investigated whether aqueous extract of the root bark of Morus alba L. (AMA), kuwanon E, kuwanon G, mulberrofuran G, and morusin significantly affect the secretion and production of airway mucin using in vivo and in vitro experimental models. Methods: Effect of AMA was examined on hypersecretion of airway mucin in sulfur dioxide-induced acute bronchitis in rats. Confluent NCI-H292 cells were pretreated with ethanolic extract, kuwanon E, kuwanon G, mulberrofuran G, or morusin for 30 minutes and then stimulated with phorbol 12-myristate 13-acetate (PMA) for 24 hours. The MUC5AC mucin secretion and production were measured by enzyme-linked immunosorbent assay. Results: AMA stimulated the secretion of airway mucin in sulfur dioxide-induced bronchitis rat model; aqueous extract, ethanolic extract, kuwanon E, kuwanon G, mulberrofuran G and morusin inhibited the production of MUC5AC mucin induced by PMA from NCI-H292 cells, respectively. Conclusion: These results suggest that extract of the root bark and the natural products derived from Morus alba L. can regulate the secretion and production of airway mucin and, at least in part, explains the folk use of extract of Morus alba L. as mucoregulators in diverse inflammatory pulmonary diseases.

The Effect of Wollastonite and Manganese Dioxide on Rice Grown on a Flooded Acid Sulfate Soil (특이산성토(特異酸性土)(답(沓))에 생육(生育)한 수도(水稻)에 대(對)한 규회석(珪灰石) 및 MnO2의 효과)

  • Park, Y.D.;Kim, Y.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.3 no.1
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    • pp.23-28
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    • 1970
  • The effect of wollastonite and manganese dioxide on the growth of rice on an acid sulfate soil were investigated in pot experiment. 1. Since aluminum content in the leachate of soil was reduced with increasing the pH and these chemical changes in the leachate were more pronounced by applying wollastonite, aluminum toxicity in flooded paddy rice was overcome by applying wollastonite, or flooding. 2. Poor growth of rice with iron toxicity-like symptoms on the untreated acid sulfate soil may be caused by excess iron and sulfur. Plants applied wollastonite, however, grew normally and did not show any symptoms. Iron and sulfur contents in the plant was reduced by applying wollastonite. 3. Because of the iron content in the both leachate and plant can be lowered by applying wollastonite, iron-toxicity was averted by applying the wollastonite. 4. Application of manganese dioxide in combination with wollastonite did not counteracted iron content in the plant as compared with the wollastonite treatment. 5. The application of wollastonite increased the dry weight of straw and grain yield. Manganese dioxide with wollastonite caused the increase of number of spickelets per panicles and ripened grains as compared with wollastonite. 6. From these results it can be concluded that the major cause of the poor growth of rice on acid sulfate soil is iron toxicity and the Fe-toxicity can be reduced by application of wollastonite.

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Measurement Study at Korean, Cheju Island during March-April, 1994: (II) Characteristics of Gaseous Air Pollutants (고산에서의 1994년 3월 - 4월 측정연구: (II) 기체상 대기오염물질의 특성)

  • 김용표;김진영;박세옥;김성주;심상규;문길주;박경윤;허철구
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.1
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    • pp.91-99
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    • 1996
  • Ozone, sulfur dioxide, and nitrogen oxides were measured at Kosan, Cheju Island, Korea during the period of March 11 .sim. April 19, 1994. During the measurement period, the average SO$_{2}$ and NOx concentrations were about 0.97 ppb and 3.5 ppb, respectively. Average NO concentration was below the detection limit and thus the effect of NO during the period was negligible. The concentrations of SO$_{2}$ and Nox were lower than those at other urban area in Korea but higher than other remote areas in the world. Average $O_{3}$ concentration for the period was about 55 ppb, slightly higher than or comparable to those at remote marine areas in the world. Detailed analyses of trend of gaseous species concentrations show that the effects of local NO emission sources for NOx concentration were significant during the period, while those of local SO$_{2}$ emission sources were not high. Backward trajectory analysis results show that when SO$_{2}$ or $O_{3}$ concentration was higher than the average concentrations, the air parcels were transported from China.

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Evaluation of Insulation Performance and Structural Integrity of an IMO Type C LNG Storage Tank (IMO Type C LNG 저장 탱크의 단열성능 및 구조적 건전성 평가)

  • Park, Heewoo;Park, Jinseong;Cho, Jong-Rae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.7
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    • pp.1-7
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    • 2021
  • Restrictions on the emissions of nitrogen oxides, sulfur oxides, carbon dioxide, and particulate matter from marine engines are being tightened. Each of these emissions requires different reduction technologies, which are costly and require many pieces of equipment to meet the requirements. Liquefied natural gas (LNG) fuel has a great advantage in reducing harmful emissions emitted from ships. Therefore, the marine engine application of LNG fuel is significantly increasing in new ship buildings. Accordingly, this study analyzed the internal support structure, insulation type, and fuel supply piping system of a 35 m3 International Maritime Organization C type pressurized storage tank of an LNG-fueled ship. Analysis of the heat transfer characteristics revealed that A304L stainless steel has a lower heat flux than A553 nickel steel, but the effect is not significant. The heat flux of pearlite insulation is much lower than that of vacuum insulation. Moreover, the analysis results of the constraint method of the support ring showed no significant difference. A553 steel containing 9% nickel has a higher strength and lower coefficient of thermal expansion than A304L, making it a suitable material for cryogenic containers.

Influence of Sulfur and Fluorine Compounds on the Growth and Yield of Rice Plants;I. Growth Retardation and Yield Reduction under Various Stressed Conditions in the Field (황화물(黃化物) 및 불화물(弗化物)이 수도생육(水稻生育)과 수량(收量)에 미치는 영향(影響);I. 오염지역(汚染地域)에서의 생육장해(生育障害) 및 수량감소(收量減少))

  • Park, Wan-Cheol;Shin, Eung-Bai;Kim, Kwang-Ho
    • Korean Journal of Environmental Agriculture
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    • v.6 no.2
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    • pp.53-65
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    • 1987
  • The study was performed to investigate the effect of gaseous emissions of sulfur dioxide and hydrogen fluoride on the growth of rice plants under stressed field conditions consisting of 88 industrial plants operating with 285 smoke stacks emitting pollutants. As for the relationship between yields and yield components it is believed that the panicles per hill is the single most important component affecting the rate of yield of the rice plant. Based on the standard partial regression coefficient analysis, panicles per hill has the largest contribution to yield and the average contribution of 54%. Other components such as spikelets per panicle, percent fertility and 1000 grain weight are also contributing factors to yield, although far less so. Fluorine content in the leaf appear to have more negative effect on panicles per hill, percent fertility and subsequent overall yield than does sulfur content in the leaf. It is constantly observed and interesting to note that fluorine and sulfur content in the leaf appears to have no effect on spikelets per panicle and 1000 grain weight. Reduction in yield seems to be affected mainly by panicles per hill which are, in turn, affected more by fluorine content in the leaf as demonstrated by the standard partial coefficient analysis. Regarding the prediction sum of the square of the regression equation, the lowest value was found when nine variables were used for the analysis. The variables taken into consideration were the monthly sulfur and fluorine content in the leaf as well as the monthly percent of leaf damage during the months of June, July and August. A significant correlation is found between the actual and predicted yields by the regression equations selected as a result of a prediction sum of the square analysis.

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