• Title/Summary/Keyword: Substitution rate

Search Result 546, Processing Time 0.026 seconds

Production of heteropolysaccharide-7 by Beijerinckia indica HS-2001 with continuous culture

  • Yang, Jae-Gyun;Seo, Hyeong-Pil;Sin, Myeong-Gyo;Lee, Jin-U
    • 한국생물공학회:학술대회논문집
    • /
    • 2003.04a
    • /
    • pp.249-252
    • /
    • 2003
  • Maximal production of heteropolysaccharide-7(PS-7) with a batch culture for 48 hr was $10.0\;g/{\ell}$ and its conversion rate from 2% (w/v) glucose to PS-7 was 50%. After substitution of media, production of PS-7 continued and reached its maximal production. The highest productivity occurred when the fresh medium, which contained all ingredients, for the production of PS-7 was substituted. Higher production of PS-7 was maintained at a dilution rate of 0.0125, which was established as the optimal dilution rate for the production of PS-7 by B. indica HS-2001.

  • PDF

Kinetic Study for the Reaction of Pyridine under High Pressure (고압하의 피리딘 반응에 대한 속도론적 연구)

  • 김명자
    • The Korean Journal of Food And Nutrition
    • /
    • v.16 no.4
    • /
    • pp.321-327
    • /
    • 2003
  • The reaction rates of 4-ethyl pyridine with p-methyl benzylbromide have been measured by conductometry in acetonitrile, and the rate constants of these reactions are determined in accordance with various temperatures (20, 25, 30$^{\circ}C$) and pressures (1, 200, 500, 1000 bar). The rate constants increased with the higher pressure and temperature. The activation energies and activation parameter values of these reactions are calculated by determination of the rate constants the same. The activation volume, activation compressibility coefficient and the activation entropy are all negative. The result of kinetic studies for the pressure show that this reaction proceeds in typical bimolecular nucleophilic substitution reaction.

A study on the Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives (Vanillylidene imine 유도체의 가수분해 반응에 관한 속도론적 연구)

  • Sung, Ki-Chun;Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.145-150
    • /
    • 1995
  • The Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives has been measured by ultra-violet ray spectrophotometer in 20wt% $dioxane-H_2O$ at $25^{\circ}C$. It was measured the reaction rate Constant of vanillylidene imine derivatives that can be applied widely following to pH-change at $25^{\circ}C$. Final products that hydrolyzed the vanillylidene imine certified in vanillin and aniline derivative, and the effect of substitution radical that has affected on hydrolysis reaction was largely promoted to reaction rate by electron attrating group in acidity and electron donoring group in basic. From the results of rate constant to hydrolysis reaction, substituent radical effect and final products. It has certified the hydrolysis reaction mechanism of vanillylidene imine derivatives.

Some Clinical Aspects of Dysarthria (마비성 조음장애의 임상적 양상에 관한 고찰)

  • Kim, H.G.;Kim, W.H.;Seo, J.H.;Hong, K.H.;Shin, H.K.;Ko, D.H.
    • Speech Sciences
    • /
    • v.3
    • /
    • pp.38-49
    • /
    • 1998
  • Dysarthrias are a sort of neuromotor disorders because of the weakness of neuromotor controls. They are classified in six types on the basis of Mayo clinic research: flaccid, spastic, ataxic, hypokinetic, hypekinetic and mixed types. Five dysarthria types are investigated in this study. MRI, EMG, neuropathological tests are essential diagnostic processing. Visi-Pitch and Spectrgraphy, CSL are used for assessing dysarthria speech. Maximum phonation time, diadochokinetic rate, Voice Onset Time and substitution rate are the speech evaluation parameters. Maximum phonation time and diadochokinetic rates are the lowest in case of spastic and ataxic dysarthrias. Spastic dysarthria shows the substituted glottalized consonants. However, flaccid, ataxic and hypokinetic dysarthrias show the substituted aspirated consonants. VOT is the longest for hypokinetic dysarthria and the shortest for ataxic dysarthria. Jitter shows higher percentage in comparison with control group. Speech evaluation using experimental phonetic instruments help create on international standardization of speech evaluation for speech disorders.

  • PDF

Mössbauer Analysis of Cations on Iron Oxyhydroxide Formation

  • Oh, Sei-Jin;Kwon, Soon-Ju
    • Journal of the Korean Magnetics Society
    • /
    • v.15 no.2
    • /
    • pp.85-91
    • /
    • 2005
  • Effect of different cations to the formation of iron oxyhydroxide was studied using $M\ddot{o}ssbauer$ spectroscopy, X-ray diffraction (XRD) and BET. Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the presence of different cations in solution. Although the oxyhydroxide compound was composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

The Effect of the Changing of C-O-C to C-S-C and C=O to C=S on Reactivity of 4-Nitrophenyl Benzoate with Alkali Metal Ethoxides in Ethanol

  • Kwon, Dong-Sook;Park, Hee-Sun;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
    • /
    • v.12 no.1
    • /
    • pp.93-97
    • /
    • 1991
  • Rate constants have been measured spectrophotometrically for the reactions of alkali metal ethoxides with 4-nitrophenyl benzoate, S-4-nitrophenyl thiobenzoate and 4-nitrophenyl thionbenzoate in ethanol at 25$^{\circ}$C. Substitution of S for O in the leaving group has not affected reactivity significantly, while the effect of the similar replacement in the acyl group has led to rate decrease by a factor of 10, although pronounced rate enhancements have been expected for both systems. The replacement of O by a polarizable S has also influenced the reactivity of the esters toward alkali metal ethoxides, i.e. the reactivity decreases as the size of the metal ion decreases. The alkali metal ions have showed inhibition effect instead of catalytic effect which would have been expected for the present system. The effect of replaced sulfur atom on the reactivity for the present system is attributed to the nature of hard and soft acids and bases.

Evaluation of Chloride Ion Diffusion Characteristics of Concrete according to the Replacement Rate of Recycled Aggregate (순환골재 치환율에 따른 콘크리트 염소이온 확산 특성 평가)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2023.11a
    • /
    • pp.203-204
    • /
    • 2023
  • Recycled aggregate is an aggregate that satisfies the quality as an aggregate by crushing waste concrete and passing it through a separator. The government grants a floor area ratio of up to 15% and building height mitigation when more than 25% of the recycled building materials are used. In addition to environmental protection issues, it is necessary to actively utilize recycled aggregates that meet the standards to secure the business feasibility of buildings. This study attempted to derive the results according to the substitution rate by measuring the chloride ion diffusion characteristics based on the electrophoresis method.

  • PDF

The Calculation of the Effected Rate in Medical Insurance Fee Schedules according to Fluctuation of Foreign Currency Exchangerate through Cost Analysis in a University Hospital (환율변동에 따른 의료보험 진료수가의 영향률 산출 - 한 대학병원의 원가분석을 중심으로 -)

  • 박은철;박웅섭;김소윤;김한중;손명세;임종건;김영삼
    • Health Policy and Management
    • /
    • v.8 no.2
    • /
    • pp.76-87
    • /
    • 1998
  • This study analyzed the effect of foreign currency exchange rate on the increasing rate of medical care cost by items of fee schedule of Korean Medical Insurance. This study uses the data of cost analysis including cost of imported goods and the data of for a university hospital National Federation's Medical Insurance for a trend of claim. The method of cost analysis is as same as that used in the study of the development of Korean RBRVS(Resource Based Relative Valus Scale). The main findings of this study are as follows; 1. The proportion of imported goods in cost related to Medical Insurance fee schedule is 7.93%, and in case of substitution of available domestic goods 6.96%. 2. If foreign currency exchange rate changes from 800wen per $1 to 1,300won, the affecting rate of Medical Insurance fee schedules is 5.00%. If the imported goods will be substituted with available domestic goods, the rate 4.35%. Our results can be used a data for updating Medical Insurance fee schedule. But this result is limited to be generalized, because this study used the cost analysis for a university hospital.

  • PDF

Intake and performance of lambs finished in feedlot with wet brewer's grains

  • Frasson, Monica Feksa;Carvalho, Sergio;Jaurena, Gustavo;Menegon, Aliei Maria;Severo, Marcelo Machado;da Motta, Juliano Henriques;Teixeira, William Soares
    • Journal of Animal Science and Technology
    • /
    • v.60 no.5
    • /
    • pp.12.1-12.5
    • /
    • 2018
  • Background: The use of agroindustrial by-products in ruminant nutrition to be an interesting alternative in order to reduce production costs and environmental impacts arising from the inadequate destination of residues. The initial step of beer production yields a large volume of wet brewer's grains all year around, which is available at a low cost and has a high nutritional quality, and hence a big potential for animal production. Methods: Twenty-four Suffolk non-castrated male lambs, from simple parturition were kept in individual spots and allocated to four treatments constituted by four levels of substitution of sorghum silage by WBG (i.e.0; 33.5; 66.5 and 100% of substitution). It was used roughage: concentrate rate of 50:50, based on dry matter. Results: The ether extract intake increased while the acid detergent fiber intake decreased linearly ($P{\leq}0.05$). Substituion of sorghum silage by WBG did not change lambs' feed DMI, daily weight gain and feed conversion. Conclusion: The substitution of sorghum silage by WBG as roughage showed to be a viable alternative from the productive and economic point of view for finishing of feedlot lambs.

Nucleophilic Substitution Reactions of Benzoic Anhyrides with Aniline in Methanol-Acetonitrile Mixtures (메탄올-아세토니트릴 혼합용매에서 벤조산 무수물과 아닐린의 친핵성 치환반응)

  • Lee, Byung Choon;Shin, Young Kook;Lee, Seung Woo;Lee, Ik Choon;Lee, Won Heui
    • Journal of the Korean Chemical Society
    • /
    • v.41 no.2
    • /
    • pp.69-76
    • /
    • 1997
  • Kinetic studies for the nucleophilic substitution reactions of the benzoic anhydrides with anilines in methanol-acetonitrile mixtures at$35.0{\circ}C$have been carried out in order to elucidate the reaction mechanism. Individual rate constants$k_{XY}$and$k_{XZ}$were decided from the ratios of the reaction products for the competitive substitution reaction at either one of the two carbonyl carbons in benzoic anhydride. Transition state structure and reaction mechanism were elucidated by the Hammett$p_x,\;p_y$and$p_z$values and cross interaction constant$p_x\;p_y$and$p_zvalues. The reaction of the benzoic anhydride has been proposed to proceed by a frontside attack$S_N2 $mechanism with four-membered ring transition state from unusually large magnitude of the$ρ_X,\;ρ_{XY},\;ρ_{XZ}$and positive$p_Y$values.

  • PDF