• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.4
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• pp.74-84
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• 2004

In this paper, a theoretical method was derived to redesign carbody members by substituting light-weight materials, and to estimate their structural characteristics. Some performance indices to estimate structural behaviors were derived in order to obtain equivalent designs in case of material substitutions under important design constraints of rolling stock, such as bending stiffness, natural frequency, bending and buckling strength. Validity of the theoretical method was evaluated by comparing its results with finite element results in some examples where the aluminium alloy was substituted for the structural steel. The numerical results of the examples show that the proposed method gives reasonable initial guesses for the material substitution designs.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.4 no.2
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• pp.95-102
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• 2000

Methane combustion over perovskite-type oxides prepared using the malic acid method was investigated. To enhance the catalytic activity, the perovskite oxides were modified by the substitution of metal into their A or B site. In addition, the reaction conditions, such as the temperature, space velocity, and partial pressure of the methane were varied to understand their effect on the catalytic performance. With the LaCoO3-type catalyst, the partial substitution of Sr or Ba into site A enhanced the catalytic activity in the methane combustion. With the LaBO3(B=Co, Fe, Mn, Cu)-type catalyst, the catalytic activities were exhibited in the order of Co>Fe Mn>Cu. Futhermore, the partial substitution of Co into site B enhanced the catalytic activity, whereas an excess amount of Co decreased the activity. The surface area and catalytic activity of the perovskite catalysts prepared using the malic acid method showed higher values than those prepared using the solid reaction method. The catalytic activity was enhanced with decreased methane concentration and with a decrease in the space velocity.

• Proceedings of the KSR Conference
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• 2003.10c
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• pp.446-454
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• 2003

This paper derived a theoretical method to estimate structural characteristics of carbody members when material substitution designs were performed, and verified the theoretical method with finite element analyses. For important factors in rolling stock design, such as bending stiffness, natural frequency, bending strength and buckling strength, some performance indices to estimate structural behaviors were developed in order to derive an equivalent design in spite of material substitutions. The developed method was used to reduce the weights of carbody components, as example problems, by substituting the aluminium alloy for the structural steel. The analysis results of the examples show that the proposed technique gives a reasonable initial guess in the case of a material substitution design.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.2
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• pp.45-54
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• 2013

In this paper, a theoretical weight-reduction method was suggested to substitute an underframe material of a box-type bodyshell having cut-outs with an alternative light-weight material. To utilize the material substitution method previously developed for a box-type hybrid bodyshell not having cut-outs, we derived a box-type baseline model without cut-outs which is similar to the stiffness condition of a box-type bodyshell having cut-outs. To do this, the thicknesses of roof and walls of the baseline model were determined such that the deflection of the baseline model under a distributed vertical load condition is equal to the sum of the theoretical section deflections of the original box model with cut-outs. Next, to derive a hybrid bodyshell by under-frame material substitution, the material substitution method for a box-type hybrid bodyshell without cut-outs was applied to the box-type baseline model. Finally, we compared the FE simulation results of the derived hybrid bodyshells having cut-outs for various materials with the theoretical results of the suggested method, and we obtained their good correlations.

• Bulletin of the Korean Chemical Society
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• v.27 no.3
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• pp.345-354
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• 2006

Ionic liquids are alternative reaction media of increasing interest and are regarded as an eco-friendly alternatives, of potential use in place of the volatile organic solvents typically used in current chemical processing methods. They are emerging as the smart and excellent solvents, which are made of positive and negative ions that they are liquids near room temperature. The nucleophilic substitution reaction is one of the important method for inserting functional groups into a carbon skeleton. Many nucleophilic substitution reactions have been found with enhanced reactivity and selectivity in ionic liquid. In this review, some recent interesting results of nucleophilic substitution reactions such as hydroxylations, ether cleavages, carbon-X (X= carbon, oxygen, nitrogen, fluorine) bond forming reactions, and ring opening of epoxides in ionic liquids are discussed.

• ETRI Journal
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• v.43 no.6
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• pp.1113-1129
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• 2021

Lightweight ciphers are increasingly employed in cryptography because of the high demand for secure data transmission in wireless sensor network, embedded devices, and Internet of Things. The PRESENT algorithm as an ultralightweight block cipher provides better solution for secure hardware cryptography with low power consumption and minimum resource. This study generates the key using key rotation and substitution method, which contains key rotation, key switching, and binary-coded decimal-based key generation used in image encryption. The key rotation and substitution-based PRESENT architecture is proposed to increase security level for data stream and randomness in cipher through providing high resistance to attacks. Lookup table is used to design the key scheduling module, thus reducing the area of architecture. Field-programmable gate array (FPGA) performances are evaluated for the proposed and conventional methods. In Virtex 6 device, the proposed key rotation and substitution PRESENT architecture occupied 72 lookup tables, 65 flip flops, and 35 slices which are comparably less to the existing architecture.

• ETRI Journal
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• v.30 no.1
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• pp.170-172
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• 2008

A substitution box (S-box) plays a central role in cryptographic algorithms. In this paper, an efficient method for designing S-boxes based on chaotic maps is proposed. The proposed method is based on the mixing property of piecewise linear chaotic maps. The S-box so constructed has very low differential and linear approximation probabilities. The proposed S-box is more secure against differential and linear cryptanalysis compared to recently proposed chaotic S-boxes.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.8
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• pp.361-366
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• 2017

For two given logical expressions and, when expression contains the same part of the logical expression as expression, substituting for that part of expression is called a substituted logic expression. If a substituted relation is established between the logical expressions, there is an advantage in that the number of literals used in the whole logical expression can be greatly reduced. However, if the substituted relation is not established, there is no simplification effect obtained from the substituted expression. Previous methods proposed a way to find substituted relations between logical expressions for the given logical expressions themselves, and to calculate substituted expressions if only substitution is possible. In this paper, a new method for performing substitution with addition and revision of logic terms is proposed in order to perform substitution, even though there is no substituted relation between two logic expressions. The proposed method is efficiently implemented using a matrix that finds terms to be added. Then, by covering the matrix that has added terms, substituted logic expressions are found. Experiment results show that the proposed method for several benchmark circuits can reduce the number of literals, compared to existing synthesis tools.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.244.2-244.2
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• 2011

We introduce a novel and robust method for the preparation of nanocomposite multilayers, which allows the excellent photoluminescent (PL) properties as well as the accurate control over the composition and dimensions of multilayers. By exchanging the oleic acid stabilizers of CdSe@ZnS quantum dots (QDs) synthesized in organic solvent with 2-bromo-2-methylpropionic acid (BMPA) in the same solvent, these nanoparticles were be alternately deposited by nucleophilic substitution reaction with highly branched poly(amidoamine) dendrimer (PAMA) through layer-by-layer (LbL) assembly process. Our approach does not need to be transformed into the water-dispersible nanoparticles with electrostatic or hydrogen-bonding groups, which can deteriorate their inherent properties, for the built-up of multilayers. The nanocomposite multilayers including QDs exhibited the strong PL properties achieving densely packed surface coverage as well as long-term PL stability under atmospheric conditions in comparison with those of conventional LbL multilayers based on electrostatic interaction. Furthermore, we demonstrate that the flexible multilayer films with optical properties can be easily prepared using nucleophilic substitution reaction between bromo and amino groups in organic media. This robust and tailored method opens a new route for the design of functional film devices based on nanocomposite multilayers.

• Journal of the Korean Ceramic Society
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• v.45 no.9
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• pp.556-560
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• 2008

The effects of Nb and Co ion substitution on the dielectric and magnetic properties of the multiferroic $BiFeO_3$ thin films have been investigated. Heteroepitaxial $BiFeO_3$ thin films were deposited by Pulsed Laser Deposition method. Nb substitution decreased the leakage current by 6 orders of magnitude and Co substituted $BiFeO_3$ thin films showed an enhanced magnetization, 2 times larger than that of un-substituted $BiFeO_3$. Through the co-substitution of Co and Nb, $BiFeO_3$ thin films with a low leakage current and an enhanced magnetization could be obtained.