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[Ca1-xSrxAl2O4:Eu2+] 형광체의 상전이 및 발광특성에 관한 연구 (Phase Transformation and Luminescent Properties of Ca1-xSrxAl2O4:Eu2+ Phosphors)

  • 박윤진;송현돈;정상현;이지희;황민하;김영진
    • 한국재료학회지
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    • 제18권1호
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    • pp.1-4
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    • 2008
  • The phase transformations and luminescent properties of Eu-doped $Ca_{1-x}Sr_xAl_2O_4$ phosphors were investigated. $Ca_{1-x}Sr_xAl_2O_4:Eu^{2+}$ phosphors were synthesized by a solid-state reaction with a flux, $H_3BO_3$. A phase transformation from monoclinic $CaAl_2O_4$ to monoclinic $SrAl_2O_4$ was observed as the x values increased. A high-temperature hexagonal phase of $SrAl_2O_4$ was formed during this transformation as an intermediate phase under an $H_2$ atmosphere due to oxygen vacancies; this did not occur in an air atmosphere. Accordingly, the emission spectra shifted from a blue region to a green region as x increased.

Midinfrared Pulse Compression in a Dispersion-decreasing and Nonlinearity-increasing Tapered As2S3 Photonic Crystal Fiber

  • Shen, Jianping;Zhang, Siwei;Wang, Wei;Li, Shuguang;Zhang, Song;Wang, Yujun
    • Current Optics and Photonics
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    • 제5권3호
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    • pp.250-260
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    • 2021
  • A tapered As2S3 photonic crystal fiber (PCF) with four layers of air holes in a hexagonal array around the core is designed in this paper. Numerical simulation shows that the dispersion D decreases and the nonlinearity coefficient γ increases from the thick to the thin end along the tapered PCF. We simulate the midinfrared pulse compression in the tapered As2S3 PCF using the adaptive split-step Fourier method. Initial Gaussian pulses of 4.4 ps and a central wavelength of 2.5 ㎛ propagating in the tapered PCF are located in the anomalous dispersion region. With an average power of assumed input pulses at 3 mW and a repetition frequency of 81.0 MHz, we theoretically obtain a pulse duration of 56 fs and a compression factor of 78 when the pulse propagates from the thick end to the thin end of the tapered PCF. When confinement loss in the tapered PCF is included in the simulation, the minimum pulse duration reaches 72 fs; correspondingly, the maximum compression factor reaches 61. The results show that in the anomalous-dispersion region, midinfrared pulses can be efficiently compressed in a dispersion-decreasing and nonlinearity-increasing tapered As2S3 PCF. Due to confinement loss in the tapered fiber, the efficiency of pulse compression is suppressed.

AN EXTENSION OF SCHNEIDER'S CHARACTERIZATION THEOREM FOR ELLIPSOIDS

  • Dong-Soo Kim;Young Ho Kim
    • 대한수학회보
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    • 제60권4호
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    • pp.905-913
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    • 2023
  • Suppose that M is a strictly convex hypersurface in the (n + 1)-dimensional Euclidean space 𝔼n+1 with the origin o in its convex side and with the outward unit normal N. For a fixed point p ∈ M and a positive constant t, we put 𝚽t the hyperplane parallel to the tangent hyperplane 𝚽 at p and passing through the point q = p - tN(p). We consider the region cut from M by the parallel hyperplane 𝚽t, and denote by Ip(t) the (n + 1)-dimensional volume of the convex hull of the region and the origin o. Then Schneider's characterization theorem for ellipsoids states that among centrally symmetric, strictly convex and closed surfaces in the 3-dimensional Euclidean space 𝔼3, the ellipsoids are the only ones satisfying Ip(t) = 𝜙(p)t, where 𝜙 is a function defined on M. Recently, the characterization theorem was extended to centrally symmetric, strictly convex and closed hypersurfaces in 𝔼n+1 satisfying for a constant 𝛽, Ip(t) = 𝜙(p)t𝛽. In this paper, we study the volume Ip(t) of a strictly convex and complete hypersurface in 𝔼n+1 with the origin o in its convex side. As a result, first of all we extend the characterization theorem to strictly convex and closed (not necessarily centrally symmetric) hypersurfaces in 𝔼n+1 satisfying Ip(t) = 𝜙(p)t𝛽. After that we generalize the characterization theorem to strictly convex and complete (not necessarily closed) hypersurfaces in 𝔼n+1 satisfying Ip(t) = 𝜙(p)t𝛽.

긴 레이저 조사방식에 의한 저밀도 이광자 광중합 영역을 이용한 Sub-100nm 정밀도의 엠보싱 패턴제작 (Fabrication of Sub-100 nm Embossing Patterns using Weakly-Polymerized Region via Long-Exposure Technique (LET) in Two-Photon Polymerization)

  • 박상후;임태우;양동열
    • 한국정밀공학회지
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    • 제24권1호
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    • pp.64-70
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    • 2007
  • A long-exposing technique (LET) has been conducted to create nanoscale patterns applicable to diverse micro-devices using two-photon polymerization (TPP). By the weakly-polymerized region via the LET, double-layered embossing patterns can be fabricated simply in a single step. The LET makes possible a voxel and its surrounding to be fully grown into more than 500 nm in lateral size and weakly-polymerized region (WPR), respectively. In the WPR. interconnecting ribs between voxels are generated, and they lead to the creation of double-layered dot patterns. Moreover, by controlling the distance between voxels, various shapes of interconnecting rib can be fabricated when the LET is applied. Various embossing patterns were fabricated to evaluate the usefulness of the proposed technique as a novel nanopatterning technique in TPP.

저밀도 이광자 광중합 영역을 이용한 30 nm 이하의 패턴제작 (Fabrication of sub-30 nm nanofibers using weakly two-photon induced photopolymerized region)

  • 박상후;임태우;양동열
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1249-1253
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    • 2007
  • Experimental studies on the fabrication of sub-30 nm nanofibers using weakly two-photon induced photopolymerized region have been carried out. For the generation of nanofibers inside or outside microstructures, an over-polymerizing method involving a long exposure technique (LET) was proposed. Such nanofibers can find meaningful applications as bio-filters, mixers, and many other uses in diverse research field. A multitude of nanofibers with a notably high resolution (about 22 nm) in two-photon polymerization was achieved using the LET. Furthermore, it was demonstrated that the LET can be employed for the direct fabrication of various embossing patterns by controlling the exposure duration and the interval between voxels. Thin interconnecting networks are formed regularly in the boundary of the over-polymerized region, which allows for the creation of various pattern shapes. Overall of this work, some patterns including nanofibers are fabricated by the LET.

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Other Southeast Asias? Beyond and Within the Association of Southeast Asian Nations

  • King, Victor T.
    • 수완나부미
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    • 제10권2호
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    • pp.57-85
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    • 2018
  • The debates continue on the conceptualization of Southeast Asia and the ways in which those of us who are concerned to attempt scholarly interventions in the region define, conceive, understand and engage with it. But, in an important sense, the region has now been defined for us by the Association of Southeast Asian Nations (ASEAN), and whatever academic researchers might wish to impose on Southeast Asia in regard to their priorities and interests, it may make little difference. Given the politically-derived, nation-state definition of Southeast Asia, are all our problems of regional definition resolved? In some respects, they have been. ASEAN has constructed and institutionalized a regional organization and an associated regional culture. But in certain fields of research we still require academic flexibility. We cannot always be confined by an ASEAN-derived regional definition. The paper will explore other configurations of 'region' and its sub-divisions and propose, that in the spirit of academic freedom, we can continue to generate imaginative depictions of Southeast Asia and its constituents both within and beyond the region.

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망간이 혼입된 층상구조 Na1.9Li0.1Ti3O7 세라믹스의 유전율 ‒ 분광법과 교류 전도도 측정 연구 (Dielectric-Spectroscopic and ac Conductivity Investigations on Manganese Doped Layered Na1.9Li0.1Ti3O7 Ceramics)

  • Pal, Dharmendra;Pandey, J.L.;Shripal
    • 대한화학회지
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    • 제53권1호
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    • pp.42-50
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    • 2009
  • 유전율-분광법과 교류 전도도 측정 연구를 망간이 혼입된 층상구조의 $Na_{1.9}Li_{0.1}Ti_3O_7$에 시도하였다. 373-723K 온도와 100Hz-1MHz 주파수 영역에서 loss 탄젠트 (Tan$\delta$), 상대적 유전율 ($\varepsilon_{r}$) 그리고 교류 전도 도 ($\sigma_{ac}$)의 의존성을 혼입 유도체들에 대하여 조사하였다. 다양한 전도도 메커니즘이 존재하는데 MSLT-1과 MSLT-2의 경우에는 낮은 온도영역에서 전자에 의한 전도도를 보인다. MSLT-3의 경우에는 금지된 층간 이온 전 도도가 전자 전도도와 함께 존재한다. 이러한 층간 이온 전도도는 모든 혼입 유도체들에 대하여 중간 온도 영역에 존재한다. 가장 높은 온도 영역에서는 MSLT-1과 MSLT-2의 경우에는 이온 전도도와 polaron에 의한 전도도가 존재하고 MSLT-3에 대하여는 이온 전도도 만이 존재한다. 망간이 혼입된 층상구조의 $Na_{1.9}Li_{0.1}Ti_3O_7$에서 Loss 탄젠트 (Tan$\delta$)는 전자 전도도와 쌍극자의 위치, 그리고 공간 전하 분극화에 기인한다. 상대적 유전율의 증가는 층간 에 쌍극자 수의 증가에 기인하고 반면 상대적 유전율의 감소는 높은 혼입율에 따른 누전 전류의 증가에 기인한다.

층상구조의 Na1.9Li0.1Ti3O7과 그 구리 혼입 유도체의 EPR 및 전기적 연구 (EPR and Electrical Studies in Layered Na1.9Li0.1Ti3O7 and its Copper Doped Derivatives)

  • Pal, D.;Chand, Prem;Tandon, R.P.;Shripal
    • 대한화학회지
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    • 제49권6호
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    • pp.560-566
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    • 2005
  • 순수한 또는 미량의 구리(몰 퍼센트(0.0$Na_{1.9}Li_{0.1}Ti_{3-X}Cu_XO_{7-X}$) 물질을 합성하였다. 상온에서 모든 구리 혼입 유도체와 다양한 낮은 온도에서 0.05몰 퍼센트 Cu 혼입 유도체의 EPR 특성을 조사하였다. 격자 안의 $Ti^{4+}$자리에 $Cu^{2+}$가 치환됨으로 인한 TiO6 팔면체의 찌그러짐이 나타났다. 또한, log(${\sigma}_{d.c.}T$) 대 1000/T 그래프를 통하여 세개의 특징적인 영역이 관찰되어진다. 가장 낮은 온도 영역은 모든 구리 혼입 유도체의 polaron 과 Li이 치환된 $Na_2Ti_3O_7$의 이온 전도도에 기인한다. 중간 온도영역의 전도 메커니즘은 관련된 층간의 이온 전도도에 기인하며 가장 높은 온도 영역에서는 변형된 층간 이온 전도도에 기인한다.

Problems of Decarbonization of the Economy of Kazakhstan

  • Yessekina, Bakhyt K.
    • The Journal of Asian Finance, Economics and Business
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    • 제2권3호
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    • pp.37-39
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    • 2015
  • In this article we consider the modern trends of global warming, GHG pollutions and discussions of the obligations of developed and developing countries before the UN Global Climate Summit in Paris. The article considers decarbonization as a national strategy, including complex tools for the improvement of energy efficiency, reduction of CO2 and development of emissions trading systems. The author underlines that the Central Asian countries such as Kazakhstan and Turkmenistan, have the largest GHG potential in the region, and for this reason they should be within the framework of the UNFCCC and join the international process on development of the national decarbonization strategies.Thesemeasuresallowthese countries to join the global carbon trade marketing, international financial recourses, and significantly reduce CO2 pollutions in the region.

STRUCTURE OF A MAGNETIC DECREASE OBSERVED IN A COROTATING INTERACTION REGION

  • LEE, ENSANG;PARKS, GEORGE K.
    • 천문학회지
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    • 제49권1호
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    • pp.19-23
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    • 2016
  • Magnetic decreases are often observed in various regions of interplanetary space. Many studies are devoted to reveal the physical nature and generation mechanism of the magnetic decreases, but still we do not fully understand magnetic decreases. In this study, we investigate the structure of a magnetic decrease observed in a corotating interaction region using multi-spacecraft measurements. We use three spacecraft, ACE, Cluster, and Wind, which were widely separated in the x- and y-directions in the geocentric solar ecliptic (GSE) coordinates. The boundaries of the magnetic decrease are the same at the three locations and can be identified as tangential discontinuities. A notable feature is that the magnetic decrease has very large dimension, ≳ RE, along the boundary, which is much larger than the size, ~ 6 RE, along the normal direction. This suggests that the magnetic decrease has a shape of a long, thin rod or a wide slab.