[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2006.27.3.345

Ionic Liquids: An Environmentally Friendly Media for Nucleophilic Substitution Reactions

Jorapur, Yogesh R. (Department of Chemistry, Inha University)
Chi, Dae-Yoon (Department of Chemistry, Inha University)

Publication Information

Bulletin of the Korean Chemical Society / v.27, no.3, 2006 , pp. 345-354 More about this Journal

Abstract

Ionic liquids are alternative reaction media of increasing interest and are regarded as an eco-friendly alternatives, of potential use in place of the volatile organic solvents typically used in current chemical processing methods. They are emerging as the smart and excellent solvents, which are made of positive and negative ions that they are liquids near room temperature. The nucleophilic substitution reaction is one of the important method for inserting functional groups into a carbon skeleton. Many nucleophilic substitution reactions have been found with enhanced reactivity and selectivity in ionic liquid. In this review, some recent interesting results of nucleophilic substitution reactions such as hydroxylations, ether cleavages, carbon-X (X= carbon, oxygen, nitrogen, fluorine) bond forming reactions, and ring opening of epoxides in ionic liquids are discussed.

Keywords

Ionic liquid; Nucleophilic substitution reaction; $S_N2$ ; Reaction media;

Citations & Related Records

Times Cited By KSCI : 2 (Citation Analysis)
Times Cited By Web Of Science : 33 (Related Records In Web of Science)
Times Cited By SCOPUS : 32

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