• Title/Summary/Keyword: Sulfide mineral

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Forecasting Methane Gas Concentration of LFG Power Plant Using Deep Learning (딥러닝 기법을 활용한 매립가스 발전소 포집공의 메탄가스 농도 예측)

  • Won, Seung-hyun;Seo, Dae-ho;Park, Dae-won
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.649-659
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    • 2018
  • In this study, after operational data for a landfill gas power plant were collected, the methane gas concentration was predicted using a deep learning method. Concentrations of methane gas, carbon dioxide, hydrogen sulfide, oxygen concentration, as well as data related to the valve opening degree, air temperature and humidity were collected from 23 pipeline bases for 88 matches from January to November 2017. After the deep learning model learned the collected data, methane gas concentration was estimated by applying other data. Our study yielded extremely accurate estimation results for all of the 23 pipeline bases.

Mineral Paragenesis and Fluid Inclusion Study of Ssangjeon Tungsten Deposits (쌍전중석광상(雙田重石鑛床)의 광물공생(鑛物共生)과 유체포유물연구(流體包有物硏究))

  • Youn, Seok Tai;Park, Hee-In
    • Economic and Environmental Geology
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    • v.15 no.4
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    • pp.221-233
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    • 1982
  • Ssangjeon tungsten ore deposits is a complex pegmatite deposits embedded along the contact between pre-Cambrian Buncheon granite gneiss and amphibolite. This pegmatite vein developed 2 km along the strike and thickness varies from 10m to 40m. Mineral constituent of the normal pegmatite are quartz, microcline, plagioclase, muscovite, biotite, tourmaline and garnet. The vein paragenesis is complicated by repeated deposition of quartz but three distinct depositional stage can be recognized. Quartz A stage is the stage of the earliest milky white quartz deposition as a rock forming mineral of normal pegmatite. Quartz B stage is the stage of gray to dark gray quartz replace earlier formed normal pegmatite minerals. Quartz C stage is the stage of latest white translucent massive quartz replace quartz A and B. Tungsten ore minerals and other sulfide minerals were precipitated during quartz B stage. Ore minerals are ferberite and scheelite. Minor amount of molybdenite, arsenopyrite, pyrrhotite, pyrite, chalcopyrite, sphalerite, galena, pentlandite, bismuthinite, native bismuth and marcasite accompanied. Fluid inclusion in quartz A and B are gaseous inclusions and liquid inclusions are contained in quartz C as a primary inclusions. Salinity of inclusions in quartz A and B ranges from 4.5 to 9.5 wt. % and from 5.1 to 6.0 wt. % equivalent NaCl respectively. Homogenization temperature of quartz A; quartz B and quartz C ranges from 415 to $465^{\circ}C$, from 397 to $441^{\circ}C$ and from 278 to $357^{\circ}C$. $CO_2$ content of the ore fluid increased at the ends of quartz B stage.

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The Study of Structural Control and Relative Photogeological Interpretation on Shiheung Mine Region (시흥군(始興郡) 서면일대(西面一帶)의 광화구제구조(鑛化規制構造)와 항공사진해석결과(航空寫眞解析結果)와의 비교연구(比較硏究))

  • Chi, Jeong Mahn;Ryuu, Byeoonghwa
    • Economic and Environmental Geology
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    • v.3 no.4
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    • pp.199-222
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    • 1970
  • One of the biggest sulfide metallic (Cu, Pb, Zn) ore deposits of South Korea is located in the area of Seo-myeon, Shiheung-gun, Gyeonggi-do. Geology of the region is mostly composed of metasediments of biotite schist, graphite schist, injection gneiss, sericite schist, limesilicate and quartzite from bottom, those are applicable to so-called Yeoncheon System of Pre-Cambrian, and granodiorite, quartz porphyry, basic dykes are outcroped in a small scope as intrusives. The origin of the ore deposit is pyrometasomatic contact deposits due to hydrothermal replacement and the ore bodies are imbedded in lower bed of limesilicate formation as impregnation and ore minerals are galena, sphalerite, marmatite, chalcopyrite, bornite, chalcocite, covellite, and the later two minerals are both hypogene and supergene. Gangue minerals are mostly skarn minerals those hornblende, diopside, epidote, hedenbergite, chlorite, garnet and quartz except primary calcite and quartz. Boundary plane (NS strike) between schists and limesilicate seemed to be primary opening of ore solution and fractures bearing $N50^{\circ}{\sim}80^{\circ}W$ are secondary structural control for localization of ore minerals and the third structural controls are both irregular gashes and schistosity in small scale. Photogeological study was carried with vertical aerial photo scaled 1: 38,000 and enlarged 1 : 10,000 under stereoscope. The study on the area convinced the fact that the geologic boundaries between rocks, limesilicates and quartzites, are traced easily by their typical topographic feature and drainage, and the main fracture patterns which derived from the result of fracture traces, that photogeologic lineament observed under stereoscope, are those bearing (1) $N20^{\circ}W$, (2) $N58^{\circ}W$, (3) $N76^{\circ}W$, (4) EW, (5) $N20^{\circ}W$, (6) $N62^{\circ}W$, (7) $N77^{\circ}W$. Among the written fractures, (5) (not schistosity, in case of fault) (6) (7) are post-mineral faults and others are pre-mineral faults and others are pre-mineral structures, and (2) (3) (6) (7) are coincided with statistical figure of 208 fractures surveyed in underground. By the result of the study, mineralized zone, are presumed to extend north and southward, total length about 4km.

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Hydrothermal Alteration around the Tofua Arc (TA) 25 Seamounts in Tonga Arc (통가열도 TA 25 해저산의 열수변질)

  • Cho, Hyen Goo;Kim, Dong-Ho;Koo, Hyo Jin;Um, In Kwon;Choi, Hunsoo
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.4
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    • pp.169-181
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    • 2014
  • Korea government has consistently investigated the development of economic mineral deposits in the Tofua volcanic arc, Tonga since 2008 for the secure of sea floor mineral resources. We studied the composition and distribution of minerals formed by hydrothermal activity around TA 25 seamounts of the Tofua volcanic arc, Lau Basin, Tonga, using X-ray diffraction analysis, scanning electron microscopy, X-ray fluorescence spectrometry, and inductively coupled plasma atomic emission spectrometry. We used 7 core samples and 9 surface sediment samples. Barite, sphalerite, and clinoclase are present in the most volcanic vent area. Gypsum, smectite, and kaolin mineral are distributed in vent A area, chalcopyrite, pyrite, smectite, and kaolin mineral are in vent B and C area, and gypsum, chalcopyrite, pyrite, and goethite are in vent D area. From the study of clay fraction, smectite and few kaolinite are detected in the most studied area except inner part of caldera, which suggest that argillic alteration are dominant in the volcanic vent areas. Various sulfide or arsenide minerals were found in the hydrothermal vent B, C, and D. The mineralogy and geochemistry suggest higher hydrothermal activities in volcanic vent B, C, and D compared to vent A and inner caldera area. Therefore higher probabilities of massive sulfide deposits may occur in hydrothermal vent B, C, and D.

Geology and Ore Deposits of Yeonhwa Mine (연화광산(蓮花鑛山)의 지질광상(地質鑛床))

  • Han, Kap Soo
    • Economic and Environmental Geology
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    • v.2 no.3
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    • pp.47-57
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    • 1969
  • The Yeonhwa Lead and Zinc Mine is located in northern part of Kyeongsang-Buk-Do, Korea, and is economically most important mine because it produces most part of the output of lead and zinc minerals in the country. Ore deposits of the mine are localized in the Pungchon Formation and several limestone seams of upper Myobong Formation in Cambrian Age. Ore solution ascended along the fractures of N-S, NE-SW or NW-SE trends and along slate and limestone boundary, and then replaced selectively limestone to make ore bodies. Skarn minerals are consisted of hedenbergite, diopside, and main sulfide mineral orebodies are composed of galena, zincblende, pyrrhotite, pyrite and a minor amounts of arsenopyrite and chalcopyrite. Metal ratio, ${\rho}_{Pb}={\frac{Pb(%)}{Pb(%)+Zn(%)}}{\times}100$, illustrates the zona I arrangements of some ore bodies. It will be inferred the flow trending of ore solution and the process reaction with adjacent country rocks. The sub-divided formations of the Pungchon limestone and Myobong slate are very useful as a criteria for detecting probable ore location. Rhodochrosite veins are good evidence for searching of ore location, especially on Pb-rich ore bodies.

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Sulfide-rich mine tailings usage for short-term support purposes: An experimental study on paste backfill barricades

  • Komurlu, Eren;Kesimal, Ayhan
    • Geomechanics and Engineering
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    • v.9 no.2
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    • pp.195-205
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    • 2015
  • Barricade failures generally occur at the early times of paste backfill when it is fresh in the stopes. The backfill strength increases and need for barricading pressure decreases as a result of the hydration reactions. In this study, paste backfill barricades of Cayeli copper mine were investigated to design cemented mineral processing plant tailings as barricade body concrete. Paste backfill in sub-level caving stopes of the mine needs to be barricaded for only four or five days. Therefore, short term strength and workability tests were applied on several cemented tailings material designs. Barricade failure mechanisms, important points of barricade designing and details of the new concrete material are explained in this work. According to the results obtained with this experimental study, the tailings were assessed to be used in concrete applied as temporary supports such as cemented paste backfill barricades.

Research on Physical Changes Based on Drying After Downpour Penetration of Floor Finishing Use Granite Stone (호우로 인한 바닥 마감용 화강석 침수 후 건조상태에 따른 물성변화에 관한 연구)

  • An, Ki-Won;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.173-174
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    • 2015
  • This research takes granite stone based floor finishing exposed to concentrated downpouring and observes the material's physical changes, adhesiveness, compressive strength under wet conditions. The results of the experiments shows that elution of sulfide mineral can occur when granite stones are exposed to downpour, but short term exposure shows little physical changes to the material. This indicates that if post maintenance is properly enacted, long term usage of granite stone materials is also possible.

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Geology and Mineralization of the Iscaycruz Pb-Zn-Cu Project, Central Peru (페루 중부 이스카이크루즈 연-아연-동 프로젝트의 지질 및 광화작용)

  • Heo, Chul-Ho;Nam, Hyeong-Tae
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.1
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    • pp.57-67
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    • 2021
  • The geology of the Iskaycruz project are mainly composed of sedimentary rocks within Cretaceous basin. The basal part is composed up of dark-gray shale, gray sandstone, and clastic rock of Oyon formation interbedded with coal measures. In the folded zone in the eastern part of the survey area, there is Chimu formation that has medium-grained massive and white quarztite. In terms of geological structure, the Iskaykruz region is located in the folded and overthrust zones of the central part of the Occidental Mountains. Ore body was formed by hydrothermal replacement process and consists of zinc, lead, silver, and copper. Stratabound-type deposits are hosted in limestone of Santa formation. It extends 12 kilometers discontinuously from northern Canaypata to southern Antapampa. Irregular iron oxide and sulfide minerals hosted in Santa and Parihuanca formations are observed. The mineralization observed on the surface consist of primary sulfides consisting of sphalerite with galena and chalcopyrite, and iron and manganese oxide produced from oxidation of primary sulfides. Skarn minerals are accompanied by tremolite, garnet, epidote and quartz.

Behavior of Oxidative Precipitation of High-Arsenic (III) Solution Utilizing Activated Carbon with Air Injection (공기와 활성탄 병용에 의한 용액 중 고농도 3가 비소의 산화-침전 거동 연구)

  • Kim, Rina;Kim, Gahee;Kim, Kwanho;You, Kwang-suk
    • Resources Recycling
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    • v.30 no.4
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    • pp.11-19
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    • 2021
  • Arsenic (As) oxidation followed by precipitation from a high-As(III)-containing leaching solution derived from a sulfidic ore was investigated in this study to remove aqueous As from the solution using activated carbon (AC) with air injection as an oxidant. To obtain the initial leaching solution, a domestic sulfidic ore was leached in a sulfuric acid solution at pH 1 and 50℃ for 95 h, and approximately 7 g/L of Fe and 3 g/L of As were leached out. To determine the effect of the oxidative reaction utilizing AC with air injection, the leaching solution was tested under the following five oxidative conditions at an initial pH of 1 and 90℃ for 72 h: air-only injection; air injection with 1, 5, and 10 w/v% of AC addition; and H2O2 addition. The tests in the presence of both air and AC revealed that the oxidation kinetics and As removal were improved by the reaction between the metallic species and the surface group formed on the AC surface. In addition, the greater the amount of AC added, the better was the reaction efficiency, removing 93-94% of As with more than 5 w/v% of AC addition. Finally, X-ray diffraction analysis confirmed that the precipitate formed from the oxidative reaction was scorodite (FeAsO4·2H2O).

Upstream Risks in Domestic Battery Raw Material Supply Chain and Countermeasures in the Mineral Resource Exploration Sector in Korea (국내 배터리원료광종 공급망 업스트림 리스크와 광물자원탐사부문에서의 대응방안)

  • Oh, Il-Hwan;Heo, Chul-Ho;Kim, Seong-Yong
    • Economic and Environmental Geology
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    • v.55 no.4
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    • pp.399-406
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    • 2022
  • In line with the megatrend of 2050 carbon neutrality, the amount of critical minerals used in clean-energy technology is expected to increase fourfold and sixfold, respectively, according to the Paris Agreement-based scenario as well as the 2050 carbon-neutrality scenario. And, in the case of Korea, in terms of the battery supply chain used for secondary batteries, the midstream that manufactures battery materials and battery cell packs shows strength, but the upstream that provides and processes raw materials is experiencing difficulties. The Korea Institute of Geoscience and Mineral Resources has established a strategy to secure lithium, nickel, and cobalt and is conducting surveys to respond to the upstream risk of these types of battery raw materials. In the case of lithium, exploration has been carried out in Uljin, Gyeongsangbuk-do since 2020, and by the end of 2021, the survey area was selected for precision exploration by synthesizing all exploration data and building a 3D model. Potential resources will be assessed in 2022. In the case of nickel, the prospective site will be selected by the end of 2022 through a preliminary survey targeting 10 nickel sulfide deposits that have been prospected in the past. In the case of cobalt, Boguk cobalt is known only in South Korea, but there is only a record that cobalt was produced as a minor constituent of hydrothermal deposit. According to the literature, a cobalt ore body was found in the contact area between serpentinite and granite, and a protocol for cobalt exploration in Korea will be established.