• Title/Summary/Keyword: Substitution method

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Functional Layer-by-Layer Assembled Multilayers Based on Nucleophilic Substitution reaction

  • Jo, Jin-Han
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.9.2-9.2
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    • 2011
  • Ultrathin polyelectrolyte (PE) multilayer films prepared by the versatile layer-by layer (LbL) assembly method have been utilized for the preparation of light-emitting diodes, electrochromic, membrane, and drug delivery system, as well as for selective area patterning and particle surface modification because the various materials with specific properties can be inserted into the film with nano-level thickness irrespective of the size or the shape of substrate. Since the introduction of the LbL technique in 1991 by Decher and Hong, various hydrophilic materials can be inserted within LbL films through complementary interactions (i.e., electrostatic, hydrogen-bonding or covalent interaction). In this study, it is demonstrated that LbL SA multilayer films based on nucleophilic substitution reaction can allow the preparation of the highly efficient magnetic and/or optical films and nonvolatile memory devices.

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The Properties of High Flowing Concrete with Fly Ash for CFT Structure (플라이 애쉬를 사용한 CFT 구조용 고유동콘크리트의 강도특성)

  • Ahn, Nam-Shik;Lim, Hong-Chul;Choi, Jae-Gon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.93-96
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    • 2006
  • To investigate the properties of high flowing concrete with fly ash and crushed sand for CFT structure, many batches were performed by a trial-error method and the results were analyzed by SPSS software program. In the experiment W/B was set up as 0.25 and the variables were a substitution ratio of fly ash, a blend ratio of crushed sand and the ages of specimens (3, 7, 28 days). The results of this study are summarized as the follows; 1) The increase of the substitution ratio of fly ash, the decrease of dosage of SP and the increase of dosage of AEA due to very fine sphere particle of fly ash. 2) The increase of the blend ratio of crushed sand, the increase of dosage of S/a and water content related with viscosity. 3) Made the high flowing concrete, the increase S/a and the increase the water content.

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The Experience Study on the Floating Properties of Concrete with Recycled Coarse Aggregate (재생굵은골재를 사용한 콘크리트의 유동특성에 관한 실험적 연구)

  • 백철우;김호수;최성우;반성수;류득현
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.94-97
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    • 2003
  • Recently, owing to the deterioration of reconstruction and the construction, much of the construction waste is discharged in our construction field, and the amount of construction waste are rapidly increased. These waste are raised to financial and environmental problems, so the method of reusing waste concretes has been studied and carried out many direction. Especially being want of resources, if waste concrete could be recycled as aggregate for concrete, it will contribute to solve the exhaustion of natural aggregate, in terms of saving resources and protecting environment. This study is that the floating properties of concrete with recycled coarse aggregate were investigated for the substitution of recycled coarse aggregate. The result of this study, in case of water reducing, the property of harden concrete for the substitution ratio of recycled coarse aggregate was increased. The Quality of recycled coarse aggregate concrete was improved by water reducing.

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COGNITIVE SPELLING THERAPIST: A combined method for correcting four types of spelling errors: insertion, deletion, transposition, substitution (인지적 철자 교정 후보 제시기: 삽입, 생략, 전위, 대치 오류 수정을 위한 복합 방안)

  • Lee, Jong-Ho;Lee, Jong-Hyeok;Lee, Gun-Bae
    • Annual Conference on Human and Language Technology
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    • 1994.11a
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    • pp.132-139
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    • 1994
  • Cognitive Spelling Therapist generates the candidates for correction of one-letter misspelling words, which correspond to over 80 % of the misspelling words. One-letter misspelling can be divided into four categories, and for each categories Cognitive Spelling Therapist copes them with seperate cognitive therapies. Each therapy is based on cognitive causes of misspelling: figural confusion, pronunciation confusion, and keyboard confusion. Cognitive Spelling Therapist generates three candidates for correction in average. After we tested the correctness of candidates with 185 misspelled words randomly sampled from two typist for two months, Cognitive Spell Therapist showed 97.5 % correction for substitution errors, while insertion, deletion, and transposition errors were perfectly corrected.

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Interactive Multiobjective Decision Making under Fuzzy Environment (Fuzzy 환경하에서의 상호작용적 다목적 의사결정)

  • 이상완;김재연
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.13 no.22
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    • pp.51-57
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    • 1990
  • A new interactive multiobjective decision making technique, which is called the fuzzy sequential proxy optimization technique, has been proposed. This technique is the revised version the sequential proxy optimization technique that the decision-maker's marginal rates of substitution is interpreted as type of L-R fuzzy numbers. It used to the square of normalized scalar product as the doptimalilry condition. However, this technique ignores the imprecise nature of a decision-maker's judgement of marginal rates of substitution. Also, it have a shortcoming that can be only applied over three objective functions. In this paper, considering the imprecise nature of a decision-maker's judgement, we presents an interactive fuzzy decision-making method on the basis of the decision-maker's MRS presented through the use of five types of membership functions including non-linear functions. FORTRAN programs that run in conversational mode are developed to implement man-machine interactive procedure.

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An Experimental Study on the Mechanical Properties of Recycled Aggregate Concrete Containing Admixtures (혼화재를 사용한 재생굵은골재 콘크리트의 역학적 특성에 관한 실험적 연구)

  • 백철우;김호수;반성수;최성우;류득현
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.223-228
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    • 2003
  • Recently, owing to the deterioration of reconstruction and the construction, much of the construction waste is discharged in our construction field, and the amount of construction waste is rapidly increased. These waste are raised to financial and environmental problems, so the method of reusing waste concretes has been studied and carried out many direction. Especially being want of resources, if waste concrete could be recycled as aggregates for concrete, it will contribute to solve the exhaustion of natural aggregate, in terms of saving resources and protecting environment. This study is that the mechanical properties of concrete with recycled coarse aggregate were investigated for types of mineral admixture and the substitution of recycled coarse aggregate. The result of this study, in case of using mineral admixture, the property of fresh concrete was rised. And the property of harden concrete for the substitution ratio of recycled coarse aggregate was decreased. But the property of concrete with mineral admixture was better than that of concrete used only cement.

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Decomposition of Energy - Induced CO2 Emissions in Korea Using Log Mean Divisia Index Approach (로그 평균 디비지아 지수 기법을 이용한 이산화탄소 배출량 변화의 요인분해)

  • Chung, Hae-Shik;Lee, Kihoon
    • Environmental and Resource Economics Review
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    • v.10 no.4
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    • pp.569-589
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    • 2001
  • We examine historical contributions of inter fuel substitution, changes in carbon efficiency and energy intensity, growth of economy and population to Korea's $CO_2$ emissions from 1970 to 1998 using the log mean weight Divisia index method. The study reveals that economic growth is the most significant factor to $CO_2$ emissions growth among the five factors. Changes in the fuel substitution and carbon coefficient are found negative contributors to $CO_2$ emissions growth. Energy intensity, which played dominant role in halting $CO_2$ emissions growth in the 1980s, began to play reversed role in the 1990s. When evaluated with the log mean Divisia index technique, deterioration of energy intensity in the 1990s is found worse and expected to contribute $CO_2$ emissions growth further.

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The Properties of High Flowing and Strength Concrete Utilizing Crushed Sand for CFT Structure (부순모래를 사용한 CFT 구조용 고유동.고강도콘크리트의 물성 변화)

  • Ahn Nam-Shik;Rhim Hong-Chul;Lim Hye-Sun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.89-92
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    • 2006
  • To investigate the properties of high flowing and high strength concrete with crushed sand and fly ash for CFT structure, many batches were performed by a trial-error method. In the experiment W/B was set up three levels as 0.25, 0.30 and 0.35. Also the variables of the experiment were a substitution ratio of fly ash, a blend ratio of crushed sand and the ages of specimens(3, 7, 28 days). The results of this study are summarized as the follows; 1) The effect a substitution ratio of fly ash on the compressive strength was not consistent with age. For twenty-eight day compressive strength, the best result was come out when cement was substituted by 10% of fly ash. 2) The decrease of the water binder ratio, the increase of compressive strength and elastic modulus. Also the relationship is very similar to the case of a normal concrete

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Synthesis and Biological Activity of 6-Substituted-2-Oxo-Purine Nucleosides

  • Lee, Sang-Jun;Kim, Jong-Bae;Cho, Young-Ho;Kim, Jung-Han
    • Archives of Pharmacal Research
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    • v.17 no.3
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    • pp.170-174
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    • 1994
  • We have synthesized various 6-substituted 2-oxo-purine nucleosides from key intemediate, 6-[(4-methylphenylthio)-2-oxo-9(2, 3, 5tri-o-acetyl-$\beta$-D-ribofuanoslyl)]-2, 3- dihydropurine in relatively high yields by one step nucleophilic substitution. Various isoguanosine, xanthosine analogs and other 2-oxo-purine nucleosides containing nitrogen, sulfur and oxygen at C-6 of purine base were easily obtained by this method. The structures of the products were established on the basis of their spectral data studies. And cytotoxicity of resulting synthetic 6-substituted-2-oxo-purine nucleosides against some tumor cell-lines was examined. $Ed_{50}$ values of these synthetic compounds were above $100\;{\mu}g/ml$ except isoguanosine, $N^6$-methyl isoguanosine and thioxanthosine analogs.

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Optical Implementation for 1-bit Symbolic substitution Adder (1-비트 기호치환 가산기의 광학적인 구현)

  • 조웅호;김수중
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.8
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    • pp.26-33
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    • 1994
  • Optical adders using a modified signed-digit(MSD) number system have been proposed to restrict the carry propagation chain encountered in a conventional binary adder to two positions to the left. But, MSD number system must encode three different states to represent the three possible digits of MSD. In this paper, we propose the design of an optical adder based on 1-bit addition rules by using the method of symbolic substitution (SS). We show that this adder can use binary input which is used by a digital computer, as it is and be implemented by smaller system in size than MSD adder.

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