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A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

Piezoelectric and Dielectric Properties of Low Temperature Sintered Pb(Mn1/3Nb2/3)0.02(Ni1/3Nb2/30.12(ZrxTi1-x)0.86O3 System Ceramics

  • Yoo, Ju-Hyun;Lee, Sang-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.121-124
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    • 2009
  • In this study, in order to develop compositions of ceramics suitable for piezoelectric actuator and ultrasonic vibrator applications using low temperature sintering, multilayer, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3$ and $Na_2CO_3$ as sintering aids. Their structural, piezoelectric and dielectric characteristics were investigated according to the Zr/Ti ratio. As the Zr/Ti ratio increased, the electromechanical coupling factor $k_p$, and piezoelectric constant $d_{33}$ and the mechanical quality factor $Q_m$ all increased with Zr/Ti ratio and then decreased after the ratio exceeded 50/50. At the ratio of Zr/Ti =49/51 and sintering temperature of $900^{\circ}C$; the density, electromechanical coupling factor $k_p$, dielectric constant ${\varepsilon}_r$ piezoelectric $d_{33}$ constant and mechanical quality factor $Q_m$ all showed the optimum values of 7.900 $g/cm^3$, 0.576, 856, 312 pC/N, 1,326, respectively. These property values are very suitable for multilayer ceramics actuator applications.

Impact of Sintering Gas Pressure on Deep-red EuSi2O2N2 Phosphors

  • Deressa, Gemechu;Kim, Jongsu;Kim, Gwangchul
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.2
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    • pp.22-25
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    • 2020
  • Deep red EuSi2O2N2 phosphors were synthesized under various sintering gas pressures (1 atm, 2 atm, and 3 atm). They were in good agreement with the standard EuSi2O2N2 ICSD card # 41-6046 (a monoclinic crystal system with space group of P21/a). Their photoluminescence intensities were significantly increased with increasing the gas pressures. They showed a broad band emission peaking at 680 nm due to 4f65d1 - 4f7 of Eu2+ ion, which can be efficiently excited in the visible range up to 550 nm. The best one at 3 atm was applied for red LED based on blue chip, which showed the strong deep red emission.

A method to construct self organizing system in robotic application

  • Noda, Hiroshi;Hashimoto, Hideki;Harashima, Fumio
    • 제어로봇시스템학회:학술대회논문집
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    • 1988.10b
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    • pp.1022-1027
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    • 1988
  • The author propose a method to realize a self organization in the artificial system. In self organizing system, sub-systems are not constructed as functional parts of the system but cooperate with one another to realize the total system. Each sub-system obtains the local purpose from the global purpose by learning. This function is realized by using a neural network. The validity of this method is confirmed by some simulations.

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Development of a Nursing Fee Schedule Model (적정간호수가 산정모형 개발을 위한 연구)

  • 조소영;박정호
    • Journal of Korean Academy of Nursing
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    • v.23 no.1
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    • pp.68-89
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    • 1993
  • This study was conducted to develop a model of a fee schedule for nursing services.'Regardless of the demand for skilled and professional nursing service today, the Korean health insurance system does not furnish a chapter for the nursing service fee schedule. A nation-wide survey of hospital nursing service fee schedules was to provide practical and realistic data about how the variety of nursing services are being charged. From September 1990 to April 1991, data from the fee schedule used by twenty hospitals located in eight large cities which are designated large medical regions in the Korea Health Care and Patient Referral System were collected. Nursing services and the fees charged for them were analyzed. The nursing services were subjected to a secondary analysis with referrence to reports on “nursing services to be charged in Korea”. The total number of nursing services recommended by the literatures was 177 : finally 141 types of nursing services were selected by investigator as chargable nursing services. In addition, data on managerial characteristics of the hospitals were collected to discover influential variables for a nursing fee schedule model. Under the assumption that all the managerial characteristics of the hospitals influenced the fee schedule, the following model was tested : Fee of nursing services (C) = f(A₁, A₂, A₃, A₄, A/sub 5/, A/sub 6/, A/sub 7/, A/sub 8/,) When, A₁ = number of nurses A₂ = the first salary of a nurse educated in a four year A₃ = scale of nursing management division A₄ = location of the hospital A/sub 5/ = the type of hospital management (profit / non-profit) A/sub 6/ = number of hospital beds A/sub 7/ = years of hospital operation A/sub 8/ = number and kinds of clinical divisions The results showed that the model should be built as follows : C = f (A₁, A/sub 4/, A/sub 5/) Each nursing service was applied to the fee schedule with consideration for the professional level and time-taken to provide the services. Detailed fee schedules were presented in the related tables. Of the 141 kinds of nursing services, 24.8% were chargeble to the Korea Health Insurance, 32.6% of the nursing services were being paid directly by the patienty. The rest of nursing services (42.6%) were not being charged to any source. It was recommened that the Korea Health Insurance Reimbursement system should add a classification system for nursing services that can be used in the national health care program. Further study is needed about how to include 32.6% of the nursing services now being paid for directly by the patients in the health insurance system.

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Stabilization Mechanisms of Powdered and Bead Type Stabilizer Made of Mg-Fe Layered Double Hydroxide (LDH) for the Arsenic Contaminated Soil (Mg-Fe 이중층수산화물로 제조한 분말상과 입상 안정화제의 비소 오염토양 안정화 기작)

  • Kim, Seonhee;Kim, Kyeongtae;Oh, Yuna;Han, Yikyeong;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.27 no.4
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    • pp.49-62
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    • 2022
  • The magnesium and iron-based layered double hydroxide (Mg-Fe LDH) was synthesized by the co-precipitation process and the bead type LDH (BLDH, 5~6 mm in diameter) was manufactured by using the Mg-Fe LDH and the starch as a binder. To evaluate the feasibility of the BLDH as the As stabilizer in the soil, various experiments were performed and the As stabilization efficiency of the BLDH was compared to that of powdered type LDH (PLDH, <149 ㎛ in diameter). For the As sorption batch experiment, the As sorption efficiency of both of the PLDH and the BLDH showed higher than 99%. For the stabilization experiment with soil, the As extraction reducing efficiency of the PLDH was higher than 87%, and for the BLDH, it was higher than 80%, suggesting that the BLDH has similar the feasibility of As stabilization for the contaminated soil, compared to the PLDH. From the continuous column experiments, when more than 7% BLDH was added into the soil, the As stabilization efficiency of the column maintained at over 91% for 7 pore volume flushing (simulating about 21 months of rainfall) and slowly decreased down to 64% after that time (to 36 months) under the non-equilibrium conditions. Results suggested that more than 7% of BLDH added in As-contaminated soil could be enough to stabilize As in soil for a long time. The main As fixation mechanisms on the LDH were also identified through the X-ray fluorescence (XRF), the X-ray diffraction (XRD), and the Fourier transform infrared (FT-IR) analyses. Results showed that the LDH has enough of an external surface adsorption capacity and an anion exchange capability at the interlayer spaces. Results of SEM/EDS and BET analyses also supported that the Mg-Fe LDH used in this study has sufficient porous structures and outer surfaces to fix the As. The reduction of carbonate (CO32-) and sulfate (SO42-) anions in the LDH after the reaction between As and the LDH was observed through the FT-IR, the XRF, and the XRD analyses, suggesting that the exchange of some of these anions with the arsenate (H2AsO4- or HAsO42-) occurs at the LDH interlayers during the stabilization process in soil.

[ H2 ] Control of Uncertain Systems with Actuator Saturation (구동기포화를 갖는 불확실한 시스템의 H2 제어)

  • Choi, Hyoun-Chul;Hong, Suk-Kyo;Chwa, Dong-Kyoung
    • Journal of Institute of Control, Robotics and Systems
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    • v.13 no.10
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    • pp.1000-1006
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    • 2007
  • This paper presents an LMI-based method to design a saturated state-feedback $H_2$ controller for uncertain systems with actuator saturation. Specifically, the paper proposes a sufficient condition such that the system under norm-bounded uncertainties and actuator saturation is asymptotically stable and the $H_2$-norm of the system has an upper-bound. The resulting condition is further utilized to solve a convex optimization problem specified in the context of $H_2$-norm minimization, whose solution yields a saturated $H_2$ controller. A numerical example is presented to show the effectiveness of the proposed method.

Selective Monobromination of 1,3-Diones with N-Bromosaccharin/Mg(ClO4)2 System in Solution and under Solvent-Free Conditions

  • Alinezhad, Heshmatollah;Tajbakhsh, Mahmood;Tehrani, Shahram Shahriari
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1543-1546
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    • 2011
  • N-Bromosaccharin/$Mg(ClO_4)_2$ is an effective and regioselective system for ${\alpha}$-monobromination of 1,3-dicarbonyl compounds. A wide variety of ${\beta}$-keto esters and 1,3-diketones in reaction with this system afforded a regioselectively ${\alpha}$-monobrominated products. The bromination reaction can be conducted at 0-5 $^{\circ}C$ either in solution or under solvent-free conditions.

The exact controllability for the nonlinear fuzzy control system in ENn (ENn상의 비선형 퍼지 제어시스템에 대한 제어가능성)

  • Kwun, Young-Chel;Park, Jong-Seo;Kang, Jum-Ran;Jeong, Doo-Hwan
    • Journal of the Korean Institute of Intelligent Systems
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    • v.13 no.4
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    • pp.499-503
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    • 2003
  • This paper we study the exact controllability for the nonlinear fuzzy control system in $E_N^n$by using the concept of fuzzy number of dimension n whose values are normal, convex, upper semicontinuous and compactly supported surface in $E_N^n$

Numerical Study on Sub-Breaking of Free Surface Viscous Flow (자유표면 점성 유동의 준쇄파 수치연구)

  • Kwag, Seung-Hyun
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2003.10a
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    • pp.226-231
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    • 2003
  • The viscous interaction of stern wave is studied by simulating the free-surface flows, including sub-breaking phenomena around a high speed catamaran hull advancing on calm water. The Navier-Stokes equation is solved by a finite difference method where the body-fitted coordinate system, the wall function and the triple-grid system are invoked. The numerical appearance of the sub-breaking waves is qualitatively supported by the experimental observation They are also applied to study precisely on the stern flow of S-103 as to which extensive experimental data are available. For the catamaran, computations are carried out for the mono ana twin hulls.

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