• Title/Summary/Keyword: Structure Stability

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Thermal and Optical Properties of Poly{1-(Cholesteryloxycarbonylalkanoyloxy)ethylene}s (폴리{1-(콜레스테릴옥시카보닐알카노일옥시)에틸렌}들의 열 및 광학 특성)

  • Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.144-152
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    • 2009
  • The thermal and optical properties of poly {1-(cholesteryloxycarbonylalkanoyloxy) ethylene}s (PCALEn, n=2$\sim$8,10, the number of methylene units in the spacer) were investigated. All of the homologues formed monotropic cholesteric phases with left-handed helical structures. PCALEn with n=2 or 10, in constrast with PCALEn with $3{\leq}n{\leq}8$, did not display reflection colors over the full cholesteric range, suggesting that the helical twisting power of the cholesteryl group highly depends on the length of the spacer connecting the cholesteryl group to the polyethylene chain. The glass transition temperatures decreased with increasing n. The isotropic-cholesteric phase transition temperatures decreased with increasing n up to 7 and showed an odd-even effect. However it became almost constant when n is more than 7. This behavior is rationalized in terms of the change in the average shape of the side chain on varing the parity of the spacer. This rationalization also accounts for the observed variation of the entropy gain for the clearing transition. The thermal stability and degree of order in the mesophase and the temperature dependence of the optical pitch observed for PCALEn were significantly different from those reported for cellulose tri(cholesteryloxycarbonyl)alkanoates. The results were discussed in terms of the differences in the chemical structure and flexibility of main chain and the number of the mesogenic units per repeating unit.

Design Methodology on Steel-type Breakwater II. Pile Design Procedure (철재형 이안제 설계기법 연구 II. 하부기초 설계 단계)

  • Kwon, Oh-Kyun;Oh, Se-Boong;Kweon, Hyuck-Min
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.3
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    • pp.219-228
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    • 2011
  • In this paper, the design procedure of substructure of the steel-type breakwater was described and the actual foundation design was performed for the test bed. The site investigation was executed at the Osan-port area, in Uljin, Gyeongbuk, where the steeltype detached breakwater is constructed. The foundation mainly depends on the lateral load and uplift force due to the wave force. Since the superstructure is stuck out about 9.0m from the ocean bed, the foundation must resist on the lateral force and bending moment. After considering various factors, the foundation type of this structure was determined by the steel pipe pile(${\varphi}711{\times}t12mm$). On the stability of pile foundation, the safety factors of the pile on the compressive, lateral and uplift forces were grater than the minimum factor of safety. The displacements of pile under the working load were evaluated as the values below the permissible ones. Based on the subgrade reaction method, we evaluated the relationship of subgrade reaction and displacement for the lateral and the vertical directions in the layers. The structural analyses along with the foundation were perfomed and the effect of pile foundations were compared quantitatively.

A Study on the Analysis of Monitoring Settlement Considering the History of the Groundwater Level in the Dredged Landfill Area Affected by Algae (조류의 영향을 받는 준설매립지역에서 지하수위 이력을 고려한 계측침하 분석에 관한 연구)

  • Jang, Ji-Gun;Son, Su-Won;Hong, Seok-Woo
    • Journal of the Korean Geotechnical Society
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    • v.37 no.7
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    • pp.13-23
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    • 2021
  • If roads, bridges, buildings, etc. are built on the ground with soft clay or organic soil, there may be a lot of problems in geotechnical engineering such as settlement and stability due to the large settlement and lack of bearing capacity. In extreme cases, it may appear due to shear failure or collapse of the constructed structure, so a ground improvement method is indispensable to increase the strength of the ground and to suppress settlement. In this study, the settlement according to each groundwater level condition was analyzed using the measurement results for the groundwater level conditions, one of the important factors in predicting the settlement in dredged and reclaimed ground, and the groundwater level conditions applied to the settlement analysis were proposed by comparing it with settlement generated 5 years after construction. As a result of the analysis, it is judged that it is reasonable to apply the measured groundwater level during construction and the low water ordinary neap tide (L.W.O.N.T) during load application for the groundwater level in the settlement analysis. In addition, in the case of the dredged and reclaimed ground, it is estimated that the water pressure acting on the clay layer is nonlinear, as the result of the observations of the head of water at the observation points above and below the in-situ clay layer were different.

Faunal Composition and Spatial Distributions of Macrozoobenthos in the Tidal Flat of the Nakdong River Estuary, Korea (낙동강 하구 모래갯벌에 서식하는 대형저서동물의 군집구조와 분포양상)

  • Seo, Jin-Young;Choi, Jin-Woo;Shin, Kyoungsoon
    • Journal of Marine Life Science
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    • v.5 no.2
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    • pp.81-91
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    • 2020
  • This study was conducted to find the faunal composition and distribution patterns of macrobenthos where the sand tidal flat around barrier island at Nakdong River estuary in May, 2016 and 2017. The number of species ranged from 31 to 39, and density was from 789 to 1,644 ind.m-2 during the study period in the three tidal flats. The number of species and density were the highest in the tidal flat of Shinja-do and Jinwoo-do, respectively. The dominant species were Gammaridae unid. in amphipods of crustacea, Scoletoma heteropoda, Scoloplos armiger, Heteromastus filiformis, Prionospio japonica in polychaeta and Batillaria cumingii, Laternula marilina in mollusks from the three tidal flats. The proportion of carnivores such as crustacea and mollusks was higher in the upper part of the tidal flat, and polychaetes of deposit feeders, dominated in the middle and lower tidal flat. Overall, the intertidal macrobenthic communities in the study area showed a high proportion of carnivores. However, the sites where the mud content is high such as muddy sand sites, they showed a higher proportion of surface deposit feeders belonging to tube-builders which contribute to sediment stability. From this study, it seemed that the macrobenthic fauna of the sandy tidal flat at the Nakdong River estuary showed a similar fauna composition and zonal distribution patterns from those in other sandy tidal flats in Korea.

A Study on the Fundamental Properties of Mortar Mixed with Converter Slag and Ferronickel Slag (전로슬래그 및 페로니켈슬래그를 혼입한 모르타르의 기초물성 연구)

  • Kim, Ji-Seok;Park, Eon-Sang;Ann, Ki-Yong;Cho, Won-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.152-160
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    • 2021
  • Converter steel slag(BOF slag) is a vast amount of solid waste generated in the steelmaking process which has very low utilization rate in Korea. Due to the presence of free CaO which can derive bad volume stability in BOF slag, it usually land filled. For recycling BOF and identify its applicability as fine aggregate, this study investigates the fundamental characteristics of mortar with cement replaced ferronickel slag(FNS), which has the potential to be used as a binder. The results suggest that the mineral phases of BOF slag mainly include larnite(CaSiO4), mayenite(Ca12Al14O33) and wuestite(FeO) while olivine crystallines are shown in FNS. The results of flow and setting time reveals that the flowability and process of hardening increased when the amount of FNS and BOF slag incorporated was increased. The length change shows that the amount of change in the length of the mortar was almost constant regardless of mix proportion while compressive strength was reduced. Micro structure test results revealed that FNS or/and BOF slag mix took a long time to react in the cement matrix to form a complete hydration products. To achieve the efficient utilization of B OF slag as construction materials, proper replacement rate is necessary.

Stabilization of Tocopheryl Acetate of Swollen Micelle by Poloxamer (Poloxamer를 이용한 Swollen Micelle의 Tocopheryl Acetate 안정화)

  • Kim, Mi-Seon;Yoon, Kyung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.609-622
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    • 2019
  • When the surfactant is dissolved in an aqueous solution, it forms aggregate called micelles (<20 nm) in the solution, and micelles can form the solubilized formulation by supporting the active ingredient therein. Swollen micelles are formulations capable of carrying larger amounts of active ingredient than conventional solubilized formulations at 50~100 nm. Unlike liposomes or nanoemulsions, which require a separate process such as high pressure emulsification, Swollen micelle is a more efficient method of solubilization and particle formation from a productive point of view. In this study, stabilization experiments on swollen micelle formulations were carried out using poloxamer 407, and then optimized formulation experiments for tocopheryl acetate components were performed using Response Surface Methodology (RSM). Tocopheryl acetate, a surfactant that affects solubilization and an active substance, were set as a factor and the correlation between them was confirmed. As the evaluation method, stability and particle size distribution and size were confirmed by temperature and time, and the structure and shape of the swollen micelle carrying the active ingredient were confirmed by FIB. These results show that poloxamer 407 0.500%, octyldodeceth-16 0.387% and tocopheryl acetate 0.945% are the most optimized prescriptions for swollen micelle stabilized with tocopheryl acetate.

Synthesis of Saccharide Nonionic Biosurfactants from Coconut Oil and Characterization of Their Interfacial Properties (코코넛 오일로부터 유래된 당계 비이온 계면활성제 합성 및 계면 특성 연구)

  • Jo, SeonHui;Lee, YeJin;Park, KiHo;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.435-444
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    • 2019
  • In this study, two types of nonionic saccharide biosurfactants, GP-6 and GP-7, were prepared from coconut oil and the structure of resulting products was investigated by FT-IR, $^1H-NMR$ and $^{13}C-NMR$ spectrophotometer. The interfacial properties of GP-6 and GP-7 were found to be excellent from interfacial property measurements such as critical micelle concentration, static and dynamic surface tensions, interfacial tension, emulsification power, wetting property and foam stability. Detergency test evaluated by using a Terg-o-tometer showed moderately good detergency compared to that of conventional surfactants used in detergent formulations. Biodegradability, acute oral toxicity, acute dermal irritation and acute eye irritation tests revealed that both surfactants possess excellent mildness and superior environmental compatibility indicating the potential applicability to detergent products formulations. In particular, GP-6 can be considered as a strong candidate in detergent formulations since it is more surface active, mild and readily biodegradable than GP-7.

Analysis of Emission Characteristics of DC/DC Converter with different Parts Layout (부품배치가 다르게 제작된 DC/DC컨버터의 Emission 특성분석)

  • Park, Jin-Hong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.1
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    • pp.179-183
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    • 2019
  • The system stability must be ensured from the switching noise due to the power conversion efficiency and power conversion system miniaturization. Therefore, countermeasures to reduce switching noise during power conversion are essential. Thus, in the previous paper, we constructed the DC / DC Buck Converter circuit using MPQ4432 driver of MPS, and simulated the switching noise characteristics which occurs when the components are arranged differently in the 4 - layer PCB circuit structure with reference plane. In this paper, two different simulated circuits are fabricated and the characteristics of the conducted emission and the radiated emission are analyzed in the same way as the simulation. As a result, it was confirmed that the Conducted Emission characteristic was reduced by 2 ~ 9dB in the low frequency band and 6 ~ 7dB in the high frequency band depending on the configuration of the current return path. And the radiated emission characteristic is reduced by 9 dB. Conducted emission simulation results show that 6 ~ 7dB in the low frequency range and 2 ~ 9dB in the measurement result are somewhat different. In the high frequency band, it is confirmed that the experimental and simulation results are about 7dB. And Radiated Emission confirmed 12dB decrease in simulation, but confirmed decrease of 9dB in measurement result. It is confirmed that there is a slight difference in the amount of reduction, but the design of the power conversion circuit improves the noise characteristics according to the configuration of the current return path.

Revaluation of the Records Center System in Korea (기록관 체제 재검토)

  • Kwak, Kun-Hong
    • The Korean Journal of Archival Studies
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    • no.27
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    • pp.3-33
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    • 2011
  • Despite the Public Records Management Act in effect for more than 10 years and the various achievements of 'Records management Innovation' made by the former government, records management in Korea still remains unsatisfactory in many fields. Especially one of the main concerns is about the records centers in the public offices failed to work efficiently. There remains lots of so-called ancient regime elements in the records center system, which causes the lack of stability. Divisions of general affairs in the public offices had played main role in records management for more than 50 years since the establishment of the government, and their role was limited to take over some records created and to manage the poor stack room. According to the Public Records Management Act revised in 2007, data center was renamed to records center and it was obliged to place records center under the office of planning management or the office of administration. But records centers have been nevertheless operated at a very formal level in most public offices. It is the real state of affairs that professional records management system interconnecting records office, records center and archives is not achieved. Why is it? This article is an answer to this question. This article attempt to find out on the inner causes such as structure of records center, records management profession, records management methodology, and above all historical background. In addition, it put stress on the necessity of definite separation between records office and records center and assurance of independent operation of records center for the normalization of the records management system. Improvement of methodology including records management process is also of great importance. And the standardization of records management business of the records center is suggested as one of the main tasks on the basis of the accumulation of 'best practices of records management' in the cooperation with the records management community.

Design of 4th Order ΣΔ modulator employing a low power reconfigurable operational amplifier (전력절감용 재구성 연산증폭기를 사용한 4차 델타-시그마 변조기 설계)

  • Lee, Dong-Hyun;Yoon, Kwang-Sub
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.1025-1030
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    • 2018
  • The proposed modulator is designed by utilizing a conventional structure employing time division technique to realize the 4th order delta-sigma modulator using one op-amp. In order to reduce the influence of KT/C noise, the capacitance in the first and second integrators reused was chosen to be 20pF and capacitance of third and fourth integrators was designed to be 1pF. The stage variable technique in the low power reconfigurable op-amp was used to solve the stability issue due to different capacitance loads for the reduction of KT/C noise. This technique enabled the proposed modulator to reduce the power consumption of 15% with respect to the conventional one. The proposed modulator was fabricated with 0.18um CMOS N-well 1 poly 6 metal process and consumes 305uW at supply voltage of 1.8V. The measurement results demonstrated that SNDR, ENOB, DR, FoM(Walden), and FoM(Schreier) were 66.3 dB, 10.6 bits, 83 dB, 98 pJ/step, and 142.8 dB at the sampling frequency of 256kHz, oversampling ratio of 128, clock frequency of 1.024 MHz, and input frequency of 250 Hz, respectively.