• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.1993-1995
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• 2007

A substitution effect on the electronic transition of bi-substituted benzyl-type radicals was discovered. The origin of the electronic D1 → D0 transition of benzyl-type radicals was red-shifted upon substitution to the benzene ring. For symmetric bi-substituted benzyl-type radicals, it was found that the predicted shift obtained from mono-substituted benzyl-type radicals agreed well with the observation. The reason for this agreement is believed that the substituent contributes independently to the electronic energy. The substitution effect was applied to the symmetric bi-substituted difluoro-, dichloro- and dimethylbenzyl radicals.

• Journal of the Korean Operations Research and Management Science Society
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• v.41 no.2
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• pp.1-16
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• 2016

Yield management, which originated from the U.S. service industry, uses pricing techniques and information systems to make demand management decisions. Demand uncertainty is an important factor in the area of demand management. A key strategy to reduce the effects of demand uncertainty is substitution. The most generally known type of substitution is inventory-driven substitution, in which consumers substitute an out-of-stock product by buying a similar or other type of product. Another type of substitution is the price-driven substitution, which occurs as a result of price changes. In this research, we consider two market segments that have unique perishable products. We develop yield management optimization models with stochastic demand based on the newsvendor model where inventory-driven and price-driven substitutions are allowed between products in the two market segments. The most significant contribution of this research is that it develops analytical procedures to determine optimal solutions and considers both types of substitution. We also provide detailed theoretical analysis and numerical examples.

• Journal of the Korean Ceramic Society
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• v.42 no.6 s.277
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• pp.405-410
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• 2005

In the hard oxidizing fire iron red glaze which colorated red exposed magnesioferrite and whitlockite-type crystals. And whitlockite-type crystals has formed before magnesioferrite forming in the step of sintering. This study tries to identify the coloration mechanism of hard oxidizing fire iron red glaze by the experiment of substitution of whitlockite-like crystals and to confirm such substitution be able to farm magnesioferrite. As the results of experiment, magnesioferrite was appeared during substitution of two kinds of whitlockite-type. It can be considered that the magnesioferrite colors the iron glaze to red with covering the glaze surface.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.2
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• pp.45-54
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• 2013

In this paper, a theoretical weight-reduction method was suggested to substitute an underframe material of a box-type bodyshell having cut-outs with an alternative light-weight material. To utilize the material substitution method previously developed for a box-type hybrid bodyshell not having cut-outs, we derived a box-type baseline model without cut-outs which is similar to the stiffness condition of a box-type bodyshell having cut-outs. To do this, the thicknesses of roof and walls of the baseline model were determined such that the deflection of the baseline model under a distributed vertical load condition is equal to the sum of the theoretical section deflections of the original box model with cut-outs. Next, to derive a hybrid bodyshell by under-frame material substitution, the material substitution method for a box-type hybrid bodyshell without cut-outs was applied to the box-type baseline model. Finally, we compared the FE simulation results of the derived hybrid bodyshells having cut-outs for various materials with the theoretical results of the suggested method, and we obtained their good correlations.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.4
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• pp.17-26
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• 2007

In this paper, a theoretical approach is studied to predict structural performances and weight reduction rates of a car-body with shell type sections in case that its materials have to be substituted. For the material substitution design of a car-body, bending, axial and twisting deformations are considered under constant stiffness and strength conditions, which utilize some new indices derived from a structural performance point of view. The developed indices to measure the weight reduction by the material substitution give good guidelines on conceptual design of car-bodies.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.4 no.2
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• pp.95-102
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• 2000

Methane combustion over perovskite-type oxides prepared using the malic acid method was investigated. To enhance the catalytic activity, the perovskite oxides were modified by the substitution of metal into their A or B site. In addition, the reaction conditions, such as the temperature, space velocity, and partial pressure of the methane were varied to understand their effect on the catalytic performance. With the LaCoO3-type catalyst, the partial substitution of Sr or Ba into site A enhanced the catalytic activity in the methane combustion. With the LaBO3(B=Co, Fe, Mn, Cu)-type catalyst, the catalytic activities were exhibited in the order of Co>Fe Mn>Cu. Futhermore, the partial substitution of Co into site B enhanced the catalytic activity, whereas an excess amount of Co decreased the activity. The surface area and catalytic activity of the perovskite catalysts prepared using the malic acid method showed higher values than those prepared using the solid reaction method. The catalytic activity was enhanced with decreased methane concentration and with a decrease in the space velocity.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.1
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• pp.25-33
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• 1998

We have studied the reduction of NO by propane over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution by substitution of metal into A or B site of perovskite oxides. In addition, the reaction conditions, such as temperature, $O_2$ concentration, space velocity have been studed. In the $LaCoO_3$ type catalyst, the partial substitution of Ba, Sr into A site enhanced the catalytic activity in the reduction of NO. In the $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3(x=0 \sim 1.9)$ catalyst, the partial substitution of Fe into B site enhanced the conversion of NO, but excess amount of Fe decreased the conversion of NO. The surface area and catalytic activity of perovskite catalysts prepared by malic acid method showed higher values than those of solid reaction method. In the $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$ catalyst, the conversion of NO increased with increasing $O_2$ concentration and contact time. The introduction of water into reactant feed decreased the catalytic activity.

• Current Research on Agriculture and Life Sciences
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• v.31 no.3
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• pp.177-181
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• 2013

This study examined the effect of the molecular weight, substitution degree, and substitution type of cellulose ether on the mechanical properties of dried rice noodles. When increasing the molecular weight of the hydroxypropyl methylcellulose (HPMC), the bending strength of the dried rice noodles also increased. However, the bending strength of the rice noodles with added HPMCs was still lower than that of the wheat noodles. Meanwhile, the bending elongation of the dried rice noodles was higher than that of the wheat noodles and was increased when decreasing the molecular weight of the HPMC. In conclusion, the bending strength and elongation of dried rice noodles is affected by the substitution degree and type of cellulose ether.

• Bulletin of the Korean Chemical Society
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• v.8 no.5
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• pp.424-425
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• 1987

Alkylation and allylation of arylborates give mono(ipso) and/or di(ortho and ipso) substitution products. Those factors which promote polarization or ionization of alkylating agents favor di substitution. The ${\sigma}$-type(ipso) substitution reaction of arylborates involves direct interaction of the carbon-boron bonds rather than predissociation of arylborates into aryllithiums and boranes.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.11a
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• pp.143-144
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• 2015

In this research it was attempted to analyze the general engineering properties of low cement mortar according to the type of setting accelerator and substitution rate, when 1% substitution rate for setting accelerator was used a high rate of compressive strength manifestation was shown and that the WS-10 type setting accelerator was appropriate. For the rate of change of length, when 3% substitution rate for setting accelerator was used, it was shown that due to initial expansion the shrinkage compensation was not significant, and when taking into consideration strength and shrinkage, 1% of WS-10 was shown to be appropriate.