• Title/Summary/Keyword: Substrate particle size

Search Result 170, Processing Time 0.03 seconds

Effects of Moisture and a Saponin-based Surfactant during Barley Processing on Growth Performance and Carcass Quality of Feedlot Steers and on In vitro Ruminal Fermentation

  • Wang, Y.;Gibb, D.;Greer, D.;McAllister, T.A.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.24 no.12
    • /
    • pp.1690-1698
    • /
    • 2011
  • Feedlot and in vitro ruminal experiments were conducted to assess the effects of saponin-containing surfactant applied during tempering of barley grain on cattle growth performance and on ruminal fermentation. In the feedlot experiment, treatments with three barley grain/barley silage based diets were prepared using barley grain at 7.7% moisture (dry, D), after tempering to 18% moisture (M), or after tempering with a saponin-based surfactant included at 60 ml/t (MS). Each treatment was rolled at settings determined previously to yield optimally processed barley. A total of 180 newly weaned British${\times}$Charolais steers were fed three diets in 18 pens for a 63-d backgrounding period and 91-d finishing period to determine feed intake, growth rate and feed efficiency. Cattle were slaughtered at the end of the experiment to measure the carcass characteristics. Tempering reduced (p<0.001) volume weight and processing index, but processing characteristics were similar between MS and M. Tempering increased (p<0.05) growth during backgrounding only, compared with D, but did not affect feed intake in either phase. During backgrounding, feed efficiency was improved with tempering, but during finishing and overall this response was only observed with the surfactant. Tempering did not affect carcass weight, fat content or meat yield. Surfactant doubled the proportion of carcasses grading AAA. In the in vitro experiment, barley (500 mg; ground to <1.0 mm or steam-rolled) was incubated in buffered ruminal fluid (40 ml) without or with surfactant up to 20 ${\mu}l/g$ DM substrate for 24 h. Surfactant increased (p<0.05) apparent DM disappearance and starch digestibility but reduced productions of gas and the volatile fatty acid and acetate:propionate ratio, irrespective of barley particle size. Compared with feeding diets prepared with non-tempered barley, tempering with surfactant increased the feed efficiency of feedlot steers. This may have arisen from alteration in processing characteristics of barley grain by surfactant rather than its direct effect on rumen microbial fermentation.

Physical Properties of Indium Reduced Materials for Transparent Conductive Electrodes

  • Kwak, Seung-Hoon;Kwak, Min-Gi;Hong, Sung-Jei;Ju, Byeong-Kwon;Han, Jeong In
    • Current Photovoltaic Research
    • /
    • v.2 no.1
    • /
    • pp.14-17
    • /
    • 2014
  • In this paper, indium reduced materials for transparent conductive electrodes (TCE) were fabricated and their physical properties were evaluated. Two of materials, indium-zinc-tin oxide (IZTO) and aluminum (Al) were selected as TCE materials. In case of IZTO nanoparticles, composition ratios of In, Zn and Sn is 8:1:1 were synthesized. Size of the synthesized IZTO nanoparticles were less than 10 nm, and specific surface areas were about $90m^2/g$ indicating particle sizes are very fine. Also, the IZTO nanoparticles were well crystallized with (222) preferred orientation despite it was synthesized at the lowered temperature of $300^{\circ}C$. Composition ratios of In, Zn and Sn were very uniform in accordance with those as designed. Meanwhile, Al was deposited onto glass by sputtering in a vacuum chamber for mesh architecture. The Al was well deposited onto the glass, and no pore was observed from the Al surface. The sheet resistance of Al on glass was about $0.3{\Omega}/{\square}$ with small deviation of $0.025{\Omega}/{\square}$, and adhesion was good on the glass substrate since no pelt-off part of Al was observed by tape test. If the Al mesh is combined with ink coated layer which is consistent of IZTO nanoparticles, it is expected that the good and reliable metal mesh architecture for TCE will be formed.

Determination of Physical Chemical Properties of Organic and Inorganic Substrates for Horticulture by European Standard Method (유럽표준배지분석법에 의한 원예용 유기·무기성 배지의 물리화학적 특성)

  • Kang, Ji-Young;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.37 no.3
    • /
    • pp.143-148
    • /
    • 2004
  • Organic and inorganic substrates commonly used in Korea include peat moss, coir, bark, rice hull, saw dust, perlite, vermiculite, rockwool granulate, clay ball, and so on. The objective of this study was to get analytical results about the physical and chemical properties of these substrates by European standard methods. Organic substrates showed different properties depending on the type, origin and manufacturing processes. Inorganic substrates showed different properties depending on the type and particle size. Further study on physical and chemical properties for more raw materials and commercially available growing media analyzed by European standard method and comparison of the results with those by Korean standard method is needed.

The Development of Functional Photocatalytic $TiO_2$-Biodegrdable Plastic Composite Material by HVOF Spraying (고속가스플래임 용사법을 이용한 광촉매 $TiO_2$-생분해성 플라스틱 복합재료의 개발)

  • Bang, Hee-Seon;Bang, Han-Sur;Ohmori, Akira
    • Journal of Welding and Joining
    • /
    • v.24 no.5
    • /
    • pp.57-61
    • /
    • 2006
  • For the production of functional $TiO_2$-biodegradable plastic (polybutylene succinate:PBS) composite material with photocayalytic activity, we attempted to prepare $TiO_2$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions. The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated by the photo degradation of gaseous acetaldehyde. The effects of primary particle size and spraying parameters on the formation behavior, photocatalytic performance of the coatings have been investigated. The results indicated that for both the HVOF sprayed $P_{200}$ and $P_{30}$ coatings, the high anatase ratio of 100% can be achieved regardless of fuel gas pressure. On the other hand, the HVOF sprayed $P_7$ coating exhibited a largely decreased anatase ratio (from 100% to 49.1%) with increasing the fuel gas pressure, which may be attributed to much higher susceptibility of heat for 7 nm agglomerated powder. HVOF sprayed $P_{200}$ and $P_{30}$ coatings show better performance as compared to that of plasma sprayed $P_{200}$ coatings owing to the higher anatase ratio. However, the HVOF sprayed $P_7$ coatings did not show the photocatalytic activity, which may result from the extremely small reaction surface area to the photocatalytic activity and low anatase ratio.

Behavior of Graphite and Formation of Intermetallic Compound Layer in Hot Dip Aluminizing of Cast Iron (주철 - 알루미늄 합금의 Hot Dip Aluminizing시 흑연 및 금속간화합물 층의 형성 거동)

  • Han, Kwang-Sic;Kang, Yong-Joo;Kang, Mun-Seok;Kang, Sung-Min;Kim, Jin-Su;Son, Kwang-Suk;Kim, Dong-Gyu
    • Journal of Korea Foundry Society
    • /
    • v.31 no.2
    • /
    • pp.66-70
    • /
    • 2011
  • Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.

Citric Acid Fermentation from Mandarin Orange Peel by Aspergillus niger (감귤과피를 기질로 한 Aspergillus niger의 구연산 발효)

  • 강신권;박형환;이재호;이윤수;권익부;성낙계
    • Microbiology and Biotechnology Letters
    • /
    • v.17 no.5
    • /
    • pp.510-518
    • /
    • 1989
  • Most of orange peels are disposed from orange juice manufacturing process. Thus, our purpose is to utilize these orange peels as fermentation substrate. We have investigated culture conditions and factors influencing citric acid production by an isolated strain, Asp. niger. Citric acid production was much higher in semisolid culture than in submerged culture and the particle size of ground orange peels was favored at 20 mesh in semisolid culture. The optimal pH and temperature were 4.5-5.0 and 3$0^{\circ}C$ respectively and the temperature cycling at 35$^{\circ}C$ for 20 hrs durig exponential phase, 1$0^{\circ}C$ for 4 hrs and 3$0^{\circ}C$ during stationary phase showed higher citric acid production than did at fixed temperature, 3$0^{\circ}C$. The addition of NH$_4$NO$_3$0.2%, MgSO$_4$7$H_2O$ 0.1%, methanol 2.5%, ethanol 1.5%, to culture medium promoted citric acid production but the addition of trace metal ions as nutrients had not effect on the acid production in orange peel medium. Under the optimal culture conditions, maximum yield of citric acid was 80.4% in solid medium. Almost of all original components of citrus peel was consumed by Asp. niger during fermentation.

  • PDF

Synthesis of Silica Aerogel and Thin Film Coating at Ambient (상입하에서의 실리카 에어로겔의 합성 및 박막코팅(I))

  • 양희선;최세영
    • Journal of the Korean Ceramic Society
    • /
    • v.34 no.2
    • /
    • pp.188-194
    • /
    • 1997
  • Wet gel with surface modification by TMCS was redispersed in EtOH and redispersed silica sol for coat-ing was prepared. After spin coating of redispersed sol was conducted on silicon substrate, processes of drying(8$0^{\circ}C$) and heat treatment(>25$0^{\circ}C$) were, followed at ambient pressure. The influence of heat treat-ment of properties of film was observed, changing temperature at heat treatment. The optimum redisp-ersion condition for stable silica sol was wet gel:EtOH=1g:110$m\ell$ and the concentration and viscosity of redispersed silica sol with average particle size of 30nm were 0.11 M, 2.0-2.2 cP respectively. Crack-free thin film with the refractive index of 1.14 and thickness of 400 nm was obtained through drying at 8$0^{\circ}C$ and subsequent heat treatment at 45$0^{\circ}C$ for 2 hrs respectively after spin coating of 1500rpm, 10 times.

  • PDF

The Fabrication of Thermal Sprayed Photocatalytic $TiO_{2}$ Coating on Bio-degradable Plastic

  • Bang, Hee-Seon;Bang, Han-sur
    • Proceedings of the KWS Conference
    • /
    • 2005.06a
    • /
    • pp.387-392
    • /
    • 2005
  • For the production of further functional bio-degradable plastic(polybutylene succinate:PBS) with $TiO_{2}$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare $TiO_{2}$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions. The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. The effects of primary particle size and spraying parameters on the formation behavior, photo catalytic performance and mechanical characteristics of the coatings have been investigated. The results indicated that with respect to both the HVOF sprayed $P_{200}$ and $P_{30}$ coatings, the high anatase ratio off 100% can be achieved regardless of fuel gas pressure. On the other hand, the HVOF sprayed $P_{7}$ coating exhibited largely decreased anatase ratio (from 100% to 49.1%) with increasing the fuel gas pressure, which may be attributed to the much higher susceptibility to heat of 7nm agglomerated powder. In terms of photocatalytic efficiency, HVOF sprayed $P_{200}$ and $P_{30}$ coatings seem to predominate as compared to that of plasma sprayed $P_{200}$ coatings owing to the higher anatase ratio. However, the HVOF sprayed $P_{7}$ coatings didn't show the photo catalytic activity, which may result from the extremely small reaction surface area to the photo-catalytic activity and low anatase ratio. Such functional PBS with new roles is expected to cosiderably contribute to the reduction of aggravated environmel problem.

  • PDF

Fabrication of shape-controlled Au nanoparticle arrays for SERS substrates

  • Shin, Seon Mi;Choi, Kyeong Woo;Ye, Seong Ji;Kim, Young Yun;Park, O Ok
    • Advances in materials Research
    • /
    • v.3 no.3
    • /
    • pp.139-149
    • /
    • 2014
  • Surface enhanced Raman Scattering (SERS) has attracted attention because the technique enables detection of various chemicals, even down to single molecular scale. Among the diverse candidates for SERS substrates, Au nanoparticles are considered promising due to their fine optical properties, chemical stability and ease of surface modification. Therefore, the fabrication and optical characterization of gold particles on solid supports is highly desirable. Such structures have potential as SERS substrates because the localized surface plasmon resonance of gold nanoparticles is very sensitive to combined molecules and environments. In addition, it is well-known that the properties of Au nanoparticles are strongly dependent on their shape. In this work, arrays of shape-controlled Au nanoparticles were fabricated to exploit their enhanced and reproducible optical properties. First, shape-controlled Au nanoparticles were prepared via seed mediated solution-phase synthesis, including spheres, octahedra, and rhombic dodecahedra. Then, these shape-controlled Au nanoparticles were arranged on a PDMS substrate, which was nanopatterned using soft lithography of poly styrene particles. The Au nanoparticles were selectively located in a pattern of hexagonal spheres. In addition, the shape-controlled Au nanoparticles were arranged in various sizes of PDMS nanopatterns, which can be easily controlled by manipulating the size of polystyrene particles. Finally, the optical properties of the fabricated Au nanoparticle arrays were characterized by measuring surface enhanced Raman spectra with 4-nitrobenezenethiol.

Synthesis of Silica Membranes on a Porous Stainless Steel by Sol-Gel Method and Effect of Preparation Conditions on Their Permselectivity

  • Lee, Dong-Wook;Nam, Seung-Eun;Sea, Bong-Kuk;Ihm, Son-Ki;Lee, Kew-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.9
    • /
    • pp.1371-1378
    • /
    • 2004
  • A porous stainless steel (SUS) as a substrate of silica composite membranes for hydrogen purification was used to improve mechanical strength of the membranes for industrial application. The SUS support was successfully modified by using submicron Ni powder, $SiO_2$ sols with particle size of 500 nm and 150 nm in turns. Silica top layer was coated on the modified supports under various preparation conditions such as calcination temperature, dipping time and repeating number of dipping-drying process. The calcination temperature for proper sintering was between H ttig temperature and Tamman temperature of the coating materials. Maximum hydrogen selectivity was investigated by changing dipping time. As repeating number of dipping-drying process increased, permeances of nitrogen and hydrogen were decreased and $H_2/N_2$ selectivity was increased due to the reduction of non-selective pinholes and mesopores. For the silica membrane prepared under optimized conditions, permeance of hydrogen was about $3\;{\times}\;10^{-5}\;cm^3{\cdot}cm^{-2}{\cdot}s^{-1}{\cdot}cmHg^{-1}$ combined with $H_2/N_2$ seletivity of about 20.