• Title/Summary/Keyword: Structure identification

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A Study on Characteristics of Natural Organic Matter using XAD and FTIR in Yeongsan River System (XAD 및 FT-IR을 이용한 영산강수계 광주시 유역 자연유기물질의 분포특성 연구)

  • Lee, Dong-Jin;Chon, Kang-Min;Kim, Sang-Don;Jung, Soo-Jung;Lee, Kyung-Hee;Hwang, Tae-Hee;Lim, Byung-Jin;Cho, Jae-Weon
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.358-363
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    • 2011
  • This study investigated the characteristics of natural organic matter(NOM) with tXAD resin and FT-IR in the Yeongsan river system of Gwangju region. NOM fractionation by XAD 8/4 resins was used to classify hydrophobic and hydrophilic substances. FTIR was applied to classify functional groups in the structure of NOM. In the XAD investigation, most of the four site-samples were mainly hydrophilic substances. In March, hydrophobic substances were dominant in the Gwangju 1 site (GJ-1), while hydrophilic substances were dominant for the other sites. In May, samples of all four sites were hydrophilic with a vigorous activity of microorganism due to increasing temperatures. The October results were very similar with those from March. In the FT-IR investigation, most of the broad and large peaks were assigned to the aliphatic group, particularly the OH group, C-H, $C-H_2$, $C-H_3$, and C-O alcohol group. All were related to hydrophilic substances. Other peaks showed the aromatic group, particularly the C=O (Ketone) Group. As a result, there is an identification of NOM in the Yeongsan river system composing mainly of hydrophilic substances and functional groups (OH, C-H etc.) of the aliphatic compound.

Isolation and Structure Identification of Antibacterial Substances from the Rhizome of Zingiber mioga Roscoe (양하의 근경에서 항균성 물질 분리 및 구조동정)

  • Kim, Seong-Cheol;Song, Eun-Young;Kim, Kong-Ho;Kwon, Hyeog-Mo;Kang, Sang-Heon;Park, Ki-Hun;Jung, Yong-Hwan;Jang, Ki-Chang
    • Applied Biological Chemistry
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    • v.46 no.3
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    • pp.246-250
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    • 2003
  • In order to isolate antibacterial substances from the rhizome of Zingiber mioga Roscoe, the ethanol extracts was fractionated according to the activity against Bacillus subtilis, B. cereus and Staphylococcus aureus. Three antibacterial substances were isolated and purified by column chromatography and recrystallization. Compounds I and III showed activity against all the tested bacterias and compound II exhibited the activity against B. subtilis and B. cereus S. aureus. Compound I was examined antimicrobial activity against B. subtilis, B. cereus and S. aureus by optical density using Bioscreen C. Compound I showed strong growth inhibition at 10 ppm on B. subtilis and B. cereus for 72 hrs, and at 25 ppm on S. aureus. On the basis of spectrometric studies including $1^H-NMR$, ${13}^C-NMR$, DEPT, IH-lH COSY, HMQC, HMBC and IR, compounds I, II and III were identified as $(E)-8{\beta}(17)-epoxylabd-12-ene-15,16-dial\;(C_{20}H_{30}O_3,\;MW=318)$, galanolactone $(C_{20}H_{30}O_3\;MW=318)$ and galanal A $(C_{20}H_{30}O_3,\;MW=318)$, respectively. These results are the first reports on the isolation of $(E)-8{\beta}(17)-epoxylabd-12-ene-15,16-dial, galanolactone and galanal A from the rhizome of Zingiber mioga.

Exclusive correlation analysis for algae and environmental factors in weirs of four major rivers in South Korea (4대강 주요지점에서의 조류 발생인자의 배타적 상관성분석에 대한 연구)

  • Lee, Eun Hyung;Kim, Yeonhwa;Kim, Kyunghyun;Kim, Sanghyun
    • Journal of Korea Water Resources Association
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    • v.49 no.2
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    • pp.155-164
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    • 2016
  • Algal blooms not only destroy fish habitats but also diminish biological diversity of ecosystem which results into water quality deterioration of 4 major rivers in South Korea. The relationship between algal bloom and environmental factors had been analyzed through the cross-correlation function between concentration of chlorophyll a and other environmental factors. However, time series of cross-correlations can be affected by the stochastic structure such auto-correlated feature of other controllers. In order to remove external effect in the correlation analysis, the pre-whitening procedure was implemented into the cross correlation analysis. The modeling process is consisted of a series of procedure (e.g., model identification, parameter estimation, and diagnostic checking of selected models). This study provides the exclusive correlation relationship between algae concentration and other environmental factors. The difference between the conventional correlation using raw data and that of pre-whitened series was discussed. The process implemented in this paper is useful not only to identify exclusive environmental variables to model Chl-a concentration but also in further extensive application to configure causality in the environment.

A Study on Total Mixed Ration Feeding System for Feeding Pigs (1) - Development of Monorail Traveling TMR Feeder for Grow-Finish Pigs -

  • Kim, Hyuck Joo;Yu, Byeong Kee;Hong, Jong Tae;Choi, Kyu Hong;Yu, Ji Su;Hong, Youngsin;Ha, Yu Shin
    • Journal of Biosystems Engineering
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    • v.38 no.4
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    • pp.295-305
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    • 2013
  • Purpose: Recent research showed that total mixed ration (TMR) feeding for pigs improved the productivity and reduced feed cost and manure odor. An automatic TMR feeding system was developed for this study because the conventional feeder cannot deliver the TMR containing roughage. Methods: Conventional feeding systems and physical properties of TMR were surveyed, and performance tests of the conventional feeder were conducted to develop a TMR feeder. Based on the TMR feeder was developed and installed, driving, measuring weight, radio frequency identification (RFID) reading, and discharging test for feeding were conducted to ensure the performance. Results: Moisture content, density, and angle of repose of the TMR 1 (mixture of 30% cut IRG silage and 70% concentrates) were 31.6%, 387 $kg/m^3$, and $51^{\circ}$, respectively. Moisture content, density, and angle of repose of the TMR 2 (mixture of 45% concentrates, 30% cut IRG silage and by-products, 10% bean curd refuse, 10% others, and 5% fermenter) were 22.2%, 544 $kg/m^3$, and $50^{\circ}$, respectively. The coefficient of variation (C.V.) of conventional concentrate feeding were 1.9~4.1%, and C.V. of TMR containing 1~3% cut IRG roughage feeding by conventional feeder were 9~42%. The conventional disc type feeder was not suitable for TMR feeding because the supply unit was clogged. The C.V. of TMR 1 was 0.6~7.9% when 0.5~10 kg of the TMR supplied, and it was suitable for feeding grow-finish pigs and sows. On the contrary, the C.V. with TMR 2 was 28% when 0.5 kg of the TMR supplied, and it was not suitable for feeding sows. Conclusions: The TMR feeder developed in this study was suitable for feeding grow-finish pigs because the feeder performed stably with over 5.0 kg feed. However, the feeder showed a lack of accuracy for feeding sows because the amount of each feed was more than 0.5 kg per a feeding. Therefore, the improvement of outlet structure for accurate feeding is needed for sow feeding.

A Study on the Regional Variation of Tenancy System in Later Yi-Dynasty in Korea (조선(朝鮮) 후기소작(後期小作) 형태(形態)의 지역적(地域的).차이(差異)에 관(關)한 연구(硏究))

  • Kim, Ki-Hyuk
    • Journal of the Korean association of regional geographers
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    • v.2 no.2
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    • pp.1-8
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    • 1996
  • The purpose of this study is to analyse the regional variation of tenancy system in later Yi-Dynasty in Korea. Materials for the analysis are acquired through materials(韓國土地農産調査報告), published in 1905 and agricultural census published in 1912. For the identification of difference of tenancy system between agricultural region, regionalization are conducted through by crop combination. Crop combination structure, using rank of LQ index, was clustered into five generic lesions through cluster analysis. In these contexts, this study has come to following conclusions. There are three types of tenancy system in materials; (1) Doji(賭地) system of which landrent was 1/3 agricultural products. Tenant healed the land tax and seeds. (2) Byoengjak(竝作) system of which landrent was 1/2 agricultural products. Landlords healed the land tax and seeds (3) Jeongaek(定額法) system of which landrent was fixed without relation to annual products. But through the analysis of relationship between agricultural region and tenancy system, a new tenancy system could be identified : Byeongjak(竝作) II system. In this system, landrent was 1/2 of agricultural products, but landlord and tenant shared the landtax and seed in common. In the distribution of these systems, relationship between tenancy system and agricultural regions could be identified. Doji system was distributed in the regions where rice and double cropping was specialized. But Byoeongjak(竝作) system was distributed in the regions where upland crops are specialized and ratio of Paddy field is comparatively low. Especially new types were emenged where ratio of paddy field was very low. These show that increase of productivity of land didn't induce the development of the right of ownership in land. The development of ownership was emerged only on the rice paddy fields. Barley cultivated through double-cropping passed into tenant's possessions. So nominal landrent in paddy field seemed to be raised, but actual landrent was maintained about 1/3 of Products through double cropping. On the contrary, rights of cultivation is developed through double cropping. As double cropping is developed, competition on paddy field between tenants was intensified. Consequently nominal land rent of Paddy fields should be raised.

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Isolation and Structure Identification of Antifungal Substance from Aspergillus terreus (Aspergillus terreus로부터 항진균성 물질의 분리 및 구조분석)

  • Kim, Keun-Ki;Park, Ki-Hun;Moon, Suk-Sik;Kang, Kyu-Young
    • Applied Biological Chemistry
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    • v.40 no.6
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    • pp.593-596
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    • 1997
  • In the course of search antagonistic fungi from soil in green house, four kind of fungi (AF1, AF2, AF3, AF4) were isolated, which have activities against Phytophthora capsici, Botrytis cinera, Rhizoctonia solani, Pythium ultimum and Fusarium oxysporum. The AF2 was identified according to the morphological description of Aspergillus terreus. This antagonistic fungus inhibiting various plant pathogens was effective to reduce disease incidence of cucumber seedlings caused by mixed inoculum of Rhizoctonia solani, Pythium ultimum and Fusarium oxysporum. Antifungal compound I was isolated and purified by fresh chromatography from A. terreus. The $^1H$ and $^{13}C$ assignment of compound I was achieved from two-dimensional $^1H-^1H\;COSY$, HMQC, HMBC with the add of homonuclear and heteronuclear double resonance experiment. The compound I was identified butyrolactone I (${\alpha}$-oxo-${\beta}$-(p-hydroxyphenyl)-${\gamma}$-(p-hydroxy-m-3,3-dimethyl-allylbenzyl)-${\gamma}$-methoxycarbonyl-${\gamma}$-butyrolactone, $C_{24}H_{24}O_7$, M.W.=424).

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Characteristics and Dynamic Modeling of MR Damper for Semi-active Vibration Control (준능동 진동 제어를 위한 MR 감쇠기의 동적 모델링을 통한 특성분석)

  • Heo, Gwang-Hee;Jeon, Seung-Gon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.61-69
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    • 2013
  • This research is aimed to evaluate characteristics and dynamic modeling of MR damper for semi-active vibration control. A MR damper of semi-active type was designed and made for the purpose of controlling the vibration of a real-size model structure. Usually a semi-active control system equipped with a MR damper requires a dynamic model which expresses numerical data about the damping capacity and dynamic characteristics generated by a MR damper. To fulfil the requirement, a Power model and a Bingham model were particularly employed among many dynamic models of MR damper. Those models being contrasted with other ones, a dynamic test was carried out on the developed MR damper. In the test, excitation frequencies were conditioned to be 0.15 Hz, 1.0 Hz, and 2.0 Hz, and three different currents were adopted for each frequency. From these test results, it was found that displacement affected control capacity of the MR damper. The test results led to the identification of model variables for each dynamic model, on the basis of which a force-speed relation curve and expected damping force were derived and contrasted to those of the developed MR damper. Therefore, it was proven that the MR damper designed and made in this research was effective as a semi-active controller, and also that displacement of 2mm at minimum was found to be secured for vibration control, through the test using various displacements.

A Study on Tree-ring Dating and Speciation of Charcoal found in Pumiceous Deposit of the Quaternary Nari Caldera, Ulleung Island, Korea (신생대 제4기 울릉도 나리칼데라 부석층에서 산출된 탄화목의 연륜연대 및 수종식별 연구)

  • Im, Ji Hyeon;Choo, Chang Oh
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.501-508
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    • 2015
  • The purpose of this study is to provide an inquiry into paleovegetation (paleoenvironment), eruption age and inferred emplacement temperature of pyroclastic deposit using charcoal occurred in the Quaternary Nari Caldera, Ulleung Island. In order to obtain the data, we carried out species identification and tree-ring analysis, radiocarbon dating for the charcoal. This sample was collected from pumiceous deposit in lowermost member(Member N-5) of the Nari Tephra Formation, which corresponds to the wood branch that has well preserved the tree-ring structure. Speciation and outermost tree-ring of wood reveal Picea spp. and $263+{\alpha}$ years. The calibrated ages from the center(pith) to the outermost tree-ring are $20,260{\pm}230$, $19,995{\pm}245$, and $19,975{\pm}265cal\;BP$, respectively, which are accordant with the tree-ring position. The youngest age, <19,710 cal BP would have implications for the eruptive age of Member N-5. Our results indicate that Picea spp. is the paleovegetation representing that Nari Caldera was under cold and wet climate conditions during the late Pleistocene. Based on the silky luster, brittleness, color, and streak of charcoal, etc., the lowest emplacement temperatures of pyroclastic flow are interpreted to have been at least as high as $350{\sim}500^{\circ}C$.

A Study on the Characteristics of Spatial and Landscape Composition in Jangneung, Paju (파주 장릉(長陵)의 공간 및 경관구성의 특성에 관한 연구)

  • Lee, Chang-Hwan;Kim, Du-Gyu
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.38 no.1
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    • pp.1-9
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    • 2020
  • This paper investigates spatial composition and landscape characteristics of the royal tomb(Jangneung in Paju) where the 12th King(Injo) and the Queen(InnYeol) of the Joseon Dynasty are buried. Based on the investigations, the study suggests the management plan of the Royal tomb at the end. The study includes research on ancient literature and the on-site survey to estimate the ancient landscape architecture of the Royal tomb. Thereby, it is intended to provide the basic data for the identification, preservation, and restoration of the landscape architecture. As a result of the study, first, Jangneung is confirmed that it is a typical formal landscape structure of the Royal tomb in the Joseon Dynasty. Second, Ecological resources around the royal tombs are consistent with previous records and current field research. Third, although the Japanese colonial rule damaged much of the Royal tomb, it preserves much of its core facilities. However, the restoration of ancillary facilities is required, and a World Heritage Conservation Management Plan is required that complies with the ICOMOS Charter.

Design and frnplernentation of a Query Processing Algorithm for Dtstributed Semistructlred Documents Retrieval with Metadata hterface (메타데이타 인터페이스를 이용한 분산된 반구조적 문서 검색을 위한 질의처리 알고리즘 설계 및 구현)

  • Choe Cuija;Nam Young-Kwang
    • Journal of KIISE:Software and Applications
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    • v.32 no.6
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    • pp.554-569
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    • 2005
  • In the semistructured distributed documents, it is very difficult to formalize and implement the query processing system due to the lack of structure and rule of the data. In order to precisely retrieve and process the heterogeneous semistructured documents, it is required to handle multiple mappings such as 1:1, 1:W and W:1 on an element simultaneously and to generate the schema from the distributed documents. In this paper, we have proposed an query processing algorithm for querying and answering on the heterogeneous semistructured data or documents over distributed systems and implemented with a metadata interface. The algorithm for generating local queries from the global query consists of mapping between g1oba1 and local nodes, data transformation according to the mapping types, path substitution, and resolving the heterogeneity among nodes on a global input query with metadata information. The mapping, transformation, and path substitution algorithms between the global schema and the local schemas have been implemented the metadata interface called DBXMI (for Distributed Documents XML Metadata Interface). The nodes with the same node name and different mapping or meanings is resolved by automatically extracting node identification information from the local schema automatically. The system uses Quilt as its XML query language. An experiment testing is reported over 3 different OEM model semistructured restaurant documents. The prototype system is developed under Windows system with Java and JavaCC compiler.