• Bulletin of the Korean Chemical Society
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• 제2권1호
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• pp.17-24
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• 1981

Thermodynamic properties such as sublimation pressures, enthalpies and entropies of sublimation, enthalpies and entropies of solid krypton and xenon are calculated from $0{\circ}K$ to the triple point, using the vacancies-in-solid model. The Mie-Lennard-Jones 12,6 potential in uniform potential field is used. The results are compared with the calorimetric and sublimation pressure values, and are in a good agreement with the available calorimetric and sublimation pressure values.

• 대한기계학회논문집
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• 제17권8호
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• pp.2088-2098
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• 1993

A mathematical model of freeze drying by sublimation was suggested and used to estimate the drying time. Under the various conditions, the drying time of pure water and carrot was numerically calculated for the suggested model. Optimal policies of freeze drying were investigated experimentally in a laboratory freeze dryer. It was found that the shortest drying times could be obtained when the chamber pressure and condenser temperature were kept at their lowest values and the best method of heat transfer for sublimation was the conduction involving radiation. The sublimation drying period was finished when the bottom temperature of material could be reached at near $0^{\circ}C$ from frozen temperature.

• 분석과학
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• 제28권3호
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• pp.187-195
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• 2015

승화열은 대기 유기 오염물질의 확산에 관련된 환경적인 문제를 해결하거나, 위험한 화학 물질의 위해성을 평가하는 데에 중요한 변수이다. 하지만 실험적으로 승화열을 측정하려면 많은 시간과 비용이 소모 되며, 그 실험자체도 복잡하고 위험하다. 따라서 본 연구에서는 유기화합물의 승화열을 간단하게 예측하는 모델을 개발하기 위하여 정량적 구조-물성 상관관계 연구를 이용하였다. 군기반 전진선택방법을 적용하여 다중선형회귀방법과 서포트 벡터 머신과 같은 학습방법에 적합한 분자표현자들을 선택하도록 하였다. 개별 모델과 복합모델들은 부스트래핑 방법과 y-임의추출법에 의해 내부검증이 되었다. 외부 테스트 데이터의 예측 성능은 적용범위를 고려하므로서 개선되었다. 다중선형회귀모델에 따르면, 승화열은 분자간의 분산력, 수소결합, 정전기적 상호작용, 쌍극자-쌍극자 상호작용과 관련이 있는 것을 나타낼 수 있었다.

• Journal of Biosystems Engineering
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• 제18권2호
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• pp.122-132
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• 1993

Effects of physical properties of garlic paste and freeze dry control parameters on the sublimation drying time were investigated to verify optimal operating method in freeze drying. A mathematical model of freeze drying by sublimation was suggested and used to estimate the drying time of garlic paste. Under various conditions, the drying time of garlic paste was calculated using the computer program for the suggested model. Among the physical properties of garlic paste, melting temperature was evaluated the most important factor in affecting the drying time. In supplying methods of the required heat energy for sublimation, it would be the best way to control the upper plate temperature and the lower plate temperature independently.

• 대한기계학회논문집
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• 제17권10호
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• pp.2624-2633
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• 1993

Mass transfer experiment by naphthalene sublimation method has great advantages in measurement of local transfer coefficients in the region of a three dimensional flow or for a model of complex geometry, which is considered to be very difficult with conventional heat transfer measurements. Mass transfer data obtained by naphthalene sublimation technique are converted to the heat transfer data through heat/mass transfer analogy. This analogy is valid for a simple or laminar flow, but new insight is needed when applying to a turbulent flow or complex flow such as separation, reattachment and recirculation, The purpose of this research is to investigate how geometries and flow conditions incorporate heat/mass transfer analogy. Mass transfer experiments are performed using naphthalene sublimation technique for a flat plate, a circular cylinder, and rectangular cylinders. And mass transfer data are compared with earlier heat transfer measurements for the same geometries. Usefulness of analogy relation between heat and mass transfer is examined with these results.

• 대한기계학회논문집B
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• 제20권3호
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• pp.1096-1105
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• 1996

A theoretical model of the frost formation has been presented to investigate the characteristics of the growth of frost layer by considering molecular diffusion of water vapor and heat generation caused by sublimation of water vapor in the frost layer. The present model was compared with existing experimental data as well as a previous model. The difference between the present model and existing experimental data was found to be about 6 percent. An analysis for the behavior of frost formation using present model shows a good agreement with the trend for a number of experimentally observed features. The present analysis can also provide the physical understanding on the phenomena of the frost formation.

• Applied Science and Convergence Technology
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• 제23권4호
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• pp.179-186
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• 2014

Fluid model based numerical simulation was carried out for an inductively coupled plasma assisted sputter deposition system. Power absorption, electron temperature and density distribution was modeled with drift diffusion approximation. Effect of an electrically conducting substrate was analyzed and showed confined plasma below the substrate. Part of the plasma was leaked around the substrate edge. Comparison between the quasi-neutrality based compact model and Poisson equation resolved model showed more broadened profile in inductively coupled plasma power absorption than quasi-neutrality case, but very similar Ar ion number density profile. Electric potential was calculated to be in the range of 50 V between a Cr rod source and a conductive substrate. A new model including Cr sputtering by Ar+was developed and used in simulating Cr deposition process. Cr was modeled to be ionized by direct electron impact and showed narrower distribution than Ar ions.

• 한국식품과학회지
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• 제25권4호
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• pp.313-320
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• 1993

동결건조에서 승화 건조시간을 예측하기 위하여 수학적 모델링과 지배방정식을 설정하고, 당근즙을 대상으로 수치계산하여 실험값과 비교한 바, 수분함량이 많은 동결건조품에서 단위면적당 승화량을 높일 수 있는 재료의 두께는 전도 열전달 방식에서 5mm이었으며, 양면 복사방식에서는 10mm이었다. 또한 동일한 압력에서 응축기 온도가 낮을수록 당근즙의 승화시간은 짧았고, 압력이 높을수록 승화시간은 선형적으로 증가하였다. 그리고 동결건조 효율이 가장 좋은 열전달 방법으로는 전도 및 복사방식으로 상, 하의 플레이트 온도를 $T_x{\leq}T_m$와 $T_m{\leq}T_x$의 제한 조건하에서도 별도 제어하는 방식이었다.

• 대한기계학회논문집B
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• 제31권7호
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• pp.628-634
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• 2007

The present study investigated the heat/mass transfer characteristics in an equilateral triangular channel simulating the leading edge cooling passage in gas turbine blade. Using naphthalene sublimation method and pressure measurement experiments, local mass (heat) transfer and pressure coefficients were obtained. The experiments were conducted with three rotating numbers between 0.0 and 0.1; two channel orientations of $0^{\circ}$ (model A) and $30^{\circ}$ (model B); the fixed Reynolds number of 10,000. The results showed that the channel rotation caused the heat transfer discrepancy between suction and pressure sides. Due to the secondary flow induced by Coriolis force, the high heat transfer appeared on the pressure side. When the channel orientation was $30^{\circ}$ (model B), the secondary flow caused the more uniform heat transfer distribution among leading edge and inner wall on pressure side than that of the model A.

• 대한기계학회논문집
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• 제14권3호
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• pp.685-693
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• 1990

본 연구에서는 복사열전달 효과를 알아보기 위해 에너지 방정식을 수치적으로 풀었으며, 그 결과를 열전달계수 및 온도의 항으로 나타내었다. 수치 해석적 모델의 검증을 위해 여러사람들이 물질전달과정 해석을 위해 사용한 나프타린 승화법(naphth- alene sublimation technique)을 이용하여 실험을 수행하였다. 또한 실험에 사용된 다공질체(ceramic blocks)의 침투율도 측정하였다.