• 제목/요약/키워드: Substitution Method

검색결과 699건 처리시간 0.029초

철도차량 구조부품의 소재대체 설계 및 평가기법 연구 (A Study on Material Substitution Design and Evaluation Method for Structural Components of Rolling Stocks)

  • 구정서;정현승
    • 한국자동차공학회논문집
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    • 제12권4호
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    • pp.74-84
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    • 2004
  • In this paper, a theoretical method was derived to redesign carbody members by substituting light-weight materials, and to estimate their structural characteristics. Some performance indices to estimate structural behaviors were derived in order to obtain equivalent designs in case of material substitutions under important design constraints of rolling stock, such as bending stiffness, natural frequency, bending and buckling strength. Validity of the theoretical method was evaluated by comparing its results with finite element results in some examples where the aluminium alloy was substituted for the structural steel. The numerical results of the examples show that the proposed method gives reasonable initial guesses for the material substitution designs.

Catalytic Combustion of Methane over Perovskite-Type Oxides

  • Hong, Seong-Soo;Sun, Chang-Bong;Lee, Gun-Dae;Ju, Chang-Sik;Lee, Min-Gyu
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제4권2호
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    • pp.95-102
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    • 2000
  • Methane combustion over perovskite-type oxides prepared using the malic acid method was investigated. To enhance the catalytic activity, the perovskite oxides were modified by the substitution of metal into their A or B site. In addition, the reaction conditions, such as the temperature, space velocity, and partial pressure of the methane were varied to understand their effect on the catalytic performance. With the LaCoO3-type catalyst, the partial substitution of Sr or Ba into site A enhanced the catalytic activity in the methane combustion. With the LaBO3(B=Co, Fe, Mn, Cu)-type catalyst, the catalytic activities were exhibited in the order of Co>Fe Mn>Cu. Futhermore, the partial substitution of Co into site B enhanced the catalytic activity, whereas an excess amount of Co decreased the activity. The surface area and catalytic activity of the perovskite catalysts prepared using the malic acid method showed higher values than those prepared using the solid reaction method. The catalytic activity was enhanced with decreased methane concentration and with a decrease in the space velocity.

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철도차량차체 경량화를 위한 소재대체설계기술 (Introduction to the material substitution design method for the weight reduction of rolling stock carbody)

  • 권태수;구정서;허신
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2003년도 추계학술대회 논문집(III)
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    • pp.446-454
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    • 2003
  • This paper derived a theoretical method to estimate structural characteristics of carbody members when material substitution designs were performed, and verified the theoretical method with finite element analyses. For important factors in rolling stock design, such as bending stiffness, natural frequency, bending strength and buckling strength, some performance indices to estimate structural behaviors were developed in order to derive an equivalent design in spite of material substitutions. The developed method was used to reduce the weights of carbody components, as example problems, by substituting the aluminium alloy for the structural steel. The analysis results of the examples show that the proposed technique gives a reasonable initial guess in the case of a material substitution design.

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Cut-out이 있는 Box형 차체의 하부구조 소재대체 경량화 설계 방법 (A Weight-reduction Design Method by Underframe Material Substitution in a Box-type Bodyshell with Cut-outs)

  • 조정길;구정서;정현승
    • 한국자동차공학회논문집
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    • 제21권2호
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    • pp.45-54
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    • 2013
  • In this paper, a theoretical weight-reduction method was suggested to substitute an underframe material of a box-type bodyshell having cut-outs with an alternative light-weight material. To utilize the material substitution method previously developed for a box-type hybrid bodyshell not having cut-outs, we derived a box-type baseline model without cut-outs which is similar to the stiffness condition of a box-type bodyshell having cut-outs. To do this, the thicknesses of roof and walls of the baseline model were determined such that the deflection of the baseline model under a distributed vertical load condition is equal to the sum of the theoretical section deflections of the original box model with cut-outs. Next, to derive a hybrid bodyshell by under-frame material substitution, the material substitution method for a box-type hybrid bodyshell without cut-outs was applied to the box-type baseline model. Finally, we compared the FE simulation results of the derived hybrid bodyshells having cut-outs for various materials with the theoretical results of the suggested method, and we obtained their good correlations.

Ionic Liquids: An Environmentally Friendly Media for Nucleophilic Substitution Reactions

  • Jorapur, Yogesh R.;Chi, Dae-Yoon
    • Bulletin of the Korean Chemical Society
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    • 제27권3호
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    • pp.345-354
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    • 2006
  • Ionic liquids are alternative reaction media of increasing interest and are regarded as an eco-friendly alternatives, of potential use in place of the volatile organic solvents typically used in current chemical processing methods. They are emerging as the smart and excellent solvents, which are made of positive and negative ions that they are liquids near room temperature. The nucleophilic substitution reaction is one of the important method for inserting functional groups into a carbon skeleton. Many nucleophilic substitution reactions have been found with enhanced reactivity and selectivity in ionic liquid. In this review, some recent interesting results of nucleophilic substitution reactions such as hydroxylations, ether cleavages, carbon-X (X= carbon, oxygen, nitrogen, fluorine) bond forming reactions, and ring opening of epoxides in ionic liquids are discussed.

Low area field-programmable gate array implementation of PRESENT image encryption with key rotation and substitution

  • Parikibandla, Srikanth;Alluri, Sreenivas
    • ETRI Journal
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    • 제43권6호
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    • pp.1113-1129
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    • 2021
  • Lightweight ciphers are increasingly employed in cryptography because of the high demand for secure data transmission in wireless sensor network, embedded devices, and Internet of Things. The PRESENT algorithm as an ultralightweight block cipher provides better solution for secure hardware cryptography with low power consumption and minimum resource. This study generates the key using key rotation and substitution method, which contains key rotation, key switching, and binary-coded decimal-based key generation used in image encryption. The key rotation and substitution-based PRESENT architecture is proposed to increase security level for data stream and randomness in cipher through providing high resistance to attacks. Lookup table is used to design the key scheduling module, thus reducing the area of architecture. Field-programmable gate array (FPGA) performances are evaluated for the proposed and conventional methods. In Virtex 6 device, the proposed key rotation and substitution PRESENT architecture occupied 72 lookup tables, 65 flip flops, and 35 slices which are comparably less to the existing architecture.

Efficient and Simple Method for Designing Chaotic S-Boxes

  • Asim, Muhammad;Jeoti, Varun
    • ETRI Journal
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    • 제30권1호
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    • pp.170-172
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    • 2008
  • A substitution box (S-box) plays a central role in cryptographic algorithms. In this paper, an efficient method for designing S-boxes based on chaotic maps is proposed. The proposed method is based on the mixing property of piecewise linear chaotic maps. The S-box so constructed has very low differential and linear approximation probabilities. The proposed S-box is more secure against differential and linear cryptanalysis compared to recently proposed chaotic S-boxes.

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항추가 및 보정을 적용한 대입에 의한 논리식 간략화 (Logic Substitution Using Addition and Revision of Terms)

  • 권오형
    • 한국산학기술학회논문지
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    • 제18권8호
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    • pp.361-366
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    • 2017
  • 2개 논리식에 대해서 어떤 논리식 F의 일부가 다른 논리식 G 전체를 포함하고 있을 때, 논리식 F의 일부분을 논리식 G로 대치한 식을 대입식이라고 한다. 논리식 사이에 대입 관계가 성립되면 전체 논리식에 사용된 리터럴 개수를 대폭 줄일 수 있는 장점이 있으나, 대입 관계가 성립하지 않는 경우 대입식으로부터 얻을 수 있는 간략화 효과가 없게 되어 상대적으로 리터럴 개수를 줄이는 효과가 줄어들게 된다. 지금까지의 연구들이 주어진 논리식들 자체에 대해서 논리식들 사이의 대입 관계를 찾고, 대입이 가능하면 대입식을 산출하기 위한 방법을 제안하였는데, 본 논문에서는 논리식들 사이에 대입식이 만들어지도록 필요한 항을 추가하고, 다시 추가된 항들에 대한 보정을 통해 대입식을 산출하는 논리합성 방법을 제안한다. 최적화하고자 하는 2개의 논리식들로부터 항추가를 위한 행렬을 만들고, 행렬에서 항이 추가 가능한 묶음 찾고 추가된 항에 대해 보정을 하여 대입식이 완성된다. 실험결과 여러 벤치마크 회로에 대하여 제안한 방법이 기존 합성도구보다 리터럴 개수를 줄일 수 있음을 보였다.

Highly Stable Photoluminescent Qunatum Dot Multilayers by Layer-by-Layer Assembly via Nucleophilic Substitution Reaction in Organic Media

  • 윤미선;김영훈;정상혁;백현희;조진한
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.244.2-244.2
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    • 2011
  • We introduce a novel and robust method for the preparation of nanocomposite multilayers, which allows the excellent photoluminescent (PL) properties as well as the accurate control over the composition and dimensions of multilayers. By exchanging the oleic acid stabilizers of CdSe@ZnS quantum dots (QDs) synthesized in organic solvent with 2-bromo-2-methylpropionic acid (BMPA) in the same solvent, these nanoparticles were be alternately deposited by nucleophilic substitution reaction with highly branched poly(amidoamine) dendrimer (PAMA) through layer-by-layer (LbL) assembly process. Our approach does not need to be transformed into the water-dispersible nanoparticles with electrostatic or hydrogen-bonding groups, which can deteriorate their inherent properties, for the built-up of multilayers. The nanocomposite multilayers including QDs exhibited the strong PL properties achieving densely packed surface coverage as well as long-term PL stability under atmospheric conditions in comparison with those of conventional LbL multilayers based on electrostatic interaction. Furthermore, we demonstrate that the flexible multilayer films with optical properties can be easily prepared using nucleophilic substitution reaction between bromo and amino groups in organic media. This robust and tailored method opens a new route for the design of functional film devices based on nanocomposite multilayers.

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Niobium과 Cobalt를 첨가한 Multiferroic BiFeO3 박막의 유전 특성 및 자성 특성 (Dielectric and Magnetic Properties of Niobium and Cobalt Co-substituted Multiferroic BiFeO3 Thin Films)

  • 전윤기;홍성현
    • 한국세라믹학회지
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    • 제45권9호
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    • pp.556-560
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    • 2008
  • The effects of Nb and Co ion substitution on the dielectric and magnetic properties of the multiferroic $BiFeO_3$ thin films have been investigated. Heteroepitaxial $BiFeO_3$ thin films were deposited by Pulsed Laser Deposition method. Nb substitution decreased the leakage current by 6 orders of magnitude and Co substituted $BiFeO_3$ thin films showed an enhanced magnetization, 2 times larger than that of un-substituted $BiFeO_3$. Through the co-substitution of Co and Nb, $BiFeO_3$ thin films with a low leakage current and an enhanced magnetization could be obtained.