• Title/Summary/Keyword: Sulfate Attack

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Prediction of compressive strength of lightweight mortar exposed to sulfate attack

  • Tanyildizi, Harun
    • Computers and Concrete
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    • v.19 no.2
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    • pp.217-226
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    • 2017
  • This paper summarizes the results of experimental research, and artificial intelligence methods focused on determination of compressive strength of lightweight cement mortar with silica fume and fly ash after sulfate attack. The artificial neural network and the support vector machine were selected as artificial intelligence methods. Lightweight cement mortar mixtures containing silica fume and fly ash were prepared in this study. After specimens were cured in $20{\pm}2^{\circ}C$ waters for 28 days, the specimens were cured in different sulfate concentrations (0%, 1% $MgSO_4^{-2}$, 2% $MgSO_4^{-2}$, and 4% $MgSO_4^{-2}$ for 28, 60, 90, 120, 150, 180, 210 and 365 days. At the end of these curing periods, the compressive strengths of lightweight cement mortars were tested. The input variables for the artificial neural network and the support vector machine were selected as the amount of cement, the amount of fly ash, the amount of silica fumes, the amount of aggregates, the sulfate percentage, and the curing time. The compressive strength of the lightweight cement mortar was the output variable. The model results were compared with the experimental results. The best prediction results were obtained from the artificial neural network model with the Powell-Beale conjugate gradient backpropagation training algorithm.

X-ray CT monitoring of macro void development in mortars exposed to sulfate attack

  • Tekin, Ilker;Birgul, Recep;Aruntas, Huseyin Y.
    • Computers and Concrete
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    • v.21 no.4
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    • pp.367-376
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    • 2018
  • This study reports the results of nondestructive monitoring of macro void developments in mortars manufactured with both ordinary Portland cement and sulfate resistant cement. Two types of curing were utilized; tap water curing and another curing environment that contains 5% $Na_2(SO_4)$ solution. Being the primary objective of this study, macro void developments of the mortar specimens were monitored by X-ray Medical Computerized Tomography. Compressive strength tests and water absorption tests were conducted on specimens that were kept in both curing environments for a duration of 560 days. Data analyses yielded consistent results among the three tests used in this experimental study. Macro void ratios of mortars decreased at the beginning of experiments for a certain period; afterwards, macro void ratios increased. The objective of this study was accomplished as anticipated since X-CT image analysis was able to nondestructively monitor macro void development process in cement mortars.

A Study on the Sulfate Attack of Concrete Using in Crushed Aggregates (부순모래 콘크리트의 황산염해에 관한 연구)

  • Kim, Kwang-Yuil;Kim, Kang-Min;Beak, Dong-Il;Kim, Myung-Sik;Kim, Jong-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.217-220
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    • 2005
  • As this study is to test effects of sulfate attack on deterioration of concrete using in crushed aggregates. Besides tests have been carried out with concrete by river sand and crushed sand by fine sand, concrete mixes various proportions of slica fume and fly ash(up to 15$\%$ by weight fo cement) were prepared and immersed in pure water, sodium sulfate solution for 28 and 60days. Test on the change in the weight and compressive strength of concrete according to the duration of immersion time and the content of slica fume and fly ash was performed.

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Evaluation on Sulfate Attack Resistance of Cement Matrix (시멘트 경화체의 황산염침식 저항성 평가)

  • 문한영;김홍삼;이승태
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.141-151
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    • 2000
  • Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

Resistance to Sulfate Attack of Concrete Containing LCD glass powder Using Industrial By-products (산업부산물을 활용한 LCD 유리 미분말 혼입 콘크리트의 황산염침식 저항성)

  • Kim, Seong-Kyum;Song, Jae-Ho
    • Journal of the Society of Disaster Information
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    • v.15 no.2
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    • pp.239-248
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    • 2019
  • Purpose: This study aims to enhance the resistance against sulfate attack compared to ordinary Portland cement (OPC) concrete by using liquid crystal display (LCD) as binder. Method: The fundamental properties including compressive strength and porosity of concrete replaced by LCD up to 15% at increments of 5% and in turn, the weight, volume, and strength loss of LCD-mixed concrete was analyzed. Results: For the concrete substituted by 5% of LCD, it showed the highest compressive strength at 28 days of curing, and particular at immersion of $Na_2SO_4$ solution, it was achieved the lowest loss of weight, volume and strength due to an decreased porosity at capillaries. In contrast, there is no distinct difference of the sulfate attack resistance between LCD-mixed concretes under exposure of $MgSO_4$ solution, excepted for OPC concrete. Conclusion: In this study, comparison of resistance to sulfate attack between LCD-mixed concretes, and it would be proposed the possibility of LCD usage as binder through long-term verification with extended replacement ratio and identification of changes of hydrates in the cement matrix.

Remaining service life estimation of reinforced concrete buildings based on fuzzy approach

  • Cho, Hae-Chang;Lee, Deuck Hang;Ju, Hyunjin;Kim, Kang Su;Kim, Ki-Hyun;Monteiro, Paulo J.M.
    • Computers and Concrete
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    • v.15 no.6
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    • pp.879-902
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    • 2015
  • The remaining service life (RSL) of buildings has been an important issue in the field of building and facility management, and its development is also one of the essential factors for achieving sustainable infrastructure. Since the estimation of RSL of buildings is heavily affected by the subjectivity of individual inspector or engineer, much effort has been placed in the development of a rational method that can estimate the RSL of existing buildings more quantitatively using objective measurement indices. Various uncertain factors contribute to the deterioration of the structural performance of buildings, and most of the common building structures are constructed not with a single structural member but with various types of structural components (e.g., beams, slabs, and columns) in multistory floors. Most existing RSL estimation methods, however, consider only an individual factor. In this study, an estimation method for RSL of concrete buildings is presented by utilizing a fuzzy theory to consider the effects of multiple influencing factors on the deterioration of durability (e.g., concrete carbonation, chloride attack, sulfate attack), as well as the current structural condition (or damage level) of buildings.

Modeling of diffusion-reaction behavior of sulfate ion in concrete under sulfate environments

  • Zuo, Xiao-Bao;Sun, Wei;Li, Hua;Zhao, Yu-Kui
    • Computers and Concrete
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    • v.10 no.1
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    • pp.79-93
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    • 2012
  • This paper estimates theoretically the diffusion-reaction behaviour of sulfate ion in concrete caused by environmental sulfate attack. Based on Fick's second law and chemical reaction kinetics, a nonlinear and nonsteady diffusion-reaction equation of sulfate ion in concrete, in which the variable diffusion coefficient and the chemical reactions depleting sulfate ion concentration in concrete are considered, is proposed. The finite difference method is utilized to solve the diffusion-reaction equation of sulfate ion in concrete, and then it is used to simulate the diffusion-reaction process and the concentration distribution of sulfate ion in concrete. Afterwards, the experiments for measuring the sulfate ion concentration in concrete are carried out by using EDTA method to verify the proposal model, and results show that the proposed model is basically in agreement with the experimental results. Finally, Numerical example has been completed to investigate the diffusion-reaction behavior of sulfate ion in the concrete plate specimen immersed into sulfate solution.

Sulfate Attack According to the Quantity of Composition of Cement and Mineral Admixtures (시멘트 화학성분(C3A)과 무기 혼화재에 따른 황산염 침투 특성)

  • Ahn, Nam-Shik;Lee, Jae-Hong;Lee, Young-Hak
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.547-556
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    • 2011
  • The primary factors affecting concrete sulfate resistance are the chemical composition of the Portland cement, and the chemistry and quantity of mineral admixtures. To investigate the effect of those on the sulfate attack, the testing program involved several different mortar mixes using the standardized test, ASTM C1012. Four different cements were evaluated, including one Type I cement, two Type I-II cements, and one Type V cement. Mortar mixes were also made with mineral admixtures, as each cement was combined with three different types of mineral admixtures. One Class F fly ash, one Class C fly ash, and one ground granulated blast furnace slag (GGBFS) were added in various percent volumetric replacement levels. Expansion measurements were taken and investigated with the expansion criteria recommended by ASTM.

Deterioration of Cement Matrix with Alkali-free Accelerator Exposed to Sulfate Media (황산염환경에 노출된 알카리프리계 급결제 사용 시멘트경화체의 성능저하)

  • Lee, Seung-Tae;Hooton, R.D.;Kim, Seong-Soo;Kim, Dong-Gyou
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.277-280
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    • 2006
  • This paper presents the findings on the sulfate resistance of mortar specimens with or without alkali-free accelerator exposed to sodium sulfate solution for 270 days. Test results confirms a negative effect of alkali-free accelerator on the sulfate deterioration. Additionally, the influences of exposure concentration and temperature of sulfate solution on expansion were investigated. Especially, at a high concentration of solution a significant expansion of mortar specimens with alkali-free accelerator was observed. Further, low temperature also promoted the deterioration of the cement system due to sulfate attack.

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