• Title/Summary/Keyword: Sulfur Dioxide

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Concentration of $NO_2$ and $SO_{2}$ of Bus Terminals in Seoul (서울시 버스터미널의 이산화질소 및 아황산가스 농도)

  • 손부순;장봉기;김영규
    • Journal of environmental and Sanitary engineering
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    • v.12 no.3
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    • pp.51-59
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    • 1997
  • In this study, we researched the concentration of nitrogen dioxide($NO_{2}$) and sulfur dioxide($SO_{2}$) of indoor(waiting room) and outdoor(place of getting on the bus) at the bus terminals (Kang-Nam, Dong-Seoul and Nam-Bu) in Seoul to recognize the degree of pollution by exhaust gas of the diesel engine vehicles, and examine the factor that might affect air pollution of terminals. The concentration of $NO_{2}$ and $SO_{2}$ were measured in winter and summer, and the results of the analysis are as follows : The mean concentration of $NO_{2}$ was $57.49{\pm}21.86$ ppb and the concentration of outdoor with $64.10{\pm}27.69$ ppb was significantly higher than the indoor with $50.89{\pm}10.92$ ppb (p<0.05), and the highest with $73.54{\pm}25.54$ ppb at Kang-Nam terminal (p<0.01). The mean concentration of $NO_{2}$ was $62.80{\pm}24.74$ ppb in winter and $52.19{\pm}17.50$ ppb in summer, and had a not statistical difference. The mean concentration of $SO_{2}$ was $31.71{\pm}8.73$ ppb and the concentration of outdoor with $31.04{\pm}8.89$ ppb was similar to the indoor $32.29{\pm}8.70$ ppb, and the highest with $32.57{\pm}9.01$ ppb at Dong-Seoul terminal (p<0.05). The mean concentration of $SO_{2}$ in winter with $39.67{\pm}4.10$ ppb was significantly higher than in summer with $23.76{\pm}2.61$ ppb (p<0.01). The concentration of outdoor $NO_{2}$ at Kang-Nam terminal was 104, 84 ppb in winter and 81.20 ppb in summer, and had a statistical difference compared with the concentration of indoor $NO_{2}$ at Dong-Seoul and Nam-Bu terminals. The concentration of indoor $NO_{2}$ and $SO_{2}$ were higher than that of outdoor at Kang-Nam and Dong-Seoul terminals, but on the contrary, lower than that of outdoor at Nam-Bu terminal. The concentration of $NO_{2}$ and $SO_{2}$ at Nam-Bu terminal were lower than those at Kang-Nam and Dong-Seoul terminals. While the concentration of $SO_{2}$ show the large difference between winter and summer, that of $NO_{2}$ dose not.

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Implementation of Air Pollutant Monitoring System using UAV with Automatic Navigation Flight

  • Shin, Sang-Hoon;Park, Myeong-Chul
    • Journal of the Korea Society of Computer and Information
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    • v.27 no.8
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    • pp.77-84
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    • 2022
  • In this paper, we propose a system for monitoring air pollutants such as fine dust using an unmanned aerial vehicle capable of autonomous navigation. The existing air quality management system used a method of collecting information through a fixed sensor box or through a measurement sensor of a drone using a control device. This has disadvantages in that additional procedures for data collection and transmission must be performed in a limited space and for monitoring. In this paper, to overcome this problem, a GPS module for location information and a PMS7003 module for fine dust measurement are embedded in an unmanned aerial vehicle capable of autonomous navigation through flight information designation, and the collected information is stored in the SD module, and after the flight is completed, press the transmit button. It configures a system of one-stop structure that is stored in a remote database through a smartphone app connected via Bluetooth. In addition, an HTML5-based web monitoring page for real-time monitoring is configured and provided to interested users. The results of this study can be utilized in an environmental monitoring system through an unmanned aerial vehicle, and in the future, various pollutants measuring sensors such as sulfur dioxide and carbon dioxide will be added to develop it into a total environmental control system.

Study on the Concentration Estimation Equation of Nitrogen Dioxide using Hyperspectral Sensor (초분광센서를 활용한 이산화질소 농도 추정식에 관한 연구)

  • Jeon, Eui-Ik;Park, Jin-Woo;Lim, Seong-Ha;Kim, Dong-Woo;Yu, Jae-Jin;Son, Seung-Woo;Jeon, Hyung-Jin;Yoon, Jeong-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.19-25
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    • 2019
  • The CleanSYS(Clean SYStem) is operated to monitor air pollutants emitted from specific industrial complexes in Korea. So the industrial complexes without the system are directly monitored by the control officers. For efficient monitoring, studies using various sensors have been conducted to monitor air pollutants emitted from industrial complex. In this study, hyperspectral sensors were used to model and verify the equations for estimating the concentration of $NO_2$(nitrogen dioxide) in air pollutants emitted. For development of the equations, spectral radiance were observed for $NO_2$ at various concentrations with different SZA(Solar Zenith Angle), VZA(Viewing Zenith Angle), and RAA(Relative Azimuth Angle). From the observed spectral radiance, the calculated value of the difference between the values of the specific wavelengths was taken as an absorption depth, and the equations were developed using the relationship between the depth and the $NO_2$ concentration. The spectral radiance mixed gas of $NO_2$ and $SO_2$(sulfur dioxide) was used to verify the equations. As a result, the $R^2$(coefficient of determination) and RMSE(Root Mean Square Error) were different from 0.71~0.88 and 72~23 ppm according to the form of the equation, and $R^2$ of the exponential form was the highest among the equations. Depending on the type of the equations, the accuracy of the estimated concentration with varying concentrations is not constant. However, if the equations are advanced in the future, hyperspectral sensors can be used to monitor the $NO_2$ emitted from the industrial complex.

A Study on the Characteristics of Electro Polishing and Utility Materials for Transit High Purity Gas (청정도 가스 이송용 재료의 특성과 전해연마에 관한 연구)

  • Lee, Jong-Hyung;Park, Shin-Kyu;Yang, Seong-Hyeon
    • Journal of the Korean Society of Industry Convergence
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    • v.7 no.3
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    • pp.259-263
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    • 2004
  • In the manufacture progress of LCD or semiconductor, there are used many kinds of gas like erosion gas, dilution gas, toxic gas as a progress which used these gas there are required high puritize to increase accumulation rate of semiconductor or LCD materials work progress of semiconductor or LCD it demand many things like the material which could minimize metallic dust that could be occured by reaction between gas and transfer pipe laying material, illumination of the surface, emition of the gas, metal liquation, welding etc also demand quality geting stricted. Material-Low-sulfur-contend (0.007-0010), vacuum-arc-remelt(VAR), seamless, high-purity tubing material is recommend for enhance welding lower surface defect density All wetted stainless steel surface must be 316LSS elecrto polishinged with ${\leq}0.254{\mu}m$($10.0{\mu}in$) Ra average surface finish, $Cr/Fe{\geq}1.1$ and $Cr_2O_3$ thickness ${\geq}25{\AA}$ From the AES analytical the oxide layer thickness (23.5~36 angstroms silicon dioxide equivalent) and chromum to iron ratios is similar to those generally found on electropolished stainless steel., molybdenum and silicon contaminants ; elements characteristic of stainless steel (iron, nickel and chromium); and oxygen were found on the surface Phosphorus and nitrogen are common contaminants from the electropolish and passivation steps.

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Air Pollutant Variations Observed at Deokjeok Island in the Yellow Sea During April 1999 to June 2000 (1999년 4월부터 2000년 6월까지 황해 덕적도에서 관찰된 대기오염물질 변화 특성)

  • 김영성;이승복;김진영;배귀남;문길주;원재광;윤순창
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.4
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    • pp.347-361
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    • 2003
  • Sulfur dioxide (SO$_2$), ozone, total suspended particulates (TSP) and PM$_{2.5}$ were measured at Deokjeok Island in the Yellow Sea during April 1999 to June 2000. Although the emission amount of air pollutants is quite low in this small island of 36 km$^2$ with 1.4 thousand inhabitants, there are pollutant sources such as an oil -firing power plant and a wharf for ferryboat. The island is also influenced from the emissions from the greater Seoul area in the east and from China in the west. In order to characterize the pollutant variations due to interactions between transport and local emissions. the correlation between variations of SO$_2$ and ozone was investigated. Mass and ion concentrations of TSP and PM$_{2.5}$ were examined on selected episode days of positive and negative correlations between the two gaseous species in spring and winter. The effects of transport were pronounced on the days of positive correlation in spring with higher concentrations of ozone and PM$_{2.5}$. TSP concentrations were also high on these days because of high wind speeds. On the days of negative correlation in spring, frequent fog associated with low wind speeds facilitated SO$_2$ oxidation and increased sulfate accompanied with decrease in nitrate in PM$_{2.5}$ and chloride in TSP. This latter phenomena was noticeable since it showed that chemical composition of fine particles could be significantly altered not only during the transport but also by local environment.ronment.

High Temperature Oxidation and Sulfidation of Ni-15at.%W Coatings

  • Kim Chanwou;You Teayoul;Shapovalov Yuriy;Ko Jaehwang;Lee Dongbok;Lee Kyuhwan;Chang Doyon;Kim Dongsoo;Kwon Sikchol
    • Journal of Surface Science and Engineering
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    • v.38 no.1
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    • pp.1-6
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    • 2005
  • Ni-15at.% W coatings with film thicknesses of 20-40 ㎛ were electroplated on a steel substrate, and their oxidation behavior was investigated at 700 and 800℃ in air. For comparison, a pure Ni coating and a bulk Ni were also oxidized. The Ni-15at.%W coating displayed the worst oxidation resistance, due to the formation of less-protective NiO, Fe₂O₃, NiFe₂O₄ and NiWO₄. The corrosion behavior Ni-15at.%W coatings electroplated on a steel substrate was similarly investigated at 700 and 800℃ in the Ar-l%SO₂ atmosphere. For comparison, the uncoated steel substrate was also corrosion-tested in the Ar-l %SO₂ atmosphere. Severe scale spallation and the internal corrosion of the steel that occurred in the uncoated substrate were not observed in the coated specimen. However, it seemed that the Ni-15at.%W coating cannot be a potential candidate as a sulfidation-resistant coating, due to the formation of less-protective NiO, NiS, WO₃ and NiWO₄.

Identifying Regional Characteristics Faxtors Affecting the Number of Tuberculosis Death - The Comparative Analysis between Urban and Rural areas - (결핵 사망자수에 영향을 미치는 지역특성 요인 규명 - 도시 및 비도시지역 비교분석 -)

  • Yoon, Sanghoon;Park, Keunoh
    • Journal of the Society of Disaster Information
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    • v.16 no.3
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    • pp.513-525
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    • 2020
  • Purpose: The purpose of this study is to analyze the characteristics of local factors affecting number of tuberculosis death by urban and rural areas. Method: The Partial Least Square(PLS) Regression analysis was used to solve the problem of multicollinearity and number of samples. Result: As a result of analysis, The number of tuberculosis deaths in urban and rural areas is about three times as large. As a result of analysis about Regional Characteristics Factor, In general, children, elderly people, and economically vulnerable populations are more likely to be exposed to tuberculosis. In differential results, it shows that environmental factors such as ultrafine dust and sulfur dioxide have a significant impact on the number of tuberculosis deaths in urban areas and social factors such as depression experience rate in rural areas. Conclusion: The Tuberculosis prevention and management policies that reflect the characteristics of urban and rural areas are needed in the future.

An Analysis of Influencing Factors on Ozone Concentration in the Ambient Air in Seoul (서울시 대기중 오존의 오염도와 그 영향인자 분석)

  • Chung, Yong;Jang, Jae-Yeon;Kwon, Sook-Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.1
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    • pp.73-79
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    • 1986
  • This study is carried out to determine the concentration of the ozone and the factors affecting the variation of ozone concentration in the ambient air in Seoul. The one-hour average concentration of ozone $(O_3)$, sulfur dioxide $(SO_2)$, nitrogen oxides (NO and $NO_2$), suspended particulate (TSP), carbon monoxide (CO) and non-methane hydrocarbon (NMHC) at 5 sites in Seoul measured from September to October in 1983 and 1984 were analysed statistically along with meteorological data for the same period. The results were as follows; 1. The average concentrations of ozone at 5 sites during the period ranged from 3.3 to 9.1 ppb, they were below 20 ppb of the ambient air quality standard of Korea. 2. The maximum hourly concentration of ozone occurred between 2 and 3 p.m. in a day and concentration at night were very low but higher concentrations were observed at around 4 a.m. 3. The concentration ratio between NO and $NO_2$ in Seoul was relatively lower than that for the cities of foreign countries reported so far. 4. The ozone concentration has negative correlationships with the concentration of other primary pollutants$(SO_2, NO, NO_2, CO and NMHC)$ in simple regression analyses. 5. The ozone concentration was positively correlated to wind speed, temperature and insolation intensity but negatively correlated to relative humidity. 6. Stepwise multiple regression analysis of the ozone concentration to the pollutants and meteorological factors indicate that insolation intensity and $[NO_2]/[NO]$ were the primary influencing factors. 7. The three factors of insolation intensity, $[NO_2]/[NO] and NO_2$ concentration had a significant combined effect on the ozone concentration $(r^2 = 0.47-0.57)$.

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Minimization of Sulfur Dioxide Gas Emission by Process Optimization of Sulfuric Acid Plants (공정최적화에 의한 황산공장의 이산화황가스 배출 최소화)

  • Cho Byoung-Hak;Song Kwang Ho;Kim In-Won
    • Journal of the Korean Institute of Gas
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    • v.3 no.2 s.7
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    • pp.70-76
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    • 1999
  • Because of the tight pollution control of $SO_2$ emission, sulfuric acid manufacturers have been interested in the operation with the highest possible conversion efficiency. In this work, the design criteria and operating conditions of the catalytic converter were investigated for maximum conversion efficiency and minimum $SO_2$ emission by parametric analysis and process optimization for the existing acid plants. The Double Converter/Double Absorber(DC/DA) process was investigated by varying $SO_2$ compositions of feed gas, pressures and temperatures of layers of the converter and the depth of the catalyst beds. In order to evaluate the process, a computer simulator for sulfuric acid plants has been developed. The results by process optimization could be used for the converter design and operating conditions with highest conversion efficiency.

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The Effects of Varying Sampling Flow Rates on the Measurements of Total Nitrate and Sulfate in Dry Acid Deposition

  • Park, Jong-Kil;Kim, Jo-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E1
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    • pp.1-12
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    • 2002
  • One technique for determining dry acid deposition fluxes involves measurement of time - averaged ambient concentrations of dry acid deposition species using filter packs (FP) coupled with estimates of mean deposition velocities for the exposure period. A critical problem associated with filter pack data comparisons between various field sampling networks is the use of diverse sampling flow rates and duration protocols. Field experiments were conducted to evaluate the effects of varying sampling flow rates, from 1.5 to 10 standard liters per minute, on total nitrate and sulfate measurements of specific dry acid deposition species . Collocated FP samplers were used to determine sampling and analysis data reproducibility and representativeness . Ambient air samples were simultaneously collected using groups of filter packs operated at various flow rates over identical 7 day periods. The species measured were sulfur dioxide, particulate sulfate , nitric acid and particulate nitrate. Statistical results (ANOVA; alpha level 5%) showed that neither the low nor high sampling flow rates caused a significant difference in the measurements of total sulfate and adjusted total nitrate (ATN) . However, it was concluded that for high flow rate sampling measurements, total nitrate (TN) could be affected during extended sampling durations because of potential nitric acid overloading and breakthrough. Although the previous workers (Costello, 1990; Quillian, 1990) used much higher sampling flow rates (~ 17 sLpm) than employed here, it was assumed that for a high loading (> 50$\mu\textrm{g}$ HNO$_3$) of nitric acid on the Nylon filters, a significant fraction (~10%) of nitric acid could pass through the Nylon filters and be collected on the carbonate impregnated filters. It was concluded that even at the highest sampling flow rate employed (10 sLpm) at the Cary Forest site, nitric acid breakthrough was less than 10% of the total HNO$_3$ collected. However, for a heavily polluted urban airshed or with longer sampling times , higher filter loadings could result in substantial nitric acid breakthrough and HNO$_3$concentrations would be underestimated.